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1.
Artigo em Inglês | MEDLINE | ID: mdl-39338139

RESUMO

BACKGROUND: Numerous risk factors have been identified as significantly influencing outdoor workers' risk for heat stress and heat-related conditions, impacting their health, well-being, and productivity. However, the specific effects of these factors on construction workers' safety, health, and well-being remain under-researched. With climate change increasing temperatures, assessing heat stress among construction workers is imperative. OBJECTIVE: To identify the barriers and facilitators influencing the safety of natural gas construction workers and evaluate an implemented heat stress intervention. METHODS: In the summer of 2023, two semi-structured interviews and six focus groups were conducted with twenty-one stakeholders at a Texas natural gas construction site. RESULTS: Key facilitators include employee preparedness, use of employer-provided resources, hydration logs, and real-time communication tools. Contrarily, the barriers include daily work schedules, access to dehydrating beverages, and generational differences with the non-implementation of mandatory rest breaks. The heat stress program was perceived as effective, surpassing recommended guidelines. CONCLUSION: To advance construction workers' safety, health, and well-being, both employee involvement and employer management are needed, along with no-cost accessible resources. Additionally, implementing a required routine rest break and comprehensive heat stress education, particularly for older workers, will significantly promote safety and safe work practices in hot environments. Note: in this study, the terms 'worker' and 'employee' are used interchangeably.


Assuntos
Indústria da Construção , Transtornos de Estresse por Calor , Gás Natural , Exposição Ocupacional , Humanos , Transtornos de Estresse por Calor/prevenção & controle , Exposição Ocupacional/prevenção & controle , Texas , Adulto , Temperatura Alta , Saúde Ocupacional , Masculino , Feminino , Pessoa de Meia-Idade , Pesquisa Qualitativa
2.
PLoS One ; 19(9): e0308097, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-39226270

RESUMO

This study investigates the relationship between consumer sentiment (CONS), inflation expectations (INEX) and international energy prices, drawing on principles from behavioral. We focus on Brent crude oil price and Henry Hub natural gas prices as key indicators of energy market dynamics. Based on the monthly data from January 2003 to March 2023, three wavelet methods are applied to examine the time-frequency linkage, while the nonlinear distributed lag model (NARDL) is used to verify the asymmetric impact of two factors on energy prices. The results highlight a substantial connection between consumer sentiment, inflation expectations and international energy prices, with the former in the short term and the latter in the medium to long term. Especially, these correlations are particularly pronounced during the financial crisis and global health emergencies, such as the COVID-19 epidemic. Furthermore, we detect short-term asymmetric effects of consumer sentiment and inflation expectations on Brent crude oil price, with the negative shocks dominating. The positive effects of these factors on oil prices contribute to observed long-term asymmetry. In contrast, inflation expectations have short-term and long-run asymmetric effects on natural gas price, and both are dominated by reverse shocks, while the impact of consumer sentiment on natural gas prices appears to be less asymmetric. This study could enrich current theories on the interaction between the international energy market and serve as a supplement to current literature.


Assuntos
COVID-19 , Comércio , Dinâmica não Linear , Humanos , Comércio/economia , COVID-19/epidemiologia , COVID-19/economia , Inflação , Petróleo/economia , Comportamento do Consumidor/estatística & dados numéricos , Comportamento do Consumidor/economia , Gás Natural/economia , Análise de Ondaletas , SARS-CoV-2
3.
J Environ Manage ; 368: 122203, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39153320

RESUMO

Existing studies that assess the impact of cooking with dirty solid fuels on human beings tend to underestimate the adverse impact on welfare. This paper aims to address this research gap by examining the happiness benefits of transitioning from solid fuel to cleaner alternatives. Using an extensive panel dataset from China, which includes 150,248 observations collected from 43,251 survey respondents interviewed between 2010 and 2018, this study employs various complementary methodologies, such as the fixed-effect model, propensity score matching, and time-varying difference-in-differences, to overcome challenges related to treatment selection bias and unobserved time-invariant heterogeneity. Further, life satisfaction approach is used to evaluate the economic benefits of cooking energy transition. Our findings indicate that switching from firewood to LPG/natural gas/gas can significantly enhance individual subjective well-being (SWB). Although the improvement brought about by electricity is slightly lower than that of LPG/natural gas/gas, it remains substantial. Notably, the positive effect is more pronounced among specific demographic groups, including females, rural residents, and low-income families. Moreover, these well-being improvements can manifest quickly and persist many years before any noticeable enhancements in physical health. This effect further amplifies over time. However, biogas shows no significant effect on SWB. These findings underscore the importance of clean fuels that contribute to increased happiness, as they are more likely to be consistently adopted. Finally, we estimate that the economic benefits of the well-being improvements resulting from the use of LPG/natural gas/gas and electricity range between $5.15 and $5.44 per day.


Assuntos
Culinária , Características da Família , Felicidade , Humanos , China , Gás Natural , Fumaça , Feminino
4.
Bioresour Technol ; 411: 131330, 2024 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-39182797

RESUMO

Biomethanation converts carbon dioxide (CO2) emissions into renewable natural gas (RNG) using mixed microbial cultures enriched with hydrogenotrophic archaea. This study examines the performance of a single methanogenic archaeon converting biogas with added hydrogen (H2) into methane (CH4) using a trickle-bed bioreactor with enhanced gas-liquid mass transport. The process in continuous operation followed the theoretical reaction of hydrogenotrophic methanogenesis (CO2 + 4 H2 â†’ CH4 + 2 H2O), producing RNG with over 99 % CH4 and more than 0.9 H2 conversion efficiency. The Monod constants of H2 uptake were experimentally determined using kinetic modelling. Also, a dimensionless parameter was used to quantify the ratio between the H2 mass transfer rate and the maximum attainable H2 consumption rate. Single-culture biomethanation averts the formation of secondary metabolites and bicarbonate buffer interferences, resulting in lower demands for H2 than mixed-culture biomethanation.


Assuntos
Biocombustíveis , Reatores Biológicos , Hidrogênio , Metano , Gás Natural , Metano/metabolismo , Biocombustíveis/microbiologia , Hidrogênio/metabolismo , Reatores Biológicos/microbiologia , Cinética , Dióxido de Carbono/metabolismo
5.
Environ Sci Pollut Res Int ; 31(38): 50595-50613, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-39102142

RESUMO

This study investigates how carbon dioxide emissions, natural gas, energy consumption, energy investment, coal and crude oil, and per capita exports affected the economic growth of the United States from 1993 to 2023 using the Vector Error Correction (VEC) model. The findings highlight the importance of exports and energy investment in driving both short- and long-term economic growth, while also highlighting interactions between carbon emissions, coal use and crude oil. It was determined that changes in natural gas and exports affected energy investment in the short term, while coal and exports affected natural gas. These results provide valuable information about the dynamics of the American economy and contribute to our understanding of the complex interactions between various factors and their effects on economic growth, offering implications for further research and policy development to promote sustainable economic development.


Assuntos
Dióxido de Carbono , Desenvolvimento Econômico , Estados Unidos , Gás Natural , Produto Interno Bruto , Investimentos em Saúde
6.
J Environ Manage ; 367: 122057, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39096727

RESUMO

This paper seeks to look into the asymmetric impacts posed by climate policy uncertainty (CPU) and investor sentiment (IS) upon the price of non-renewable energy, specifically natural gas prices, and the consumption of renewable energy, embodied in geothermal energy, biofuels, and fuel ethanol. To this end, the analysis draws on a non-linear autoregressive distributed lag (NARDL) model and wavelet coherence (WTC) technique with monthly data from January 2000 to December 2021. The NARDL results establish an asymmetric association between the variables, where negative shocks to CPU exert a greater effect on each energy variable than positive shocks, while the reverse is true for IS. Furthermore, it has been noticed that CPU and IS exhibit primarily negative correlations with the target variables over the long term, with CPU having a more pronounced effect on natural gas prices than on other forms of renewable energy consumption. Wavelet analysis also reveals that CPU leads the energy variables over the medium to long run, while IS assumes a dominant role in the short to medium run. These momentous findings underscore the importance of this study in informing energy policy formulation and environmental management, as well as optimizing investor portfolios.


