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Structural and chemical characterization of TiO2 memristive devices by spatially-resolved NEXAFS.
Strachan, John Paul; Joshua Yang, J; Münstermann, Ruth; Scholl, Andreas; Medeiros-Ribeiro, Gilberto; Stewart, Duncan R; Stanley Williams, R.
Afiliación
  • Strachan JP; Hewlett-Packard Labs, 1501 Page Mill Road, Palo Alto, CA 94304, USA.
Nanotechnology ; 20(48): 485701, 2009 Dec 02.
Article en En | MEDLINE | ID: mdl-19880979
We used spatially-resolved NEXAFS (near-edge x-ray absorption fine structure) spectroscopy coupled with microscopy to characterize the electronic, structural and chemical properties of bipolar resistive switching devices. Metal/TiO2/metal devices were electroformed with both bias polarities and then physically opened to study the resulting material changes within the device. Soft x-ray absorption techniques allowed isolated study of the different materials present in the device with 100 nm spatial resolution. The resulting morphology and structural changes reveal a picture of localized polarity-independent heating occurring within these devices initiated by and subsequently accelerating polarity-dependent electrochemical reduction/oxidation processes.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanotechnology Año: 2009 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Nanotechnology Año: 2009 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido