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Simultaneous quantification of different cyclodextrins and Gantrez by HPLC with evaporative light scattering detection.
Agüeros, M; Campanero, M A; lrache, J M.
Afiliación
  • Agüeros M; Centro Galénico, Universidad de Navarra, Aptdo. 177, C/ Irunlarrea s/n, 31080 Pamplona, Navarra, Spain.
J Pharm Biomed Anal ; 39(3-4): 495-502, 2005 Sep 15.
Article en En | MEDLINE | ID: mdl-15946816
A rapid and simple HPLC method with evaporative scattering detection (ELSD) has been developed for the separation and quantitation of beta-cyclodextrin (beta-CD), 2-hydroxypropyl-beta-cyclodextrin (2-HP-beta-CD) and poly(methyl vinyl ether-co-maleic anhydride) (Gantrez). Separation was carried out on a Zorbax Eclipse XDB-Phenyl narrow bore column, with water-acetonitrile in gradient elution as mobile phase at a flow-rate of 0.25 ml/min. Polyethylenglycol 6000 was used as internal standard. The limit of quantification was of about 0.2 mg/ml for cyclodextrins and 0.05 mg/ml for Gantrez. The precision did not exceed 7%. This method was successfully applied to the rapid analysis of CD-Gantrez nanoparticle conjugates without interference from other components of the formulation.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Cromatografía Líquida de Alta Presión / Ciclodextrinas / Beta-Ciclodextrinas Tipo de estudio: Diagnostic_studies Idioma: En Revista: J Pharm Biomed Anal Año: 2005 Tipo del documento: Article País de afiliación: España Pais de publicación: Reino Unido
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Cromatografía Líquida de Alta Presión / Ciclodextrinas / Beta-Ciclodextrinas Tipo de estudio: Diagnostic_studies Idioma: En Revista: J Pharm Biomed Anal Año: 2005 Tipo del documento: Article País de afiliación: España Pais de publicación: Reino Unido