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Tetragonal crystalline carbon nitrides: theoretical predictions.
Kim, E; Chen, C; Köhler, T; Elstner, M; Frauenheim, T.
Afiliación
  • Kim E; Department of Physics and High Pressure Science Center, University of Nevada, Las Vegas, 89154, USA.
Phys Rev Lett ; 86(4): 652-5, 2001 Jan 22.
Article en En | MEDLINE | ID: mdl-11177904
New tetragonal phases of crystalline carbon nitride (CN) and their atomic structures have been identified using a self-consistent-charge density-functional tight-binding method. A tetragonal rocksalt structure provides theoretical support to recent experimental evidence for a stoichiometric CN phase with tetragonal symmetry. A body-centered tetragonal CN phase with 1:1 stoichiometry is predicted to be highly stable and of interesting atomic structure with complicated C-C and N-N dimerizations along the c axis. The cubic-to-tetragonal transitions are carefully examined to understand the underlying mechanism.
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Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Phys Rev Lett Año: 2001 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
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Colección: 01-internacional Base de datos: MEDLINE Tipo de estudio: Prognostic_studies / Risk_factors_studies Idioma: En Revista: Phys Rev Lett Año: 2001 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos