RESUMO

This study aimed to verify the effects of 4 weeks of high-intensity interval training (HIIT), heavy (HRT) and explosive (ERT) resistance training on aerobic, anaerobic and neuromuscular parameters and performance of well-trained runners. Twenty-six male athletes were divided into HIIT (n = 10), HRT (n = 7) and ERT (n = 9) groups. Maximal oxygen uptake (VO2max) and the corresponding velocity (vVO2max), anaerobic threshold (AT), running economy (RE), oxygen uptake kinetics, lower-body strength (1RM) and power (CMJ), and the 1500m and 5000m time-trial (TT) were determined. Improvements were observed in vVO2max (mean difference (Δ): 2.6%; effect size (ES): 0.63) with HIIT, while AT was incresead in ERT (Δ: 4.3%; ES: 0.73) and HRT (Δ: 6.9%; ES: 0.72) groups. The CMJ performance was increased in ERT (Δ: 13.8%; ES: 1.03), HRT (Δ: 6.9%; ES: 0.55) and HIIT (Δ: 5.4%; ES: 0.34), whereas 1RM increase in HRT (Δ: 38.1%; ES: 1.21) and ERT (Δ: 49.2%; ES: 0.96) groups. HIIT improved the 1500m (Δ: -2.3%; ES: -0.62) and both HRT (Δ: -1.6%; ES: -0.32) and ERT (Δ: -1.7%; ES: -0.31) the 5000m TT. Despite performance adaptations were dependent on the training characteristics, both RT and HIIT model constitute an alternative for training periodization.

Assuntos

RESUMO

ABSTRACT Purpose: This study aimed to describe the demographic and clinical characteristics of victims of fireworkrelated ocular trauma treated at the ophthalmologic emergency de partments of two reference centers in Pernambuco, Brazil, and to identify risk factors related to poor visual prognosis. Methods: We retrospectively evaluated the medical records of patients admitted in emergency departments with a report of firework-related trauma between January 2012 and December 2018. Data collected included patient's age, sex, place of origin, month and year of the accident, ocular structures affected, characteristics of the injuries, and type of treatment that patients received. For patients who were followed for >30 days, the final visual acuity and patient's origin were analyzed. Results: Three hundred and seventy eyes from 314 patients were included, of which 248 (79.0%) were male and 160 (51.0%) were from the metropolitan region of Recife. The mean patient age was 25.6 ± 18.8 years. In 56 (17.8%) patients, the ocular trauma was bilateral. A total of 152 (48.4%) cases occurred in June. The most affected sites were the eyelids in 91 (24.6%) eyes and ocular surface in 252 (68.1%). Surgical treatment was required in 87 (23.5%) eyes. After clinical and surgical management, 37 (10.0%) eyes presented final visual acuity of <20/400. Of these, 34 (91.9%) eyes were from patients from the countryside or from another state. Patients from the countryside presented higher risk of developing blindness after a firework trauma than those from the metropolitan area (odds ratio of 5.46). Conclusions: Victims of firework-related ocular trauma were mostly male, from the metropolitan region of Pernambuco state and mainly pediatric patients or economically active. Those coming from the countryside and other states had higher risk of developing blindness

RESUMO Objetivos: Descrever as características demográficas e clínicas das vítimas de trauma ocular por fogos de artifício atendidas nas emergências oftalmológicas de dois centros de referência em Pernambuco e identificar fatores relacionados a mau prognóstico visual. Métodos: Avaliação retrospectiva dos prontuários de pacientes admitidos na emergência oftalmológica com história de trauma por fogos de artifício entre janeiro de 2012 e dezembro de 2018. A coleta de dados incluiu idade, gênero, procedência, mês e ano do acidente, estruturas oculares acometidas e características das lesões, além do tipo de tratamento a que os pacientes foram submetidos. Naqueles pacientes acompanhados por mais de 30 dias, analisou-se a acuidade visual final e a associação com sua procedência. Resultados: Foram incluídos 370 olhos de 314 pacientes. Destes, 248 (79,0%) vítimas eram do sexo masculino e 160 (51,0%) da região metropolitana do Recife, com uma média de idade de 25.6 ± 18.8 anos. Em 56 (17,8%) dos casos o trauma foi bilateral. No mês de junho ocorreu um total de 152 (48,4%) casos. Os sítios mais acometidos foram pálpebras em 91 (24,6%) olhos e superfície ocular em 252 (68,1%). O tratamento cirúrgico foi necessário em 87 (23,5%) olhos. Após manejo clínico-cirúrgico, 37 (10.0%) olhos desenvolveram visão pior do que 20/400. Destes, 34 (91,9%) olhos eram de pacientes do interior do estado de Pernambuco ou de outro estado. Os pacientes provenientes do interior do estado apresentaram maior chance de desenvolver cegueira quando comparados aos que eram provenientes da região metropolitana (Odds Ratio de 5,46). Conclusões: As vítimas de trauma ocular por fogos de artificio foram em sua maioria do sexo masculino, procedentes da região metropolitana do estado e das faixas etárias pediátrica e economicamente ativa. Aqueles provenientes do interior ou de outros estados apresentaram maior chance de desenvolver cegueira.

