NaBH4-InCl3-mediated one-pot chemo- and stereoselective decarboxylative reduction of alpha-aza gem-dicarboxylic esters to monoalcohols.

Haldar, Pranab; Ray, Jayanta K

Haldar, Pranab; Ray, Jayanta K.

Afiliación

Haldar P; Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India.

Org Lett ; 7(20): 4341-3, 2005 Sep 29.

Article en En | MEDLINE | ID: mdl-16178528

RESUMEN

[reaction: see text] The combination of NaBH4 and a catalytic amount of InCl3 provides a one-pot method for chemo- and stereoselective decarboxylative reduction of gem-dicarboxylic esters 1 to monoalcohols 2 in the presence of the lactam carbonyl in refluxing acetonitrile under inert atmosphere.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2005 Tipo del documento: Article País de afiliación: India Pais de publicación: Estados Unidos

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