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1.
Food Chem ; 462: 141017, 2025 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-39216379

RESUMO

The Atlantic salmon is an extremely popular fish for its nutritional value and unique taste among several fish species. Researchers are focusing on the utilization of Atlantic salmon waste for generating protein hydrolysates rich in peptides and amino acids and investigating their health benefits. Several technological approaches, including enzymatic, chemical, and the recently developed subcritical water hydrolysis, are currently used for the production of Atlantic salmon waste protein hydrolysates. Hydrolyzing various wastes, e.g., heads, bones, skin, viscera, and trimmings, possessing antioxidant, blood pressure regulatory, antidiabetic, and anti-inflammatory properties, resulting in applications in human foods and nutraceuticals, animal farming, pharmaceuticals, cell culture, and cosmetics industries. Furthermore, future applications, constraints several challenges associated with industrial hydrolysate production, including sensory, safety, and economic constraints, which could be overcome by suggested techno processing measures. Further studies are recommended for developing large-scale, commercially viable production methods, focusing on eradicating sensory constraints and facilitating large-scale application.


Assuntos
Proteínas de Peixes , Hidrolisados de Proteína , Salmo salar , Animais , Salmo salar/metabolismo , Hidrolisados de Proteína/química , Proteínas de Peixes/química , Proteínas de Peixes/metabolismo , Humanos , Hidrólise , Resíduos/análise
2.
Food Chem ; 462: 141000, 2025 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-39241686

RESUMO

Food waste, accounting for about one-third of the total global food resources wasted each year, is a substantial challenge to global sustainability, contributing to adverse environmental impacts. The utilization of food waste as a valuable source for bioactive extraction can be facilitated through the application of DES (Deep Eutectic Solvents). Acknowledging the significant need to tackle this issue, the United Nations integrated food waste management into its Sustainable Development Goals, hence, the present review explores the role of DES in bioactive compounds extraction from food waste. Various extraction processes using the DES system are thoroughly studied and the application of bioactive components as antioxidants, antimicrobials, flavourings, nutraceuticals, functional ingredients, additives, and preservatives is investigated. Most importantly, regulatory considerations and safety aspects of DES in food applications are discussed in-depth along with consumer perception and acceptance of DES in the food sector. The key hypothesis of the review is to evaluate emerging DES systems for their efficiency in bioactive extraction technologies and various food applications. Overall, this review provides a comprehensive understanding of utilizing DES for synthesizing valuable food waste-derived bioactive components, offering a sustainable approach to waste management and the development of high-value products.


Assuntos
Solventes Eutéticos Profundos , Desenvolvimento Sustentável , Solventes Eutéticos Profundos/química , Resíduos/análise , Gerenciamento de Resíduos/métodos , Humanos , Antioxidantes/química , Antioxidantes/isolamento & purificação , Perda e Desperdício de Alimentos
3.
Food Chem ; 462: 140925, 2025 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-39190981

RESUMO

Grape pomace (GP) and pecan shell (PS) are two by-products rich in phenolic compounds (PC), and dietary fiber (DF) that may be considered for the development of functional baked foods. In this study, four formulations with different GP:PS ratios (F1(8%:5%), F2(5%:5%), F3(5%:2%), F4(0%:5%), and control bread (CB)) were elaborated and characterized (physiochemical and phytochemical content). Also, their inner structure (SEM), changes in their FTIR functional group's vibrations, and the bioaccessibility of PC and sugars, including an in vitro glycemic index, were analyzed. Results showed that all GP:PS formulations had higher mineral, protein, DF (total, soluble, and insoluble), and PC content than CB. Additionally, PC and non-starch polysaccharides affected gluten and starch absorbance and pores distribution. In vitro digestion model showed a reduction in the glycemic index for all formulations, compared to CB. These findings highlight the possible health benefits of by-products and their interactions in baked goods.


Assuntos
Pão , Fibras na Dieta , Índice Glicêmico , Fenóis , Vitis , Fibras na Dieta/análise , Fibras na Dieta/metabolismo , Pão/análise , Vitis/química , Fenóis/química , Fenóis/metabolismo , Humanos , Digestão , Alimentos Fortificados/análise , Resíduos/análise
4.
Sci Total Environ ; 952: 175938, 2024 Nov 20.
Artigo em Inglês | MEDLINE | ID: mdl-39218118

RESUMO

Seabirds have become biovectors of plastic pollutants between marine and terrestrial ecosystems, and transport of plastics to their nesting sites becomes relevant due to increasing levels of pollution. To determine the pathways by which plastic reaches their colonies, we analysed the abundance of plastics at the nesting sites of five seabird species (Humboldt penguin Spheniscus humboldti, Peruvian booby Sula variegata, kelp gull Larus dominicanus, grey gull Leucophaeus modestus, Markham's storm-petrel Hydrobates markhami) nesting in northern Chile. Seabirds were primarily grouped according to their nesting behaviour, but two species foraging in contrasting habitats (kelp gull and Markham's storm-petrel) were also compared directly. The abundance, type, and polymer of macro-, meso- and microplastics were analysed in the soil of colonies and control sites, and microplastic ingestion was evaluated for selected species. Densities of plastics in colonies of surface-nesting seabirds ranged from 0 to 21.4 items m-2 (mainly plastic bags and thin films), and 0.002 to 19.7 items m-2 (mainly hard fragments) in colonies of burrow-nesting seabirds. Mean microplastic loads in the stomachs of seabirds were between 3.7 ± 4.2 plastic items individual-1. Overall, the abundances of plastic items in all seabird colonies were low, suggesting a limited transfer of plastics from sea to land. For kelp gulls, the results indicate transfer of macroplastic items to colonies, reaching the colony via regurgitates, with landfills considered as the main plastic source. Our results suggest that contrasting nesting behaviour and foraging habitats among species can explain differential plastic accumulation in seabird colonies, but also other factors, such as wind, contribute to the accumulation of plastic debris in colonies. Proper management of sanitary landfills are key to reduce plastic contamination of coastal seabirds and their colonies.


Assuntos
Aves , Ecossistema , Monitoramento Ambiental , Plásticos , Animais , Plásticos/análise , Chile , Charadriiformes/fisiologia , Resíduos/análise , Poluentes Químicos da Água/análise , Microplásticos/análise
5.
Mar Pollut Bull ; 207: 116911, 2024 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-39241369

RESUMO

The accumulation of marine litter on beaches has a detrimental impact on the environment, human health, and recreational activities. A total of 116 monitoring surveys were conducted along the shore of the Kaliningrad region between 2019 and 2023. Sampling of anthropogenic and plastic litter (>0.5 cm) was carried out under various meteorological conditions on eight sandy beaches. The greatest abundance and mass of plastic marine litter (mean ± SE: 13.75 ± 8.61 items/m2 and 19.97 ± 5.92 gDW/m2, correspondingly) were observed in the aftermath of storms within beach-cast accumulation stains at the shoreline, where it was intermixed with organic debris. This is two orders of magnitude greater than the plastic litter contamination obtained using the OSPAR methodology at the same beach during fine weather (0.11 ± 0.01 items/m2, 0.33 ± 0.02 gDW/m2). The results suggest that the most effective strategy for beach cleaning is to implement it in the post-storm period.


Assuntos
Praias , Monitoramento Ambiental , Plásticos , Plásticos/análise , Praias/estatística & dados numéricos , Resíduos/análise , Areia
6.
Mar Pollut Bull ; 207: 116888, 2024 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-39243467

RESUMO

Using satellite remote sensing, we show the distribution, dominant type, and amounts of marine debris off the northeast coast of Japan after the Great East Japan Earthquake on 11 March 2011 and subsequent tsunami. Extensive marine debris was found on March 12, with the maximal amount found on March 13. The debris was found to be mainly wood (possibly lumber wood), with an estimated 1.5 million metric tons in an elongated water area of 6800 km2 (18 km E-W and 380 km N-S) near parallel to the coast between 36.75°N and 40.25°N. The amount decreased rapidly with time, with scattered debris patches captured in high-resolution satellite images up to April 6. These results provide new insights on the initial distribution of the Japanese Tsunami Marine Debris, which may be used to help find bottom deposition of debris and help refine numerical models to predict the debris trajectory and fate. SYNOPSIS: Marine debris induced by the 2011 Great East Japan Earthquake and Tsunami is found to be mainly composed of wood and possibly lumber wood from constructions, with maximum amount on 13 March 2011 distributed within a narrow band of ∼18 km near parallel to the northeast coast of Japan between 36.75°N and 40.25°N.


Assuntos
Terremotos , Monitoramento Ambiental , Tecnologia de Sensoriamento Remoto , Tsunamis , Japão , Monitoramento Ambiental/métodos , Resíduos/análise , Madeira
7.
Compr Rev Food Sci Food Saf ; 23(5): e70008, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39223761

RESUMO

Shrimp consumption is in great demand among the seafood used globally. However, this expansion has resulted in the substantial generation and disposal of shrimp shell waste. Through literature search, it has been observed that since 2020, global scholars have shown unprecedented interest in shrimp shell waste and its chitin/chitosan. However, these new insights lack corresponding and comprehensive summarization and analysis. Therefore, this article provides a detailed review of the extraction methods, applications, and the latest research developments on chitin/chitosan from shrimp shells, including micro-nano derivatives, from 2020 to the present. The results indicate that chemical extraction remains the primary technique for the extraction and preparation of chitin/chitosan from shrimp shells. With further refinement and development, adjusting parameters in the chemical extraction process or employing auxiliary techniques such as microwave and radiation enable the customization of target products with different characteristics (e.g., deacetylation degree, molecular weight, and degree of acetylation) according to specific needs. Additionally, in pursuit of environmentally friendly, efficient, and gentle extraction processes, recent research has shifted toward microbial fermentation and green solvent methods for chitin/chitosan extraction. Beyond the traditional antibacterial, film-forming, and encapsulation functionalities, research into the applications of chitosan in biomedical, food processing, new materials, water treatment, and adsorption fields is gradually deepening. Chitin/chitosan derivatives and their modified products have also been a focal point of research in recent years. However, with the rapid expansion, the future development of chitin/chitosan and its derivatives still faces challenges related to the unclear mechanism of action and the complexities associated with industrial scale-up.


Assuntos
Exoesqueleto , Quitina , Quitosana , Quitina/química , Quitosana/química , Animais , Exoesqueleto/química , Resíduos/análise , Penaeidae/química , Crustáceos/química
8.
Nature ; 633(8028): 101-108, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39232151

RESUMO

Negotiations for a global treaty on plastic pollution1 will shape future policies on plastics production, use and waste management. Its parties will benefit from a high-resolution baseline of waste flows and plastic emission sources to enable identification of pollution hotspots and their causes2. Nationally aggregated waste management data can be distributed to smaller scales to identify generalized points of plastic accumulation and source phenomena3-11. However, it is challenging to use this type of spatial allocation to assess the conditions under which emissions take place12,13. Here we develop a global macroplastic pollution emissions inventory by combining conceptual modelling of emission mechanisms with measurable activity data. We define emissions as materials that have moved from the managed or mismanaged system (controlled or contained state) to the unmanaged system (uncontrolled or uncontained state-the environment). Using machine learning and probabilistic material flow analysis, we identify emission hotspots across 50,702 municipalities worldwide from five land-based plastic waste emission sources. We estimate global plastic waste emissions at 52.1 [48.3-56.3] million metric tonnes (Mt) per year, with approximately 57% wt. and 43% wt. open burned and unburned debris, respectively. Littering is the largest emission source in the Global North, whereas uncollected waste is the dominant emissions source across the Global South. We suggest that our findings can help inform treaty negotiations and develop national and sub-national waste management action plans and source inventories.


Assuntos
Cidades , Monitoramento Ambiental , Poluição Ambiental , Internacionalidade , Microplásticos , Gerenciamento de Resíduos , Resíduos , Cidades/estatística & dados numéricos , Poluição Ambiental/análise , Mapeamento Geográfico , Cooperação Internacional , Aprendizado de Máquina , Microplásticos/análise , Gerenciamento de Resíduos/legislação & jurisprudência , Gerenciamento de Resíduos/estatística & dados numéricos , Resíduos/análise
9.
Compr Rev Food Sci Food Saf ; 23(5): e13422, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39245910

RESUMO

Food wastes can be a valuable reservoir of bioactive substances that can serve as natural preservatives in foods or as functional ingredients with potential health benefits. The antimicrobial properties of protein hydrolysates, especially antimicrobial peptides (AMPs) derived from food byproducts (FBs), have been extensively explored. These protein fragments are defined by their short length, low molecular weight, substantial content of hydrophobic and basic amino acids, and positive net charge. The intricate mechanisms by which these peptides exert their antimicrobial effects on microorganisms and pathogens have been elaborately described. This review also focuses on techniques for producing and purifying AMPs from diverse FBs, including seafood, livestock, poultry, plants, and dairy wastes. According to investigations, incorporating AMPs as additives and alternatives to chemical preservatives in food formulations and packaging materials has been pursued to enhance both consumer health and the shelf life of foods and their products. However, challenges associated with the utilization of AMPs derived from food waste depend on their interaction with the food matrix, acceptability, and commercial viability. Overall, AMPs can serve as alternative safe additives, thereby ensuring the safety and prolonging the storage duration of food products based on specific regulatory approvals as recommended by the respective safety authorities.


Assuntos
Peptídeos Antimicrobianos , Peptídeos Antimicrobianos/química , Peptídeos Antimicrobianos/farmacologia , Animais , Resíduos/análise
10.
Environ Monit Assess ; 196(9): 777, 2024 Aug 03.
Artigo em Inglês | MEDLINE | ID: mdl-39095686

RESUMO

Efforts are ongoing to utilise agricultural waste to achieve a full resource use approach. Bambara groundnut is an important crop widely grown in the sub-Saharan Africa with potential future importance because of its resilience to thrive under heightened weather uncertainty and widespread droughts that have challenged food security. After harvesting, the edible nuts are separated from the shells which are discarded as waste. Therefore, this research is aimed at characterising the chemical composition and the structural properties of Bambara groundnut shells (BGS) in view of their potential application as a biomass for different bio-products. The chemical composition of BGS was found to be 42.4% cellulose, 27.8% hemicellulose, 13% lignin and 16.8% extractives. Proximate analysis showed a high amount of volatile matter (69.1%) and low moisture (4.4%). XRD analysis confirmed crystallinity of cellulose I polymer and FTIR analysis observed functional groups of lignocellulosic compounds. Thermal stability, maximum degradation temperature and activation energy were found to be 178.5 °C, 305.7 °C and 49.4 kJ/mol, respectively. Compared to other nutshells, BGS were found to have a relatively high amount of cellulose and crystallinity that may result in biocomposites with improved mechanical properties.


Assuntos
Biomassa , Vigna , Vigna/química , Lignina/química , Lignina/análise , Celulose/química , Celulose/análise , Resíduos/análise , Nozes/química , Biocombustíveis , Polissacarídeos
11.
Mar Pollut Bull ; 206: 116758, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39098135

RESUMO

The nearshore zone turns out to be the area with the higher concentration of plastic debris and, for this reason, it is important to know the processes that affect the transport and the fate of this type of litter. This study focuses on investigating the dynamics of various plastic types under several hydrodynamic conditions primarily induced by waves. 2D tests were carried out at the Hydraulic Laboratory of the University of Messina reproducing the main phenomena that occurred during the wave propagation on a planar beach. More than 200 different conditions were tested changing the wave characteristics, the water depth, the plastic debris characteristics (density and shape), and the roughness of the fixed bottom. In general, it can be observed that the reduction in particle displacement occurs due to: i) a decrease in wave steepness; ii) an increase in depth; iii) an increase in particle size; iv) an increase in plastic density. However, the experimental investigation shows that some plastic characteristics and bed roughness, even when hydraulically smooth, can alter these results. The experimental data analysis identified a criterion for predicting the short-term fate of plastic debris under wave action. This criterion to determine equilibrium conditions, based on an empirical relationship, takes into account the wave characteristics, the bed roughness and slope, and the weight of the debris.


Assuntos
Monitoramento Ambiental , Plásticos , Movimentos da Água , Monitoramento Ambiental/métodos , Tamanho da Partícula , Resíduos/análise , Hidrodinâmica , Poluentes Químicos da Água/análise
12.
Int J Biol Macromol ; 278(Pt 1): 134374, 2024 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-39098671

RESUMO

The consumption of animal products has witnessed a significant increase over the years, leading to a growing need for industries to adopt strict waste control measures to mitigate environmental impacts. The disposal of animal waste in landfill can result in diverse and potentially hazardous decomposition by-products. Animal by-products, derived from meat, poultry, seafood and fish industries, offer a substantial raw material source for collagen and gelatin production due to their high protein content. Collagen, being a major protein component of animal tissues, represents an abundant resource that finds application in various chemical and material industries. The demand for collagen-based products continues to grow, yet the availability of primary material remains limited and insufficient to meet projected needs. Consequently, repurposing waste materials that contain collagen provides an opportunity to meet this need while at the same time minimizing the amount of waste that is dumped. This review examines the potential to extract value from the collagen content present in animal-derived waste and by-products. It provides a systematic evaluation of different species groups and discusses various approaches for processing and fabricating repurposed collagen. This review specifically focuses on collagen-based research, encompassing an examination of its physical and chemical properties, as well as the potential for chemical modifications. We have detailed how the research and knowledge built on collagen structure and function will drive the new initiatives that will lead to the development of new products and opportunities in the future. Additionally, it highlights emerging approaches for extracting high-quality protein from waste and discusses efforts to fabricate collagen-based materials leading to the development of new and original products within the chemical, biomedical and physical science-based industries.


Assuntos
Colágeno , Resíduos , Colágeno/química , Colágeno/isolamento & purificação , Animais , Resíduos/análise
13.
Environ Pollut ; 360: 124659, 2024 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-39097262

RESUMO

The ingestion of debris by marine fauna is a growing threat to biodiversity. This study aimed to evaluate and characterize litter ingestion by odontocetes from the Western South Atlantic. Between 2018 and 2022, 154 stomachs from six species were collected from stranded individuals and incidental captures. Stomach contents were analyzed with the naked eye and items of anthropic origin found were counted and physically/chemically characterized. Generalized Linear Models were used to evaluate the influence of biological factors on the presence/absence of litter in stomachs, and for Pontoporia blainvillei only, the influence of these factors on the number of ingested items was also tested; additionally, a temporal analysis of ingestion was done for this species (1994-2022). A total of 156 items, mainly macro-sized plastics made of polypropylene, were found in 52 stomachs of four species: Tursiops spp. (FO% = 3.3%), Steno bredanensis (10.0%), Delphinus delphis (28.6%) and P. blainvillei (47.5%). The presence/absence of litter was explained only by species (χ2 = 28.29 and p < 0.001). For P. blainvillei, a threatened species in the region, the number of items was positively influenced by individual size (χ2 = 6.01 and p = 0.01) and sex (χ2 = 7.93 and p = 0.005). There was an increase in plastic ingestion by this species over the years (χ2 = 121.6 and p < 0.001) and it was estimated that 75% of P. blainvillei stomachs will contain plastic by 2040. The ingestion of litter by odontocetes from the Western South Atlantic was confirmed and the potential risks posed by this type of pollution were evidenced, especially since these species also face other anthropic pressures. These results further demonstrate the increasing threat of litter in the ocean and highlight the importance of circularity of plastics and proper waste management.


Assuntos
Espécies em Perigo de Extinção , Plásticos , Plásticos/análise , Animais , Monitoramento Ambiental/métodos , Oceano Atlântico , Feminino , Conteúdo Gastrointestinal/química , Masculino , Ingestão de Alimentos , Resíduos/análise
14.
Mar Pollut Bull ; 207: 116844, 2024 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-39163732

RESUMO

The aim of this paper is to characterize the plastic and to study a potential relationship between plastic debris characteristics and the presence of fouling biota in an Antarctic Specially Protected Area Robert Island, on the Antarctic peninsula region. A combination of lab-based sorting, advanced spectral analysis and general linear modelling was used to assess the abundance and type of plastic debris washed up on the shore. Observations recorded 730 debris items, with 85 % being plastic. Polystyrene (PS) and Polyethylene terephthalate (PET) were the dominant plastics (61 %). Biofouling was observed on 25 % of plastic debris, with debris complexity and degradation significantly increasing the likelihood of fouling occurring. There was no correlation found between biofouling type and plastic polymer type. Findings raise concerns that even with the highest level of environmental protection, an external marine-based source of pollution can intrude the coastal habitat, with uncertain consequences to local flora and fauna.


Assuntos
Incrustação Biológica , Monitoramento Ambiental , Plásticos , Regiões Antárticas , Plásticos/análise , Polietilenotereftalatos , Resíduos/análise , Ecossistema
15.
Int J Biol Macromol ; 278(Pt 3): 134909, 2024 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-39168220

RESUMO

Exploiting royal shrimp waste to produce value-added biocomposites offers environmental and therapeutic benefits. This study proposes biocomposites based on chitosan and bioglass, using shrimp waste as the chitosan source. Chitin extraction and chitosan preparation were characterized using various analytical techniques. The waste composition revealed 24 % chitin, convertible to chitosan, with shells containing 77.33-ppm calcium. (X-ray diffraction) XRD analysis showed crystallinity index of 54.71 % for chitin and 49.14 % for chitosan. Thermal analysis indicated degradation rates of 326 °C and 322 °C, respectively. The degree of deacetylation of chitosan was 97.08 % determined by proton nuclear magnetic resonance (1H-NMR) analysis, with an intrinsic viscosity of 498 mL.g-1 and molar mass of 101,720 g/mol, showing improved solubility in 0.3 % acetic acid. Royal chitosan (CHR) was combined with bioglass (BG) via freeze-drying to create a CHR/BG biocomposite for bone surgery applications. The bioactivity of the CHR/BG was tested in simulated body fluid (SBF), revealing a biologically active apatite layer on its surface. Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) analysis confirmed enhanced bioactivity of the CHR/BG compared to commercial chitosan. The CHR/BG biocomposite demonstrated excellent apatite formation, validated by Scanning Electron Microscopy (SEM), highlighting its potential in bone surgery.


Assuntos
Cerâmica , Quitosana , Quitosana/química , Cerâmica/química , Animais , Materiais Biocompatíveis/química , Resíduos/análise , Difração de Raios X , Solubilidade , Viscosidade
16.
Spectrochim Acta A Mol Biomol Spectrosc ; 323: 124919, 2024 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-39111033

RESUMO

Lignocellulosic bioplastics were produced using four different green wastes: hemp, parsley stem, pineapple leaves and walnut shell. Two different solutions were used to dissolve the green wastes: trifluoroacetic acid (TFA) and pure water. The changes in their natural structures and the solvent effect during the regeneration in biofilm formation were investigated by using Synchrotron FTIR Microspectroscopy (SR-µFTIR). The presence of cellulose, hemicellulose and lignin components in the water-based biofilms was confirmed. After dissolving in TFA, the spectra demonstrated some additional bands especially in the hemicellulose region. This is due to the hydrolysis of ester bonds and conversion to carboxylic acids. Principal component analysis showed grouping due to different solvents and polymer addition. Hemp-PVA (Polyvinyl Alcohol) composite biofilms were obtained by adding polyvinyl alcohol to the hemp solution to give extra strength to the hemp biofilms. It has been shown that water-based hemp-PVA biofilms do not cause any significant spectral changes, comparing with pure hemp and PVA spectra. However, after dissolving in TFA, unlike water-based biofilms, it appears that TFA molecules are retained by PVA through hydrogen bonds of TFA's carboxylic acid and hydroxyl groups and distinct spectral regions belong to TFA bands are clearly identified.


