Fluorine-free organoxenon chemistry: HXeCCH, HXeCC, and HXeCCXeH.

Khriachtchev, Leonid; Tanskanen, Hanna; Lundell, Jan; Pettersson, Mika; Kiljunen, Harri; Räsänen, Markku

Khriachtchev, Leonid; Tanskanen, Hanna; Lundell, Jan; Pettersson, Mika; Kiljunen, Harri; Räsänen, Markku.

Afiliación

Khriachtchev L; Department of Chemistry, FIN-00014 University of Helsinki, Finland. Leonid.Khriachtchev@Helsinki.Fi

J Am Chem Soc ; 125(16): 4696-7, 2003 Apr 23.

Article en En | MEDLINE | ID: mdl-12696873

RESUMEN

Three novel Xe-containing organic compounds, HXeCCH, HXeCC (open-shell species), and HXeCCXeH, are identified using infrared absorption spectroscopy. They are prepared in a low-temperature Xe matrix using UV photolysis of acetylene and subsequent annealing at 40-45 K. The experimental observations are supported by extensive ab initio calculations. This work demonstrates a new way to activate the H-Ctbd1;C- group without use of XeF(2), which can extend the range of organoxenon compounds.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2003 Tipo del documento: Article País de afiliación: Finlandia Pais de publicación: Estados Unidos

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