Assuntos
Energia Renovável , Incerteza , Investimentos em Saúde , Gás Natural
7.
Environ Int ; 190: 108945, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-39151268

RESUMO

Vehicle exhaust is one of the major organic sources in urban areas. Old taxis equipped with failed three-way catalysts (TWCs) have been regarded as "super emitters". Compressed natural gas (CNG) is a regular substitution fuel for gasoline in taxis. The relative effect of fuel substitution and TWC failure has not been thoroughly investigated. In this work, vehicle exhausts from gasoline and CNG taxis with optimally functioning and malfunctioning TWCs are sampled by Tenax TA tubes and then analyzed by a comprehensive two-dimensional gas chromatography-mass spectrometer (GC×GC-MS). A total of 216 organics are quantified, including 80 volatile organic compounds (VOCs) and 132 intermediate volatility organic compounds (IVOCs). Failure of TWC introduces super emitters with 30 - 70 times emission factors (EFs), 60 - 112 times ozone formation potentials (OFPs), and 34 - 92 times secondary organic aerosols (SOAs) more than normal vehicles. Specifically, for the taxi with failed TWC, the total organic EF of CNG is 16 times that of gasoline, indicating that the failure of TWC exceeds the emission reduction achieved by CNG-gasoline substitution. A significant but unbalanced reduction of ozone and SOA is observed after TWC, whereas a notable "enrichment" in IVOCs was observed. Naphthalene is a typical IVOC component strongly associated with CNG-gasoline substitution and TWC failure, which is lacking in current VOC measurement. We especially emphasize that there is an urgent need to scrap vehicles with failed TWCs in order to significantly reduce air pollution.


Assuntos
Poluentes Atmosféricos , Monitoramento Ambiental , Gasolina , Gás Natural , Emissões de Veículos , Compostos Orgânicos Voláteis , Emissões de Veículos/análise , Poluentes Atmosféricos/análise , Compostos Orgânicos Voláteis/análise , Gasolina/análise , Monitoramento Ambiental/métodos , Gás Natural/análise , Catálise , Cromatografia Gasosa-Espectrometria de Massas , Ozônio/química , Ozônio/análise , Poluição do Ar/prevenção & controle , Aerossóis/análise
8.
Environ Sci Technol ; 58(35): 15539-15550, 2024 Sep 03.
Artigo em Inglês | MEDLINE | ID: mdl-39169712

RESUMO

Oil and natural gas (O&G) production and processing activities have changed markedly across the U.S. over the past several years. However, the impacts of these changes on air pollution and greenhouse gas emissions are not clear. In this study, we examine U.S. ethane (C2H6) emissions, which are primarily from O&G activities, during years 2015-2020. We use C2H6 observations made by the NOAA Global Monitoring Laboratory and partner organizations from towers and aircraft and estimate emissions from these observations by using an inverse model. We find that U.S. C2H6 emissions (4.43 ± 0.2 Tg·yr-1) are approximately three times those estimated by the EPA's 2017 National Emissions Inventory (NEI) platform (1.54 Tg·yr-1) and exhibit a very different seasonal cycle. We also find that changes in U.S. C2H6 emissions are decoupled from reported changes in production; emissions increased 6.3 ± 7.6% (0.25 ± 0.31 Tg) between 2015 and 2020 while reported C2H6 production increased by a much larger amount (78%). Our results also suggest an apparent correlation between C2H6 emissions and C2H6 spot prices, where prices could be a proxy for pressure on the infrastructure across the supply chain. Overall, these results provide insight into how U.S. C2H6 emissions are changing over time.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Monitoramento Ambiental , Etano , Poluentes Atmosféricos/análise , Etano/análise , Atmosfera/química , Estados Unidos , Gás Natural
9.
PLoS One ; 19(7): e0307109, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-39024367

RESUMO

The prevention and control of natural gas hydrates is an important link in ensuring winter production. Traditional thermodynamic inhibitors, like methanol, are commonly utilized due to their low unit costs and pricing, but they come with considerable safety issues when used on-site due to their high toxicity, flammability, and explosive potential. A cost-effective and eco-friendly hydrate inhibitor was created by combining light polyol amine with other ingredients to solve this problem. At a concentration of 30%, the product has a flash point greater than 80°C and a solidification point of -45°C. With success rates of 99% and 100%, respectively, it was used for winter casing pre-injection anti-freezing operations and balancing tank defoamer anti-freezing operations. Experiments have demonstrated the effectiveness of this inhibitor in preventing the formation of natural gas hydrates. In wintertime on-site anti-freezing activities, the projected cost can be substituted for methanol, as it is essentially equivalent to methanol.


Assuntos
Gás Natural , Água/química , Estações do Ano , Termodinâmica
10.
Environ Sci Pollut Res Int ; 31(33): 45970-46001, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38981964

RESUMO

Natural gas hydrate (NGH) is a significant alternative energy resource in achieving carbon neutrality. The developmental trend and competitive landscape of NGH exploitation and production are crucial for policymakers in government, managers of enterprises, and researchers. This study introduces a novel framework for conducting an in-depth analysis of NGH, integrating patentometrics, technology evolution, and correlation relationships to monitor developmental trends and competitive landscape through patent analysis. The results indicate that China, the USA, and Japan have distinct technology advantages. Current technological developments in the NGH field focus primarily on extraction technologies, equipment, and processing systems. The co-opetition analysis among countries reveals that the most extensive international cooperation network is primarily in Europe and the USA, with national partnerships in Asia concentrated in China and Japan. Institutional cooperation remains limited, primarily within universities in China, while both the USA and Japan foster collaboration between enterprises. The competitive landscapes of key NGH-related technologies among countries and institutions are also examined. This study contributes not only to monitoring the developmental trend and competitive landscape in NGH but also to providing policy recommendations for government and enterprises regarding strategic management and collaborative innovation.


Assuntos
Gás Natural , China , Japão , Estados Unidos , Patentes como Assunto
11.
Annu Rev Chem Biomol Eng ; 15(1): 63-80, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-39047722

RESUMO

Hydrogen is similar to natural gas in terms of its physical and chemical properties but does not release carbon dioxide when burnt. This makes hydrogen an energy carrier of great importance in climate policy, especially as an enabler of increasing integration of volatile renewable energy, progressive electrification, and effective emission reductions in the hard-to-decarbonize sectors. Leaving aside the problems of transporting hydrogen as a liquid, technological challenges along the entire supply chain can be considered as solved in principle, as shown in the experimental findings of the Hydrogen Innovation Program of the German Technical and Scientific Association for Gas and Water. By scaling up production and end-use capacities and, most importantly, producing hydrogen in regions with abundant renewable energy, hydrogen and its applications can displace natural gas at affordable prices in the medium term. However, this substitution will take place at different rates in different regions and with different levels of added value, all of which must be understood for hydrogen uptake to be successful.


Assuntos
Hidrogênio , Gás Natural , Hidrogênio/química , Gás Natural/análise , Energia Renovável , Dióxido de Carbono/química
12.
Reproduction ; 168(4)2024 10 01.
Artigo em Inglês | MEDLINE | ID: mdl-39074054

RESUMO

In Brief: Unconventional oil and natural gas (UOG) operations, particularly hydraulic fracturing, have revolutionized oil and gas production, using and containing complex mixtures of chemicals that may impact reproductive health. While there is growing evidence for effects on births in hydraulic fracturing/UOG regions and good mechanistic evidence for potential reproductive toxicity, there is much research still needed to make firm conclusions about these practices and reproductive health. Abstract: Unconventional oil and natural gas (UOG) operations have emerged over the last four decades to transform oil and gas production in the United States and globally by unlocking previously inaccessible hydrocarbon deposits. UOG development utilizes many compounds associated with conventional oil and gas, as well as some specific to UOG extraction, particularly during hydraulic fracturing (HF). While research is increasing on UOG chemicals and their mixtures, this review discusses the current evidence for reproductive toxicity following exposures to UOG/HF mixtures. These complex chemical mixtures have been demonstrated to interact with numerous mechanisms known to influence reproductive health. A growing number of environmental and controlled laboratory testing studies have reported adverse reproductive health effects in animals exposed to various UOG chemical mixtures. An expanding body of epidemiological literature has assessed adverse birth outcomes, although none has directly examined reproductive measures such as time to pregnancy, semen quality, and other direct measures of fertility. The existing literature provides moderate evidence for decreased birth weights, increased risk of small for gestational age and/or preterm birth, increased congenital abnormalities, and increased infant mortality, though importantly, studies are widely variable in methods used. Most studies utilized distance from UOG operations as an exposure proxy and did not measure actual chemical exposures experienced by those living near these operations. As such, while there is growing evidence for effects on births in these regions and good mechanistic evidence for potential reproductive toxicity, there is much research still needed to make firm conclusions about UOG development and reproductive health.


Assuntos
Exposição Ambiental , Fraturamento Hidráulico , Reprodução , Saúde Reprodutiva , Humanos , Reprodução/efeitos dos fármacos , Animais , Exposição Ambiental/efeitos adversos , Feminino , Gravidez , Gás Natural , Masculino
13.
J Environ Manage ; 364: 121459, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38870798

RESUMO

The current trend in the European biogas industry is to shift away from electricity production towards the production of biomethane for the need to replace natural gas. The upgrading of biogas to biomethane is normally performed by separating the biogas in a stream containing natural gas grid quality methane and a stream containing mostly CO2. The CO2 stream is normally released into the atmosphere; however, part of the methane may still remain in it, and, if not oxidized, even a small fraction of methane released may jeopardise all the GHG emissions savings from producing the biomethane, being methane a powerful climate forcer. Scope of this work is to assess the opportunity cost of installing an Off Gas Combustion (OGC) device in biomethane upgrading plants. The currently available technologies for biogas upgrading to biomethane and the most common technology of OGC (the Regenerative Thermal Oxidisers, RTO) are described according to their performances and cost. Then the cost per tonne of CO2eq avoided associated to the adoption of RTO systems in relation to the upgrading performance is calculated to identify a potential threshold for an effective and efficient application of the RTO systems. It is found that, in case of upgrading technologies which can capture almost all biomethane in the upgrading off-gas (i.e. 99.9%), currently the adoption of an RTO to oxidise the methane left in the off-gas would add costs and need additional fuel to be operated, but would generate limited GHG emission savings, therefore the cost per tonne of CO2eq emissions avoided would result not competitive with other GHG emissions mitigation investments. While the installation of RTOs on upgrading systems with a methane slip of 0.3%, or higher, normally results cost competitive in reducing GHG emissions. The installation of an RTO on systems with a methane slip of 0.2% results in a cost per tonne of CO2eq emissions avoided of 50-100 euro, which is comparable to the current cost of CO2 emissions allowances in the EU ETS carbon market, representing therefore a reasonable choice for a threshold on methane slip regulation for biogas upgrading systems.


Assuntos
Biocombustíveis , Dióxido de Carbono , Gases de Efeito Estufa , Metano , Gases de Efeito Estufa/análise , Dióxido de Carbono/análise , Efeito Estufa , Gás Natural
14.
Environ Sci Technol ; 58(27): 12018-12027, 2024 Jul 09.
Artigo em Inglês | MEDLINE | ID: mdl-38875010

RESUMO

The timely detection of underground natural gas (NG) leaks in pipeline transmission systems presents a promising opportunity for reducing the potential greenhouse gas (GHG) emission. However, existing techniques face notable limitations for prompt detection. This study explores the utility of Vegetation Indicators (VIs) to reflect vegetation health deterioration, thereby representing leak-induced stress. Despite the acknowledged potential of VIs, their sensitivity and separability remain understudied. In this study, we employed ground vegetation as biosensors for detecting methane emissions from underground pipelines. Hyperspectral imaging from vegetation was collected weekly at both plant and leaf scales over two months to facilitate stress detection using VIs and Deep Neural Networks (DNNs). Our findings revealed that plant pigment-related VIs, modified chlorophyll absorption reflectance index (MCARI), exhibit commendable sensitivity but limited separability in discerning stressed grasses. A NG-specialized VI, the optimized soil-adjusted vegetation index (OSAVI), demonstrates higher sensitivity and separability in early detection of methane leaks. Notably, the OSAVI proved capable of discriminating vegetation stress 21 days after methane exposure initiation. DNNs identified the methane leaks following a 3-week methane treatment with an accuracy of 98.2%. DNN results indicated an increase in visible (VIS) and a decrease in near-infrared (NIR) in spectra due to methane exposure.


Assuntos
Gás Natural , Redes Neurais de Computação , Monitoramento Ambiental/métodos , Imageamento Hiperespectral , Metano/análise
15.
Environ Sci Pollut Res Int ; 31(29): 42160-42173, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38861060

RESUMO

The world faces several problems related to natural gas resource rents and energy production from renewable sources. One of the main problems is the influence of energy imports, manufacturing exports, and alternative energy sources on natural gas and electricity production from renewable sources. Energy imports, manufacturing exports, and alternative energy sources can impact natural gas and electricity production. This paper examines natural gas resource rents and electricity production from renewable sources nexus from 1971 to 2021, using energy imports, manufacturer's exports, and alternative energy sources in China. Electricity production from renewable sources and manufacturing exports are negatively associated with natural gas resource rents. Energy imports and alternative energy sources positively relate to natural gas resource rents in China. These results suggest that the energy sector in China is highly interconnected and that policies that seek to promote renewable energy sources and other alternatives can positively affect natural gas resource rents. China needs to develop an energy policy considering the policy implications of energy imports and natural gas resource rents. Such a policy should focus on increasing domestic production, reducing energy imports, and ensuring adequate revenue from natural gas resource rents. Additionally, regulations could be implemented that support the development of alternative energy sources, such as requiring utilities to purchase a certain percentage of their power from renewable sources.


Assuntos
Eletricidade , Gás Natural , Energia Renovável , China , Energia Nuclear
16.
Sci Total Environ ; 945: 174080, 2024 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-38906281

RESUMO

Reverse osmosis (RO) plays a pivotal role in shale gas wastewater resource utilization. However, managing the reverse osmosis concentrate (ROC) characterized by high salinity and increased concentrations of organic matter is challenging. In this study, we aimed to elucidate the enhancement effects and mechanisms of pre-ozonation on organic matter removal efficacy in ROC using a biological activated carbon (BAC) system. Our findings revealed that during the stable operation phase, the ozonation (O3 and O3/granular activated carbon)-BAC system removes 43.6-72.2 % of dissolved organic carbon, achieving a 4-7 fold increase in efficiency compared with that in the BAC system alone. Through dynamic analysis of influent and effluent water quality, biofilm performance, and microbial community structure, succession, and function prediction, we elucidated the following primary enhancement mechanisms: 1) pre-ozonation significantly enhances the biodegradability of ROC by 4.5-6 times and diminishes the organic load on the BAC system; 2) pre-ozonation facilitates the selective enrichment of microbes capable of degrading organic compounds in the BAC system, thereby enhancing the biodegradation capacity and stability of the microbial community; and 3) pre-ozonation accelerates the regeneration rate of the granular activated carbon adsorption sites. Collectively, our findings provide valuable insights into treating ROC through pre-oxidation combined with biotreatment.


