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A simple preparative route to highly stable dispersions of uniform silver nanoparticles.
Jitianu, Andrei; Kim, Myung-Sub; Andreescu, Daniel; Goia, Dan V.
Afiliación
  • Jitianu A; Department of Chemistry, Lehman College, City University of New York, Davis Hall, 250 Bedford Park Boulevard West, Bronx, New York 10468, USA.
J Nanosci Nanotechnol ; 9(3): 1891-6, 2009 Mar.
Article en En | MEDLINE | ID: mdl-19435055
Stable dispersions of uniform silver nanoparticles were prepared by heating silver salts in polyols in the presence of a naphthalene sulfonate/formaldehyde copolymer as dispersant. In the temperature range explored (150-190 degrees C) the modal size and the size distribution of the particles depended on the nature and concentration of the silver salt and the polyol used. Highly dispersed uniform nanoparticles with a diameter of approximately 12 nm were obtained by reducing silver salicylate in diethylene glycol at a metal concentration of 2.5 x 10(-2) mol x cm(-3). Larger silver nanoparticles (approximately 30 nm) and more concentrated dispersions (1.0 mol x cm(-3)) were prepared in ethylene glycol. In all cases the selected dispersant yielded remarkably stable silver sols and facilitated the transfer of the nanoparticles into water, while preserving the stability of the dispersions.
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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Nanosci Nanotechnol Año: 2009 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
Buscar en Google
Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Nanosci Nanotechnol Año: 2009 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos