Your browser doesn't support javascript.
loading
An essential intermediate in the folding of dihydrofolate reductase.
Heidary, D K; O'Neill, J C; Roy, M; Jennings, P A.
Afiliación
  • Heidary DK; Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0359, USA.
Proc Natl Acad Sci U S A ; 97(11): 5866-70, 2000 May 23.
Article en En | MEDLINE | ID: mdl-10811909
The folding of Escherichia coli dihydrofolate reductase was examined at pH 7.8 and 15 degrees C by using stopped-flow fluorescence and absorbance spectroscopies. The formation of a highly fluorescent intermediate occurs with relaxation times ranging between 142 and 343 msec, whereas stopped-flow absorbance spectroscopy using methotrexate binding assays shows a distinct lag phase during these time frames for the native state. The lag in absorbance kinetics and the lack of fast-track folding events indicate that the formation of this ensemble of intermediates is an obligatory step in the folding reaction.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Tetrahidrofolato Deshidrogenasa / Proteínas Bacterianas Idioma: En Revista: Proc Natl Acad Sci U S A Año: 2000 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Tetrahidrofolato Deshidrogenasa / Proteínas Bacterianas Idioma: En Revista: Proc Natl Acad Sci U S A Año: 2000 Tipo del documento: Article País de afiliación: Estados Unidos Pais de publicación: Estados Unidos