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The fate of endosulfan in aquatic ecosystems.
Peterson, S M; Batley, G E.
Afiliación
  • Peterson SM; CSIRO Centre for Advanced Analytical Chemistry, Private Mail Bag 7, Menai, NSW, 2234, Australia.
Environ Pollut ; 82(2): 143-52, 1993.
Article en En | MEDLINE | ID: mdl-15091783
Endosulfan, one of the major pesticides used in cotton-growing, is of environmental concern because of its toxicity to fish and its apparent persistence in the environment. This study examines the distribution and degradation pathways for endosulfan in an aquatic system and the processes by which it is removed. In the alkaline waters of the cotton region, hydrolysis is the dominant degradation process. By this mechanism alone, the expected half-lives for the alpha- and beta-endosulfan isomers were found to be 3.6 days and 1.7 days, respectively. Partitioning studies showed, however, that the major proportion of endosulfan would associate with the sediments (log Koc(alpha) 3.6 and log Koc(beta) 4.3). Field studies confirmed the presence of high concentrations in sediments. Microcosm experiments showed that loss of endosulfan was slower than predicted from hydrolysis rates. Models are presented to explain how desorption from sediment limits the loss of endosulfan from a system.
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Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Environ Pollut Asunto de la revista: SAUDE AMBIENTAL Año: 1993 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Reino Unido
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Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies Idioma: En Revista: Environ Pollut Asunto de la revista: SAUDE AMBIENTAL Año: 1993 Tipo del documento: Article País de afiliación: Australia Pais de publicación: Reino Unido