RESUMO

Terrorist organizations have compelled security authorities of every nation to make an increasingly significant commitment toward mitigating the risk of mass casualties and severe financial and property damages. As a result, various security measures have been implemented, including the use of advanced equipment and an uptick in intelligence activities. One of the most effective tools that has yielded outstanding results is the use of explosive detection dogs (EDDs). The nature of EDDs demands a high level of sensitivity given the inherent danger and severity of real threat situations that may involve the risk of explosion. Moreover, the operating procedures for EDDs are unique and distinguishable from other forms of detection. We conducted a review to ensure a comprehensive understanding of the subject, highlighting the EDDs' personality profile, selection, training methods, performance, and employment, incorporating insights from diverse fields, conducting an analysis, and presenting a perspective on using EDDs to prevent explosion threats.

RESUMO

Here, lab-made graphite and polylactic acid (Gpt-PLA) biocomposite materials were used to additively manufacture electrodes via the fused deposition modeling (FDM) technique for subsequent determination of the explosive 2,4,6-trinitrotoluene (TNT, considered a persistent organic pollutant). The surface of the 3D-printed material was characterized by SEM and Raman, which revealed high roughness and the presence of defects in the graphite structure, which enhanced the electrochemical response of TNT. The 3D-printed Gpt-PLA electrode coupled to square wave voltammetry (SWV) showed suitable performance for fastly determining the explosive residues (around 7 s). Two reduction processes at around -0.22 V and -0.36 V were selected for TNT detection, with linear ranges between 1.0 and 10.0 µM. Moreover, detection limits of 0.52 and 0.66 µM were achieved for both reduction steps. The proposed method was applied to determine TNT in different environmental water samples (tap water, river water, and seawater) without a dilution step (direct analysis). Recovery values between 98 and 106% confirmed the accuracy of the analyses. Additionally, adequate selectivity was achieved even in the presence of other explosives commonly used by military agencies, metallic ions commonly found in water, and also some electroactive camouflage species. Such results indicate that the proposed device is promising to quantify TNT residues in environmental samples, a viable on-site analysis strategy.

Assuntos

RESUMO

This study aimed to investigate the interindividual responses following two different concurrent training (CT) regimens in neuromuscular, cardiorespiratory and functional outcomes of older men. Thirty-five older men (65.8 ± 3.9 years) were randomly allocated into one of two CT groups: power training (PT) + high-intensity interval training (HIIT) (n = 17); or traditional strength training (TST) + HIIT (n = 18). Maximal dynamic strength (one-repetition maximum, 1RM), rate of force development at 100 milliseconds (RDF100), countermovement jump power (CMJ), quadriceps femoris muscle thickness (QF MT), functional tests (sit-to-stand, timed-up-and-go, and stair climbing), and peak oxygen consumption (VO2peak) were assessed pre-, post-8 and post-16 weeks of training. The Chi-squared test was used for assessing differences in the prevalence of responders (Rs), non-responders (NRs), and adverse responders (ARs). Similar prevalence of individual responses (Rs, NRs and ARs) between groups were observed after intervention in almost all outcomes: 1RM; power at CMJ; QF MT, and functional tests (P > 0.05). However, a significant difference in the distribution of Rs, NRs and ARs between groups was observed in the RFD100 after 16 weeks (p = 0.003), with PT + HIIT group presenting high prevalence of Rs than TST + HIIT (100 % vs. 50 %). The inclusion of explosive-type of contractions in a concurrent training regime induces greater responsiveness in the RFD100 in older men, while no differences compared to traditional strength training are observed in maximal strength, muscle size, VO2peak, and functional performance.

