Simultaneous and stereoselective formation of planar and axial chiralities in enantiopure sulfinyl iron diene complexes.

Paley, Robert S; Liu, Jane M; Lichtenstein, Bruce R; Knoedler, Vanessa L; Sanan, Toby T; Adams, Drew J; Fernández, Jorge; Rablen, Paul R

Paley, Robert S; Liu, Jane M; Lichtenstein, Bruce R; Knoedler, Vanessa L; Sanan, Toby T; Adams, Drew J; Fernández, Jorge; Rablen, Paul R.

Afiliación

Paley RS; Swarthmore College, Department of Chemistry, Swarthmore, Pennsylvania 19081, USA. rpaley1@swarthmore.edu

Org Lett ; 5(3): 309-12, 2003 Feb 06.

Article en En | MEDLINE | ID: mdl-12556179

RESUMEN

[reaction: see text] Enantiopure (1Z,3E)-1-sulfinyl dienes bearing an o-dithianylphenyl group can be prepared and complexed with (bda)Fe(CO)(3) to afford the corresponding sulfinyl diene iron(0) tricarbonyl complexes. This diastereoselective complexation introduces planar and axial chirality simultaneously, with a high degree of facial selectivity as well as atropselectivity. Dynamic kinetic resolution is likely to be the origin of the atropselectivity.

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Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2003 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

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