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Passive air sampling of polychlorinated biphenyls and organochlorine pesticides at the Korean Arctic and Antarctic research stations: implications for long-range transport and local pollution.
Choi, Sung-Deuk; Baek, Song-Yee; Chang, Yoon-Seok; Wania, Frank; Ikonomou, Michael G; Yoon, Young-Jun; Park, Byong-Kwon; Hong, Sungmin.
Afiliación
  • Choi SD; School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Nam-gu, Pohang 790-784, Republic of Korea.
Environ Sci Technol ; 42(19): 7125-31, 2008 Oct 01.
Article en En | MEDLINE | ID: mdl-18939536
To assess levels and patterns of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in polar regions, XAD-resin based passive air samplers were deployed for one year at the Korean polar research stations at Ny-Alesund, Norway (2005-2006) and King George Island, Antarctica (2004-2005). Backward trajectories suggest that these stations are affected by long-range transport from source regions in Northern Europe and Russia and the southern tip of South America, respectively. Relatively high levels of PCB-11, averaging 60 pg x m(-3), were observed in Antarctica, suggesting an unusual source of PCB-11 to the Southern Hemisphere. Reflecting the hemispheric distribution of global PCB emissions, the average level of sigma205PCB (excluding three mono-CBs and PCB-11) was five times higher in the Arctic (95 pg x m(-3)) than in the Antarctic (19 pg x m(-3)). Levels of sigma9PCB at Ny-Alesund were similarto those reported for other Arctic sites, while levels at King George Island were lower than at other sites on the Antarctic Peninsula but 1 order of magnitude higher than background levels measured at a more remote Antarctic site. Light homologues were predominant in all samples (except for one Arctic sample), consistent with the hypothesis of global fractionation and predictions of long-range transport potential. Dominance of heavy PCBs on the roof of the main building at Ny-Alesund and a concentration gradient with distance from the main building at King George Island strongly indicated the influence of local sources. OCP levels were also influenced by long-range transport but not by local sources. This study highlights the feasibility of using passive air sampling to assess both long-range transport and local pollution in remote regions.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Plaguicidas / Transportes / Monitoreo del Ambiente / Bifenilos Policlorados / Aire / Contaminación del Aire Tipo de estudio: Prognostic_studies País/Región como asunto: Asia Idioma: En Revista: Environ Sci Technol Año: 2008 Tipo del documento: Article Pais de publicación: Estados Unidos
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Plaguicidas / Transportes / Monitoreo del Ambiente / Bifenilos Policlorados / Aire / Contaminación del Aire Tipo de estudio: Prognostic_studies País/Región como asunto: Asia Idioma: En Revista: Environ Sci Technol Año: 2008 Tipo del documento: Article Pais de publicación: Estados Unidos