Preconcentration-separation of Co2+, Ni2+, Cu2+ and Cd2+ in real samples by solid phase extraction of a calix[4] resorcinarene modified Amberlite XAD-16 resin.
J Hazard Mater
; 172(2-3): 802-8, 2009 Dec 30.
Article
en En
| MEDLINE
| ID: mdl-19765894
A new method is described for the simultaneous preconcentration of trace metal ions. The method is based on the adsorption of Co(2+), Ni(2+), Cu(2+) and Cd(2+) ions on 2,4,6,8-tetra(2-hydroxyphenyl)-1,3,5,7(1,3)tetrabenzenzcyclooctaphane-14,16,34,36,54, 56,74,76-octol (salicylaldehyde calix[4] resorcinarenes) (new resorcinarenes derivative) modified on Amberlite XAD-16. The adsorbed analyte ions were eluted with 6 mL 3M HCl in acetone solution, which then were determined by atomic absorption spectroscopy. The influences of the analytical parameters including pH, ligand amount and solid phase ingredient, eluting solution conditions and sample volume were investigated. Common coexisting ions did not interfere with the separation and determination. The preconcentration factor is 208. The sorbent exhibited excellent stability and its sorption capacity under optimum conditions has been found to be more than 60 microg of ions per gram of sorbent. The relative standard deviation under optimum conditions is lower than 4.10%. The accuracy of the method was estimated by using different real samples.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Fenilalanina
/
Metales Pesados
/
Calixarenos
/
Extracción en Fase Sólida
Idioma:
En
Revista:
J Hazard Mater
Asunto de la revista:
SAUDE AMBIENTAL
Año:
2009
Tipo del documento:
Article
País de afiliación:
Irán
Pais de publicación:
Países Bajos