Assuntos
Plásticos , Síncrotrons , Espectroscopia de Infravermelho com Transformada de Fourier/métodos , Plásticos/química , Cannabis/química , Resíduos/análise , Lignina/química , Biofilmes/efeitos dos fármacos , Análise de Componente Principal , Álcool de Polivinil/química , Celulose/química , Polissacarídeos
17.
J Agric Food Chem ; 72(34): 19051-19060, 2024 Aug 28.
Artigo em Inglês | MEDLINE | ID: mdl-39155698

RESUMO

Walnut shells, often discarded as waste, hold hidden potential as a source of ellagitannins (ETs), compounds known for their promising antioxidant properties and health benefits. This study employed reversed-phase liquid chromatography (RPLC) coupled with Orbitrap-based high-resolution mass spectrometry (HRMS) via electrospray ionization (ESI) in negative polarity to investigate the ET profile in extracts of dried powdered walnut shells. Several compounds belonging to various ET families were successfully identified as deprotonated molecules ([M - H]-) and characterized, including mono-, di-, tri-, tetra-, and pentagalloyl glucopyranoses, as well as ETs containing the hexahydroxydiphenoyl (HHDP) group. Characteristic product ions were identified in HR tandem MS spectra and employed to recognize the ET landscape. Analysis revealed a complex picture with more than 10 isomers identified in some cases. However, the structural similarity and limitations in MS/MS data hindered the definitive identification of all isomers. Characterization of ETs featuring HHDP groups also remained challenging. Despite these restraints, the estimated total content of ETs suggests potential application in the food, pharmaceutical, and cosmetic industries of those extracts. These findings indicate that walnut shells can be considered a sustainable source of health-promoting compounds, contributing to a greener economy.


Assuntos
Taninos Hidrolisáveis , Juglans , Nozes , Extratos Vegetais , Espectrometria de Massas em Tandem , Taninos Hidrolisáveis/química , Taninos Hidrolisáveis/análise , Juglans/química , Espectrometria de Massas em Tandem/métodos , Extratos Vegetais/química , Nozes/química , Cromatografia Líquida de Alta Pressão/métodos , Cromatografia Líquida/métodos , Resíduos/análise , Estrutura Molecular
18.
Luminescence ; 39(8): e4830, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-39129381

RESUMO

Fabricating metal oxide nanoparticles has garnered much attention lately because creating safe chemicals, sustainable materials, economic processes, and renewable resources is becoming increasingly important. This research shows how TiO2 nanoparticles (NPs) could be generated in an ecologically responsible way using waste coconut husk with the help of tender coconut. This extract functions as both a reducing agent and a sealing agent. The investigation of TiO2 NPs exploited ultraviolet (UV), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and field-emission scanning electron microscopy (FE-SEM) with energy-dispersive X-ray (EDX) methods. The germicidal properties of TiO2 NPs against food-borne pathogenic strains were studied using the agar well method. Employing Congo red pigment, the photodecomposition behavior was investigated. The TiO2 NPs produced had a crystallite size measuring 16.2 nm. The average grain size of the sample, as measured by FE-SEM inspection, falls within the range of 15 to 25 nm. Impressive anti-germ effects against food-borne germs like Gram-positive (Staphylococcus aureus and Listeria monocytogenes), Gram-negative (Salmonella typhimurium and Escherichia coli) bacteria, and fungi (Candida albicans and Aspergillus niger) have been proved by the sustainable fabrication of TiO2 NPs. The catalytic effectiveness of Congo red decreased by 88% after 90 min. The findings suggest that sustainable synthesis of TiO2 NPs is an effective tool for food-borne germicides and photodecomposition behaviors.


