Novel metallamacrocyclic gold(I) thiolate cluster complex: structure and luminescence of [Au9(mu-dppm)4(mu-p-tc)6](PF6)3.

Chen, Jinhua; Mohamed, Ahmed A; Abdou, Hanan E; Bauer, Jeanette A Krause; Fackler, John P; Bruce, Alice E; Bruce, Mitchell R M

Chen, Jinhua; Mohamed, Ahmed A; Abdou, Hanan E; Bauer, Jeanette A Krause; Fackler, John P; Bruce, Alice E; Bruce, Mitchell R M.

Afiliación

Chen J; Department of Chemistry, University of Maine, Aubert Hall, Orono, ME 04469-5706, USA.

Chem Commun (Camb) ; (12): 1575-7, 2005 Mar 28.

Article en En | MEDLINE | ID: mdl-15770264

RESUMEN

The structure of a novel metallamacrocyclic phosphine gold(I) thiolate cluster, [Au9(mu-dppm)4(mu-p-tc)6](PF6)3, where dppm = bis(diphenylphosphine)methane and p-tc = p-thiocresolate, is reported and shows AuAu attractions of approximately 3.0 A and gold(I) atoms linked to thiolate and phosphine ligands in distorted trigonal and nearly linear geometries.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2005 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Reino Unido

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