Assuntos

RESUMO

In the industrial production of the explosive 2,4,6-trinitrotoluene (TNT), purification steps are required to ensure the quality of the product, procedures that generate wastewater of a complex nature and with eco-toxicological potential, called red water, which consists of soluble sulfonates, TNT isomers, and other typical nitro aromatic compounds. The present work aimed to study the effects of integrating heterogeneous photocatalysis based on commercial TiO2, with a biological process, based on activated sludge, for red water treatment. For the photocatalytic treatment, a 72% reduction in the typical absorption of nitro aromatic compounds (the region between 195 - 275 nm), a 36% reduction in chemical oxygen demand (COD), and a 68% reduction in total phenols were obtained. In the biological treatment, there was a 60% reduction in absorbance in the typical nitro aromatics region (NA), 10% reduction in COD, and 36% reduction in total phenols (FT). The integration of photocatalytic and biological treatments showed promising results compared to the individual processes. Having 94% reduction in NA absorbance, 72% reduction in FT, and 89% reduction in COD with an association of photocatalytic pretreatment followed by biological, and reductions of 88% in NA absorbance, 62% in FT, and 87% in COD for a biological pretreatment followed by the photocatalytic process. In general, when comparing the chemical and biological processes, isolated and integrated, both types of integration showed significantly superior results. They were able to remove the main nitro aromatic constituents of the Red Water effluent.

Assuntos

RESUMO

Resumen. Las heridas por artefactos explosivos y las secuelas causadas por estos se han convertido en el foco de diversos estudios en el ámbito médico y psicológico, aunque en el entorno neuropsicológico son pocos los hallazgos encontrados, debido a esto la presente investigación surge con el fin de describir el perfil neuropsicológico de un grupo de militares colombianos heridos por artefactos explosivos. Participaron 60 militares colombianos heridos y se les realizó un análisis descriptivo de las funciones neuropsicológicas a partir de la batería Neuropsi Atención y Memoria. Los participantes presentaron un déficit de leve a moderado en la curva de memoria de codificación y evocación; memoria verbal espontánea, memoria por claves y en memoria lógica, igualmente, en procesos ejecutivos de organización de la conducta, capacidad de planeación e inhibición de conductas. De igual forma, se encontró una alteración de moderada a severa en atención sostenida, planificación y codificación visual. Los resultados son discutidos con la literatura existente.

Abstract. Injuries from explosive devices and the sequelae caused by them have become the focus of various studies in the medical and psychological fields, although in the neuropsychological environment there are few findings, due to this the present investigation arises in order to describe the neuropsychological profile of a group of Colombian soldiers injured by explosive devices. Sixty wounded Colombian soldiers participated and a descriptive analysis of the neuropsychological functions was carried out from the Neuropsi Attention and Memory battery. The participants had a mild to moderate deficit in the coding and recall memory curve; Spontaneous verbal memory, memory by keys and in logical memory, likewise, in executive processes of behavior organization, planning capacity and behavior inhibition. Similarly, a moderate to severe alteration was found in sustained attention, planning and visual coding. The results are discussed with the existing literature.

RESUMO

This retrospective study reports data obtained by the Federal Police's National Institute of Criminalistics (INC-PF) relating to chemical analysis aimed at identifying explosives used in Automated teller machines (ATMs)/cash safes robberies between 2014 and 2020 in Brazil. 93 Real cases were studied and, based on the analysis carried out on the materials related to these cases, focusing on the type of explosive used, the following distribution profile was obtained: I) explosive mixtures based on chlorates and/or perchlorates (53%); explosive emulsion (22%); black gunpowder (13%); negative/inconclusive (11%) and organic - pentaerythritol tetranitrate (PETN) (1%). These results can contribute to investigations related to diversion/loss of explosives for criminal purposes, indicating, for example, through relationships between prevalence in the use of a certain type of explosive with a certain location, its possible origin (mining industry, explosive industries, fireworks factories, among others). The profile observed in the results can guide the selection of explosives to be studied in future research, as the possibilities are vast. Furthermore, despite the expressive number of occurrences in Brazil in the period of interest of this study, only a small fraction of samples was sent to the forensic chemistry laboratory to identify the explosive involved, which suggests that expanding chemical analysis should be encouraged in this field. In combination with an increase in professional training and collaboration trials between the laboratories, these activities can improve the chemical explosive's profile in Brazil, enabling the search for correlations between occurrences and contributing to the growth and development of this area.

