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The N-terminal domain of 2',3'-cyclic nucleotide 3'-phosphodiesterase harbors a GTP/ATP binding site.
Stingo, Stefania; Masullo, Mariorosario; Polverini, Eugenia; Laezza, Chiara; Ruggiero, Immacolata; Arcone, Rosaria; Ruozi, Enrica; Dal Piaz, Fabrizio; Malfitano, Anna Maria; D'Ursi, Anna Maria; Bifulco, Maurizio.
Afiliación
  • Stingo S; Dipartimento di Scienze Farmaceutiche, Università di Salerno, Via Ponte Don Melillo, Fisciano (SA) 84084, Italy.
Chem Biol Drug Des ; 70(6): 502-10, 2007 Dec.
Article en En | MEDLINE | ID: mdl-17986204
The interaction between 2',3'-cyclic nucleotide 3'-phosphodiesterase and guanine/adenine nucleotides was investigated. The binding of purine nucleotides to 2',3'-cyclic nucleotide 3'-phosphodiesterase was revealed by both direct and indirect methods. In fact, surface plasmon resonance experiments, triphosphatase activity measurements, and fluorescence experiments revealed that 2',3'-cyclic nucleotide 3'-phosphodiesterase binds purine nucleotide triphosphates with an affinity higher than that displayed for diphosphates; on the contrary, the affinity for both purine monophosphates and pyrimidine nucleotides was negligible. An interpretation of biological experimental data was achieved by a building of 2',3'-cyclic nucleotide 3'-phosphodiesterase N-terminal molecular model. The structural elements responsible for nucleotide binding were identified and potential complexes between the N-terminal domain of CNP-ase and nucleotide were analyzed by docking simulations. Therefore, our findings suggest new functional and structural property of the N-terminal domain of CNPase.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Nucleótidos de Purina / Simulación por Computador / Modelos Moleculares / 2',3'-Nucleótido Cíclico Fosfodiesterasas Tipo de estudio: Prognostic_studies Límite: Animals Idioma: En Revista: Chem Biol Drug Des Asunto de la revista: BIOQUIMICA / FARMACIA / FARMACOLOGIA Año: 2007 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Nucleótidos de Purina / Simulación por Computador / Modelos Moleculares / 2',3'-Nucleótido Cíclico Fosfodiesterasas Tipo de estudio: Prognostic_studies Límite: Animals Idioma: En Revista: Chem Biol Drug Des Asunto de la revista: BIOQUIMICA / FARMACIA / FARMACOLOGIA Año: 2007 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido