Speciation of arsenic in water samples by high-performance liquid chromatography-hydride generation-atomic absorption spectrometry at trace levels using a post-column reaction system.
Anal Bioanal Chem
; 354(3): 344-51, 1996 Jan.
Article
en En
| MEDLINE
| ID: mdl-15048460
Anion-exchange HPLC has been combined with hydride generation - atomic absorption spectrometry (HG-AAS) for the routine speciation of arsenite, arsenate, monomethylarsenic acid and dimethylarsinic acid. The sensitivity of the AAS-detection was increased by a post-column reaction system to achieve complete formation of volatile arsines from the methylated species and arsenate. The system allows the quantitative determination of 0.5 microg/l of each arsenic compound in water samples. The stability of synthetical and natural water containing arsenic at trace levels was investigated. To preserve stored water samples, a method for quantitative separation of arsenate at high pH-values with the basic anion-exchange resin Dowex 1x8 was developed.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Anal Bioanal Chem
Año:
1996
Tipo del documento:
Article
País de afiliación:
Alemania
Pais de publicación:
Alemania