Chloro and hydroxo forms of a boron(III) subtriazaporphyrin macrocycle.

Stork, Jay R; Brewer, Jeffrey J; Fukuda, Takamitsu; Fitzgerald, Jeffrey P; Yee, Gordon T; Nazarenko, Alexander Y; Kobayashi, Nagao; Durfee, William S

Stork, Jay R; Brewer, Jeffrey J; Fukuda, Takamitsu; Fitzgerald, Jeffrey P; Yee, Gordon T; Nazarenko, Alexander Y; Kobayashi, Nagao; Durfee, William S.

Afiliación

Stork JR; Department of Chemistry, Buffalo State College, 1300 Elmwood Avenue, Buffalo, NY 14222-1095, USA.

Inorg Chem ; 45(16): 6148-51, 2006 Aug 07.

Article en En | MEDLINE | ID: mdl-16878923

RESUMEN

cis-3,4-Dicyano-3-hexene undergoes cyclotrimerization with BCl3 to form the new subtriazaporphyrin chloro[hexaethylsubtriazaporphyrinato]boron(III). The hydroxo derivative of this macrocycle has also been made, and the X-ray crystal structure of the hydroxy form was determined. Electronic absorption and magnetic circular dichroism spectra of the hydroxo monomer species were interpreted using time-dependent density functional theory calculations.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2006 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

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