Formation of M2+(O2)(C3H8) species in alkaline-earth-exchanged Y zeolite during propane selective oxidation.

Xu, Jiang; Mojet, Barbara L; van Ommen, Jan G; Lefferts, Leon

Xu, Jiang; Mojet, Barbara L; van Ommen, Jan G; Lefferts, Leon.

Afiliación

Xu J; Catalytic Processes and Materials, Faculty of Science and Technology, Institute of Mechanics Processes and Control Twente (IMPACT), University of Twente, P.O. box 217, 7500 AE, Enschede, The Netherlands.

J Phys Chem B ; 109(39): 18361-8, 2005 Oct 06.

Article en En | MEDLINE | ID: mdl-16853364

RESUMEN

The adsorption of oxygen and d2-propane (CH3CD2CH3) on a series of alkaline-earth-exchanged Y zeolite at room temperature was studied with in situ infrared spectroscopy. Surprisingly at room temperature, oxygen adsorption led to the formation of supercage M2+(O2) species. Further, at low propane coverage, propane was found to adsorb linearly on Mg2+ cations, but a ring-adsorption structure was observed for propane adsorbing on Ca2+, Sr2+, and Ba2+ cations. It is demonstrated that O2 and propane can simultaneously attach to one active center (M2+) to form a M2+(O2)(C3H8) species, which is proposed to be the precursor in thermal propane selective oxidation. Selectivity to acetone in the propane oxidation reaction decreases with increasing temperature and cation size due to the formation of 2-propanol and carboxylate ions. An extended reaction scheme for the selective oxidation of propane over alkaline earth exchanged Y zeolites is proposed.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Phys Chem B Asunto de la revista: QUIMICA Año: 2005 Tipo del documento: Article País de afiliación: Países Bajos Pais de publicación: Estados Unidos

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