Control over directional metal-metal charge transfer in cyanide-bridged dimanganese complexes: effects of mu-CN linkage isomerism and ancillary ligand set.
Chem Commun (Camb)
; (18): 1734-5, 2001 Sep 21.
Article
en En
| MEDLINE
| ID: mdl-12240289
Synthesis and characterisation of cyano-bridged complexes of the form [(eta-C5R4Me)L(ON)Mn(mu-XY)Mn(CO)2-L'(dppm)]z (X,Y = C,N; z = 1-3) shows that systematic variation of the orientation of the CN bridge and the nature and geometric arrangement of the ancillary ligands affords control of the direction and energy of metal-metal charge transfer in the mixed valence dications.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2001
Tipo del documento:
Article
Pais de publicación:
Reino Unido