Total syntheses of tambjamines C, E, F, G, H, I and J, BE-18591, and a related alkaloid from the marine bacterium Pseudoalteromonas tunicata.

Pinkerton, David M; Banwell, Martin G; Willis, Anthony C

Pinkerton, David M; Banwell, Martin G; Willis, Anthony C.

Afiliación

Pinkerton DM; Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia.

Org Lett ; 9(24): 5127-30, 2007 Nov 22.

Article en En | MEDLINE | ID: mdl-17963401

RESUMEN

The acetate salts of tambjamines C, E, and F (2-4, respectively), as well as those of the related alkaloids BE-18591 (5) and 6, have been prepared by treatment of bipyrrole aldehyde 16 with the relevant amine in the presence of acetic acid. The 5'-bromo-analogue, 30, of compound 16 has also been prepared and used to obtain the acetate salts of tambjamines G, H, I, and J (8-11 respectively).

Asunto(s)

Alcaloides/síntesis química; Pseudoalteromonas/química; Pirroles/síntesis química; Alcaloides/química; Cristalografía por Rayos X; Modelos Moleculares; Estructura Molecular; Pirroles/química; Estereoisomerismo

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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pirroles / Pseudoalteromonas / Alcaloides Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2007 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Estados Unidos

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