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Room-temperature, phosphorimetric determination of the beta-blocking agent pindolol in pharmaceutical tablets, urine and blood serum.
Salinas-Castillo, A; Cañabate-Díaz, B; Segura-Carretero, A; Fernández-Gutiérrez, A.
Afiliación
  • Salinas-Castillo A; Department of Analytical Chemistry, Faculty of Sciences, University of Granada, c/ Fuentenueva s/n, 18071 Granada, Spain.
Anal Bioanal Chem ; 387(5): 1945-8, 2007 Mar.
Article en En | MEDLINE | ID: mdl-17203265
It is already recognised that heavy-atom-induced, room-temperature phosphorescence can be used to determine pindolol in pharmaceutical samples and biological fluids. We describe here a new, simple, rapid and selective development of this technique. The phosphorescence signals derive from the interaction of pindolol with a relatively high concentration of heavy-atom salts in the presence of sodium sulphite as oxygen scavenger. Phosphorescence was registered in the presence of 1.2 M potassium iodide, 15 mM sodium sulphite and 30% v/v methanol at 450 nm, exciting at 285 nm. The detection limit was 21.1 ng mL(-1). The method has been successfully applied to the determination of pindolol in commercial pharmaceutical tablets, urine and blood serum.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pindolol / Comprimidos / Análisis Químico de la Sangre / Urinálisis / Mediciones Luminiscentes Tipo de estudio: Diagnostic_studies / Evaluation_studies Idioma: En Revista: Anal Bioanal Chem Año: 2007 Tipo del documento: Article País de afiliación: España Pais de publicación: Alemania
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Pindolol / Comprimidos / Análisis Químico de la Sangre / Urinálisis / Mediciones Luminiscentes Tipo de estudio: Diagnostic_studies / Evaluation_studies Idioma: En Revista: Anal Bioanal Chem Año: 2007 Tipo del documento: Article País de afiliación: España Pais de publicación: Alemania