Assuntos
Carvão Vegetal , Osmose , Ozônio , Eliminação de Resíduos Líquidos , Águas Residuárias , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias/química , Carvão Vegetal/química , Biodegradação Ambiental , Poluentes Químicos da Água/análise , Gás Natural
17.
Sci Rep ; 14(1): 11996, 2024 05 25.
Artigo em Inglês | MEDLINE | ID: mdl-38796638

RESUMO

Different from the Qaidam basin with about 320 billion m3 microbial gas, only limited microbial gases were found from the Junggar basin with similarly abundant type III kerogen. To determine whether microbial gases have not yet identified, natural gas samples from the Carboniferous to Cretaceous in the Junggar basin have been analyzed for chemical and stable isotope compositions. The results reveal some of the gases from the Mahu sag, Zhongguai, Luliang and Wu-Xia areas in the basin may have mixed with microbial gas leading to straight ethane to butane trends with a "dogleg" light methane in the Chung's plot. Primary microbial gas from degradation of immature sedimentary organic matter is found to occur in the Mahu sag and secondary microbial gas from biodegradation of oils and propane occurred in the Zhongguai, Luliang and Beisantai areas where the associated oils were biodegraded to produce calcites with δ13C values from + 22.10‰ to + 22.16‰ or propane was biodegraded leading to its 13C enrichment. Microbial CH4 in the Mahu sag is most likely to have migrated up from the Lower Wuerhe Formation coal-bearing strata by the end of the Triassic, and secondary microbial gas in Zhongguai and Beisantan uplifts may have generated after the reservoirs were uplifted during the period of the Middle and Late Jurassic. This study suggests widespread distribution of microbial gas and shows the potential to find large microbial gas accumulation in the basin.


Assuntos
Metano , Gás Natural , Metano/análise , Metano/metabolismo , Gás Natural/análise , Gases/metabolismo , Gases/análise , China , Sedimentos Geológicos/microbiologia , Sedimentos Geológicos/química , Sedimentos Geológicos/análise , Isótopos de Carbono/análise
18.
Chemosphere ; 359: 142259, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38723692

RESUMO

6-Methylquinoline (6-MQ) is identified as a high-concentration organic compound pervasive in shale gas wastewater (SGW) and poses a significant risk of environmental pollution. In response, this study aimed to address these challenges by introducing an innovative electrochemical membrane constructed with multi-walled carbon nanotubes (CNTs) for the removal of 6-MQ. The investigation systematically explored the impact of voltage, initial pollutant concentration, and salinity on the performance of the electrochemical CNTs filter. It was found a positive correlation between removal efficiency and increasing voltage and salinity levels. Conversely, as the initial concentration of pollutants increased, the efficiency showed a diminishing trend. The electrochemical CNTs filter exhibited remarkable efficacy in both adsorption removal and electrochemical oxidation of 6-MQ. Notably, the CNTs membrane exhibited robust adsorption capabilities, evidenced by the sustained adsorption of 6-MQ for over 33 h. Furthermore, applying an electrochemical oxidation voltage of 3 V consistently maintained a removal rate exceeding 34.0% due to both direct and indirect oxidation, underscoring the sustained efficacy of the electrochemical membranes. Besides, real wastewater experiments, while displaying a reduction in removal efficiency compared to synthetic wastewater experiments, emphasized the substantial potential of the electrochemical CNTs filter for practical applications. This study underscores the significant promise of electrochemical membranes in addressing low molecular weight contaminants in SGW, contributing valuable insights for advancing SGW treatment strategies.


