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A reactive metabolite of furan, cis-2-butene-1,4-dial, is mutagenic in the Ames assay.
Peterson, L A; Naruko, K C; Predecki, D P.
Afiliación
  • Peterson LA; Division of Environmental and Occupational Health and Cancer Center, University of Minnesota, Minneapolis 55455, USA.
Chem Res Toxicol ; 13(7): 531-4, 2000 Jul.
Article en En | MEDLINE | ID: mdl-10898583
Furan is classified as a nongenotoxic hepatocarcinogen. It is thought to be activated to a toxic metabolite, cis-2-butene-1,4-dial, which is acutely toxic to liver cells. The resulting cytotoxicity is followed by compensatory cell proliferation, increasing the likelihood of tumor production. We examined the genotoxic activity of cis-2-butene-1,4-dial in several strains of Salmonella typhimurium commonly used in the Ames assay. This reactive compound tested positive in TA104, a strain that is sensitive to aldehydes. Mutagenic activity was concentration-dependent (1000 +/- 180 revertants/micromol). Incubation of cis-2-butene-1,4-dial with glutathione prior to addition of bacteria inhibited both the acute toxic and genotoxic activity of this compound. No evidence of mutagenic activity was seen at nontoxic concentrations in TA97, TA98, TA100, and TA102. Our findings are consistent with the hypothesis that cis-2-butene-1,4-dial reacts with DNA to form mutagenic adducts. Our data suggest that cis-2-butene-1,4-dial may be an important genotoxic as well as toxic intermediate in furan-induced tumorigenesis.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Aldehídos / Furanos / Mutágenos Idioma: En Revista: Chem Res Toxicol Asunto de la revista: TOXICOLOGIA Año: 2000 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Aldehídos / Furanos / Mutágenos Idioma: En Revista: Chem Res Toxicol Asunto de la revista: TOXICOLOGIA Año: 2000 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos