Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine).

Cinellu, Maria A; Minghetti, Giovanni; Stoccoro, Sergio; Zucca, Antonio; Manassero, Mario

Cinellu, Maria A; Minghetti, Giovanni; Stoccoro, Sergio; Zucca, Antonio; Manassero, Mario.

Afiliación

Cinellu MA; Dipartimento di Chimica, Universita di Sassari, via Vienna 2, I-07100 Sassari, Italy. cinellu@uniss.it

Chem Commun (Camb) ; (14): 1618-9, 2004 Jul 21.

Article en En | MEDLINE | ID: mdl-15263946

RESUMEN

Gold alkene complexes [Au(bipyR)(eta2-alkene)][PF6] (bipyR = 6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au2(bipyR)2(mu-O)2][PF6]2 with alkenes. The crystal structure of the styrene adduct [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine) has been solved by X-ray analysis.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2004 Tipo del documento: Article País de afiliación: Italia Pais de publicación: Reino Unido

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