57Fe Mössbauer spectroscopy predicts superstructure for K0.08[Cu(II)(N,N'app)Cl]2[Fe(III)(CN)6].0.92H3O.3H2O.

Mukhopadhyay, Uday; Grunert, C Matthias; Kusz, Joachim; Reiman, Sergey; Gütlich, P; Bernal, Ivan

Mukhopadhyay, Uday; Grunert, C Matthias; Kusz, Joachim; Reiman, Sergey; Gütlich, P; Bernal, Ivan.

Afiliación

Mukhopadhyay U; University of Houston, Chemistry Department, Houston, TX 77204-5003, USA.

Chem Commun (Camb) ; (14): 1444-6, 2007 Apr 14.

Article en En | MEDLINE | ID: mdl-17389987

RESUMEN

The compound [Cu(N,N'app)Cl](2)[Fe(CN)(6)].xH(2)O, with N,N'app being bis(N,N'-3-aminopropylpiperazine), was prepared and its structure determined by single crystal X-ray analysis, confirming a ratio of two copper complexes to one iron complex; (57)Fe Mössbauer spectra showed three quadrupole doublets typical of iron(iii) low spin species which call for the presence of a superstructure.

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Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2007 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

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