Unmasking the 6,7,5-tricarbocyclic frame of
J Org Chem
; 65(8): 2528-31, 2000 Apr 21.
Article
en En
| MEDLINE
| ID: mdl-10789466
Opening of the bridging ether of 8-oxabicyclo[3.2.1]oct-6-ene systems 1,7-fused to a five-membered carbocycle that bears a double bond conjugated to that of the oxabicycle can be induced at low temperaure by the addition of an organolithium reagent. If this double bond is unsubstituted, the opening occurs via an anti-1,6-addition pathway, and if substituted it takes place by means of a more classical syn SN2' addition.
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01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Año:
2000
Tipo del documento:
Article
País de afiliación:
España
Pais de publicación:
Estados Unidos