Assuntos
Cocos , Titânio , Titânio/química , Titânio/farmacologia , Cocos/química , Resíduos/análise , Nanopartículas Metálicas/química , Luminescência , Microbiologia de Alimentos , Antibacterianos/farmacologia , Antibacterianos/química , Antibacterianos/síntese química , Testes de Sensibilidade Microbiana , Processos Fotoquímicos , Tamanho da Partícula
19.
Nutrients ; 16(16)2024 Aug 18.
Artigo em Inglês | MEDLINE | ID: mdl-39203893

RESUMO

Fruit pomace, a by-product of the fruit industry, includes the skins, seeds, and pulp most commonly left behind after juice extraction. It is produced in large quantities: apple residues alone generate approximately 4 million tons of waste annually, which is a serious problem for the processing industry but also creates opportunities for various applications. Due to, among other properties, their high content of dietary fiber and polyphenolic compounds, fruit residues are used to design food with functional features, improving the nutritional value and health-promoting, technological, and sensory properties of food products. This article presents the health-promoting (antioxidant, antidiabetic, anti-inflammatory, and antibacterial) properties of fruit pomace. Moreover, the possibilities of their use in the food industry are characterized, with particular emphasis on bread, sweet snack products, and extruded snacks. Attention is paid to the impact of waste products from the fruit industry on the nutritional value and technological and sensory characteristics of these products. Fruit pomace is a valuable by-product whose use in the food industry can provide a sustainable solution for waste management and contribute to the development of functional food products with targeted health-promoting properties.


Assuntos
Indústria Alimentícia , Frutas , Valor Nutritivo , Frutas/química , Humanos , Alimento Funcional , Antioxidantes/análise , Resíduos/análise , Promoção da Saúde/métodos , Fibras na Dieta/análise , Anti-Inflamatórios , Hipoglicemiantes , Polifenóis/análise , Malus/química , Antibacterianos , Lanches
20.
Sci Total Environ ; 949: 175171, 2024 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-39094648

RESUMO

Plastic pollution has become a global concern, affecting many species around the world. While well-documented for marine ecosystems, the impact of plastic pollution on terrestrial ecosystems is comparatively limited. In fact, only recently have some studies begun to explore the occurrence, pathways, and impacts of plastic in the atmosphere and on terrestrial species. Here, we assess the presence of synthetic material in nests of three swift species breeding in the Western Palearctic: the common swift (Apus apus), the pallid swift (Apus pallidus), and the alpine swift (Tachymarptis melba). Using data from 487 nests spanning 25 colonies and seven European countries, we show that 36.5 % of the examined nests contained anthropogenic materials, mainly plastic debris. Notably, Pallid swifts' nests, with 85 % of the total nests examined with plastic, rank among birds with the highest plastic content in nests. We also demonstrate that the probability of finding plastic in the nest increased substantially with the human footprint of the landscape. Last, we recorded four cases of swifts entangled in their own nest, a low proportion compared to other species studied previously. Our study provides compelling evidence that plastic pollution may also be considered a concern for other terrestrial species, particularly for birds with highly aerial lifestyles, such as other swifts. The correlation with the human footprint suggests that areas with higher human activity contribute more significantly. Moreover, the entanglement cases, although low, indicate a threat to bird health and welfare. To our knowledge, our study is the first to report a direct interaction between floating plastic debris in the atmosphere and any species. Understanding this interaction is key, not only due to the lack of research on the topic, but also because it highlights that plastic pollution is a multifaceted environmental issue affecting various ecosystem categories, and the broader implications of atmospheric plastic circulation on wildlife and ecosystems health.


Assuntos
Aves , Monitoramento Ambiental , Plásticos , Animais , Plásticos/análise , Comportamento de Nidação , Resíduos/análise , Poluentes Atmosféricos/análise , Ecossistema , Europa (Continente) , Poluição Ambiental/estatística & dados numéricos , Poluição do Ar/estatística & dados numéricos
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