Asymmetric synthesis of deoxypolypropionate units via stereoselective hydrogenation of optically active cycloheptatriene.

Sugimura, Takashi; Sato, Yasuhiro; Im, Chun Young; Okuyama, Tadashi

Sugimura, Takashi; Sato, Yasuhiro; Im, Chun Young; Okuyama, Tadashi.

Afiliación

Sugimura T; Graduate School of Material Science, Himeji Institute of Technology, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo 678-1297, Japan.

Org Lett ; 6(24): 4439-42, 2004 Nov 25.

Article en En | MEDLINE | ID: mdl-15548045

RESUMEN

Optically active polypropionate units were synthesized in 9-11 steps from 3,5-dimethylphenol. The sequence consists of the Buchner reaction controlled by a chiral 2,4-pentanediol tether and diastereoselective hydrogenation over Raney nickel. [reaction: see text]

Buscar en Google

Añadir a Mi BVS

Imprimir

XML

PubMed Links

Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2004 Tipo del documento: Article País de afiliación: Japón Pais de publicación: Estados Unidos

Buscar en Google

Añadir a Mi BVS

Imprimir

XML

PubMed Links