RESUMO
Some mononitrosyl complexes of transition metals exhibit one or two metastable states (linkage isomers, MS1 and MS2) when irradiated at low temperatures with appropriate wavelengths. In this work, the generation of metastable state one (MS1) (or Ru-ON linkage isomer) in K2[RuF5NO].H2O at 77 K was studied by sample excitation using laser light in a wide range of wavelengths. The effects of irradiation was monitored by infrared spectroscopy. ν(NO) in the ground state was shifted by -161 cm-1 when the complex was excited to MS1, a magnitude similar to that observed in other transition metal nitrosyls for a such state. We report on the excitation and deactivation of metastable states by using a wide variety of laser lines. A novel method for exploring the electronic structure of [RuF5NO]2- through the generation of MS1 is proposed. For this purpose, a sample was carefully irradiated with the same intensity of light for all laser lines in the spectral region 260-1064 nm. The integrated area under the ν(NO)MS1 band was used as a measure of MS1 population. The profile peaks of the MS1 population (ν(NO)MS1 band area) vs. the irradiation wavelength fit well with those of the electronic spectrum of the [RuF5NO]2- ion in an aqueous solution. The onset temperature for MS1 decay in K2[RuF5NO].H2O, at approximately 180 K, is slightly lower than the average reported for other ruthenium-nitrosyl systems.
RESUMO
This work analyzes the magnetic configurations of cylindrical nanowires with a bulk Dzyaloshinskii-Moriya interaction and easy-plane anisotropy. We show that this system allows the nucleation of a metastable toron chain even when no out-of-plane anisotropy exists in the nanowire's top and bottom surfaces, as usually required. The number of nucleated torons depends on the nanowire length and the strength of an external magnetic field applied to the system. The size of each toron depends on the fundamental magnetic interactions and can be controlled by external stimuli, allowing the use of these magnetic textures as information carriers or nano-oscillator elements. Our results evidence that the topology and structure of the torons yield a wide variety of behaviors, revealing the complex nature of these topological textures, which should present an exciting interaction dynamic, depending on the initial conditions.