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Assembly and thermal stability of thin EP-PTCDI films on Ag(111).
Serkovic Loli, Laura N; Sánchez, Esteban A; Esteban Gayone, J; Grizzi, Oscar; Esaulov, Vladimir A.
Afiliación
  • Serkovic Loli LN; Centro Atómico Bariloche, Instituto Balseiro, CONICET, Río Negro, Argentina.
Phys Chem Chem Phys ; 11(20): 3849-53, 2009 May 28.
Article en En | MEDLINE | ID: mdl-19440611
We report a multi-technique study of the adsorption kinetics and self-assembly characteristics of EP-PTCDI grown on Ag(111) at UHV conditions and room temperature. Changes in the valence band characteristics for the mono and the multilayer film and the stability as a function of the annealing temperature are discussed. The results show that the molecules start to adsorb on the step edges forming ordered islands that grow to fully cover a monolayer. Further exposure results in the stacking of similarly ordered islands of several layers. The desorption experiment shows that the film is stable up to 150 degrees C where a rapid desorption of the multilayer takes place, followed by a decomposition of the molecules for temperatures higher than 170 degrees C.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Phys Chem Chem Phys Asunto de la revista: BIOFISICA / QUIMICA Año: 2009 Tipo del documento: Article País de afiliación: Argentina Pais de publicación: Reino Unido

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Phys Chem Chem Phys Asunto de la revista: BIOFISICA / QUIMICA Año: 2009 Tipo del documento: Article País de afiliación: Argentina Pais de publicación: Reino Unido