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Focused microwave aqueous extraction of chlorophenols from solid matrices and their analysis by chromatographic techniques.
Ganeshjeevan, R; Chandrasekar, Raghavan; Sugumar, Ponnusamy; Kadigachalam, Parasuraman; Radhakrishnan, Ganga.
Afiliación
  • Ganeshjeevan R; Eco Analytical Laboratory, Central Leather Research Institute, Adyar, Chennai 600020, Tamilnadu, India.
J Chromatogr A ; 1069(2): 275-80, 2005 Apr 01.
Article en En | MEDLINE | ID: mdl-15830955
Open-vessel focused microwave (FMW) extraction with a purely aqueous carbonate solution was used for the extraction of chlorophenols from various solid matrices. After SPE on C18-bonded silica, the analytes were determined as such by LC-UV or, as their acetyl derivatives, by GC-ECD. The FMW aqueous extraction is efficient and rapid and no organic solvents are used. PCP was detected in several solid samples, with recoveries of 101-115% (RSD, 2-4%) relative to Soxhlet extraction. Similar recoveries were obtained for the other chlorophenols for spiked samples.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Clorofenoles / Cromatografía de Gases / Cromatografía Liquida / Microondas Límite: Animals Idioma: En Revista: J Chromatogr A Año: 2005 Tipo del documento: Article País de afiliación: India Pais de publicación: Países Bajos
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Clorofenoles / Cromatografía de Gases / Cromatografía Liquida / Microondas Límite: Animals Idioma: En Revista: J Chromatogr A Año: 2005 Tipo del documento: Article País de afiliación: India Pais de publicación: Países Bajos