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Scattering of water from the glycerol liquid-vacuum interface.
Benjamin, I; Wilson, M A; Pohorille, A; Nathanson, G M.
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  • Benjamin I; Department of Chemistry, University of California, Santa Cruz 95064, USA.
Chem Phys Lett ; 243(3-4): 222-8, 1995 Sep 15.
Article en En | MEDLINE | ID: mdl-11540427
Molecular dynamics calculations of the scattering of D2O from the glycerol surface at different collision energies are reported. The results for the trapping probabilities and energy transfer are in good agreement with experiments. The calculations demonstrate that the strong attractive forces between these two strongly hydrogen bonding molecules have only a minor effect on the initial collision dynamics. The trapping probability is influenced to a significant extent by the repulsive hard sphere-like initial encounter with the corrugated surface and, only at a later stage, by the efficiency of energy flow in the multiple interactions between the water and the surface molecules.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Agua / Glicerol / Modelos Químicos Idioma: En Revista: Chem Phys Lett Año: 1995 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Países Bajos
Buscar en Google
Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Agua / Glicerol / Modelos Químicos Idioma: En Revista: Chem Phys Lett Año: 1995 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Países Bajos