Assuntos
Nanotubos de Carbono , Quinolinas , Águas Residuárias , Poluentes Químicos da Água , Nanotubos de Carbono/química , Águas Residuárias/química , Adsorção , Poluentes Químicos da Água/química , Poluentes Químicos da Água/análise , Quinolinas/química , Técnicas Eletroquímicas/métodos , Gás Natural , Filtração/métodos , Oxirredução , Eliminação de Resíduos Líquidos/métodos
19.
J Environ Manage ; 360: 121091, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38761617

RESUMO

In an exploration of environmental concerns, this groundbreaking research delves into the relationship between GDP per capita, coal rents, forest rents, mineral rents, oil rents, natural gas rents, fossil fuels, renewables, environmental tax and environment-related technologies on CO2 emissions in 30 highly emitting countries from 1995 to 2021 using instrumental-variables regression Two-Stage least squares (IV-2SLS) regression and two-step system generalized method of moments (GMM) estimates. Our results indicate a significant positive relationship between economic growth and CO2 emissions across all quantiles, showcasing an EKC with diminishing marginal effects. Coal rents exhibit a statistically significant negative relationship with emissions, particularly in higher quantiles, and mineral rents show a negative association with CO2 emissions in lower and middle quantiles, reinforcing the idea of resource management in emissions reduction. Fossil fuels exert a considerable adverse impact on emissions, with a rising effect in progressive quantiles. Conversely, renewable energy significantly curtails CO2 emissions, with higher impacts in lower quantiles. Environmental tax also mitigates CO2 emissions. Environment-related technologies play a pivotal role in emission reduction, particularly in lower and middle quantiles, emphasizing the need for innovative solutions. These findings provide valuable insights for policymakers, highlighting the importance of tailoring interventions to different emission levels and leveraging diverse strategies for sustainable development.


Assuntos
Dióxido de Carbono , Desenvolvimento Econômico , Dióxido de Carbono/análise , Combustíveis Fósseis , Conservação dos Recursos Naturais , Gás Natural
20.
Nature ; 629(8011): 295-306, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38720037

RESUMO

Fossil fuels-coal, oil and gas-supply most of the world's energy and also form the basis of many products essential for everyday life. Their use is the largest contributor to the carbon dioxide emissions that drive global climate change, prompting joint efforts to find renewable alternatives that might enable a carbon-neutral society by as early as 2050. There are clear paths for renewable electricity to replace fossil-fuel-based energy, but the transport fuels and chemicals produced in oil refineries will still be needed. We can attempt to close the carbon cycle associated with their use by electrifying refinery processes and by changing the raw materials that go into a refinery from fossils fuels to carbon dioxide for making hydrocarbon fuels and to agricultural and municipal waste for making chemicals and polymers. We argue that, with sufficient long-term commitment and support, the science and technology for such a completely fossil-free refinery, delivering the products required after 2050 (less fuels, more chemicals), could be developed. This future refinery will require substantially larger areas and greater mineral resources than is the case at present and critically depends on the capacity to generate large amounts of renewable energy for hydrogen production and carbon dioxide capture.


Assuntos
Dióxido de Carbono , Combustíveis Fósseis , Indústria de Petróleo e Gás , Energia Renovável , Ciclo do Carbono , Dióxido de Carbono/efeitos adversos , Dióxido de Carbono/isolamento & purificação , Carvão Mineral/efeitos adversos , Carvão Mineral/provisão & distribuição , Combustíveis Fósseis/efeitos adversos , Combustíveis Fósseis/provisão & distribuição , Hidrogênio/química , Gás Natural/efeitos adversos , Gás Natural/provisão & distribuição , Petróleo/efeitos adversos , Petróleo/provisão & distribuição , Energia Renovável/estatística & dados numéricos , Indústria de Petróleo e Gás/métodos , Indústria de Petróleo e Gás/tendências
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