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N-and O-acetylation of aromatic and heterocyclic amine carcinogens by human monomorphic and polymorphic acetyltransferases expressed in COS-1 cells.
Minchin, R F; Reeves, P T; Teitel, C H; McManus, M E; Mojarrabi, B; Ilett, K F; Kadlubar, F F.
Afiliación
  • Minchin RF; Department of Pharmacology, University of Western Australia, Nedlands.
Biochem Biophys Res Commun ; 185(3): 839-44, 1992 Jun 30.
Article en En | MEDLINE | ID: mdl-1627140
Human monomorphic and polymorphic arylamine acetyltransferases (EC 2.3.1.5) were expressed in monkey kidney COS-1 cells and used to study the N- and O-acetylation of a number of carcinogenic amines and their N-hydroxy metabolites. The monomorphic enzyme N-acetylated the aromatic amines, 2-aminofluorene and 4-aminobiphenyl, and also O-acetylated their N-hydroxy derivatives. None of the food-derived heterocyclic amines (Glu-P-1, PhIP, IQ, MeIQx) were substrates and their N-hydroxy metabolites were poorly O-acetylated by this isozyme. By contrast, the polymorphic acetyltransferase catalyzed the N-acetylation of both aromatic amines, and to a lesser extent, Glu-P-1 and PhIP. However, all six N-hydroxy amine substrates were readily O-acetylated to form DNA-bound adducts by the polymorphic isozyme. These data suggest that, for the heterocyclic amine carcinogens, rapid acetylator individuals will be predisposed to their genotoxicity.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arilamina N-Acetiltransferasa / Carcinógenos / Transfección / Aminas / Compuestos Heterocíclicos Límite: Animals / Humans Idioma: En Revista: Biochem Biophys Res Commun Año: 1992 Tipo del documento: Article Pais de publicación: Estados Unidos
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Arilamina N-Acetiltransferasa / Carcinógenos / Transfección / Aminas / Compuestos Heterocíclicos Límite: Animals / Humans Idioma: En Revista: Biochem Biophys Res Commun Año: 1992 Tipo del documento: Article Pais de publicación: Estados Unidos