Fluorescence determination of the pesticide asulam by flow injection analysis.
Anal Sci
; 22(1): 21-4, 2006 Jan.
Article
en En
| MEDLINE
| ID: mdl-16429766
This paper presents the analytical determination of the pesticide Asulam based on its native fluorescence. The method was optimized in either a flow injection analysis (FIA) assembly or in batch. The maximum fluorescence intensity was observed for basic pH solutions and at a lamda(ex) of 258 nm and a lamda(em) of 342 nm. The influence of different empirical parameters, such as the pH, the presence of surfactants, solvent polarity or solved oxygen amount, was studied. The calibration range was fitted with a linear equation from 0.01-3 mg l(-1) Asulam and 0.005-15 mg l(-1) Asulam for batch and continuous-flow, respectively. The RSD for both procedures was 1.0%. After testing the influence of a large series of potential interferents, the method was applied to water samples from different locations.
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Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Carbamatos
/
Residuos de Plaguicidas
/
Herbicidas
Tipo de estudio:
Diagnostic_studies
Idioma:
En
Revista:
Anal Sci
Año:
2006
Tipo del documento:
Article
País de afiliación:
España
Pais de publicación:
Suiza