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Synthesis, characterization and mutagenicity of new cis-[Pt(2-substituted-benzimidazole)2Cl2] complexes.
Gümüs, F; Demirci, A B; Ozden, T; Eroglu, H; Diril, N.
Afiliación
  • Gümüs F; Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Gazi University, Etiler, Ankara, Turkey. gumusf@pharmacy.gazi.edu.tr
Pharmazie ; 58(5): 303-7, 2003 May.
Article en En | MEDLINE | ID: mdl-12779045
In this study, four new platinum(II) complexes with the structures cis-[Pt(Ligand)2Cl2] (ligand = 2-(p-methoxy-/or-p-chlorobenzyl or p-methoxyphenyl)benzimidazol (1, 2, 4 respectively) and 5(6)-methyl-2-phenoxymethylbenzimidazole (3) were synthesized and characterized by their elemental analysis, and IR and 1H NMR spectra. The potentials of the Pt(II) complexes for short-term bacterial mutagenicity were tested in reverse-mutation assays using Salmonella typhimurium frame-shift strain T 98 and S. typhimurium TA 100 and TA 102 strains, which carry mutations particularly sensitive to reversion by DNA base-pair substitution. The tests were performed in the absence of S9 rat liver fraction. Among the complexes tested 1 had no mutagenic activity. Complex 4 was found to be weakly mutagenic in TA 98 only. The Pt(II) complexes 2 and 3 were found to be mutagenic in TA 98, TA 100 and TA 102.
Asunto(s)
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Compuestos Organoplatinos / Bencimidazoles / Mutágenos / Antineoplásicos Límite: Animals Idioma: En Revista: Pharmazie Asunto de la revista: FARMACIA Año: 2003 Tipo del documento: Article País de afiliación: Turquía Pais de publicación: Alemania
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Compuestos Organoplatinos / Bencimidazoles / Mutágenos / Antineoplásicos Límite: Animals Idioma: En Revista: Pharmazie Asunto de la revista: FARMACIA Año: 2003 Tipo del documento: Article País de afiliación: Turquía Pais de publicación: Alemania