Assuntos

RESUMO

La investigación se refiere a un estudio de la rentabilidad de la acción del viraje del estilo libre en nadadoras escolares. El objetivo para la investigación se centró en evaluar las características temporales durante la acción del viraje en nadadoras de la categoría 13 y 14 años de la provincia de Sancti Spíritus. Para la recogida de la información, se utilizaron los métodos del nivel empírico: la observación científica, así como la de medición. Se utilizaron dos cámaras de videos, ubicadas en serie, y una cámara subacuática marca Sony. Para el análisis temporal, se requirió del software Kinovea, ver 0.9.3. Se aplicó el test de 15 m. para comprobar la rentabilidad del viraje. Se pudo comprobar una pobre efectividad de este elemento técnico en el estilo libre en las nadadoras evaluadas, lo que mostró, de forma generalizada, deficiencias durante la fase de impulso y se comprobó la formación de ángulos muy abiertos de las piernas que favoreció un déficit en la utilización de la potencia de las piernas durante el empuje de la pared, aspecto este que ayudó a disminuir el deslizamiento y comenzar a realizar los movimientos de salida a la superficie de forma prematura, aumentó el tiempo de forma general en la ejecución del viraje, concluyendo que para las categorías escolares es oportuno obtener ángulos entre las articulaciones de tobillos, rodillas y cadera en el rango de los 90° y 110° al momento de iniciar el impulso de la pared.

A pesquisa diz respeito a um estudo sobre a rentabilidade da ação de viragem em estilo livre em nadadores escolares. O objectivo da investigação foi centrado na avaliação das características temporárias durante a ação de viragem em nadadores de 13 e 14 anos de idade na província de Sancti Spíritus. Para a recolha de informação, foram empregues métodos empíricos: observação científica e medição. Foram instaladas duas câmaras de vídeo, colocadas em série, e uma câmara subaquática Sony. Para a análise temporal, foi utilizado o software Kinovea, ver 0.9.3. O teste de 15 m foi executado para verificar a relação custo-benefício da curva. Foi possível constatar uma baixa eficácia deste elemento técnico no estilo livre dos nadadores avaliados, que mostraram, em geral, deficiências durante a fase de impulso e a formação de ângulos de pernas muito abertos que favoreceram um défice na utilização da força das pernas durante o impulso para a parede, Este aspecto permitiu reduzir o deslizamento e começar a realizar os movimentos de saída para a superfície antecipadamente, aumentou o tempo total na execução da curva, concluindo-se que para as categorias escolares é adequado obter ângulos entre o calcanhar, o joelho e as articulações da anca na gama de 90° e 110° no momento de iniciar o impulso da parede.

The research refers to a study of the profitability of the freestyle turning action in school swimmers. The objective of the research was focused on evaluating the temporal characteristics during the action of the turn in swimmers of the 13 and 14 years old category in the province of Sancti Spíritus. For the collection of information, the empirical level methods used were: scientific observation, as well as measurement. Two video cameras, placed in series, and a Sony underwater camera were used. For the temporal analysis, the Kinovea software, ver 0.9.3, was used. The 15 m test was applied to check the profitability of the turn. It was possible to verify a poor effectiveness of this technical element in the freestyle in the swimmers evaluated, which showed, in a generalized way, deficiencies during the impulse phase and the formation of very open angles of the legs that favored a deficit in the use of the power of the legs during the wall push, This aspect helped to decrease the sliding and to begin to perform the exit movements to the surface prematurely, increased the time in general in the execution of the turn, concluding that for the school categories it is appropriate to obtain angles between the ankle, knee and hip joints in the range of 90° and 110° at the moment of initiating the wall push.

RESUMO

Cutaneous leishmaniasis is a vector-borne disease that produces growing skin ulcers. In Colombia, the transmitting phlebotomine sandfly is native to the same jungles that have been the primary theater of war. Although combatants are the most affected by leishmaniasis, military landmine detection dogs are also significantly impacted. This article draws on ethnographic field research with human and canine members of the Colombian military. While their leishmaniasis ulcers constitute a shared expression of violence that makes evident the closeness of the human-dog bond, differences in their state-provided health care reveal the production of shifting species hierarchies. I argue that war scrambles both human-dog affective relationships and biopolitically configured interspecies hierarchies in ways that produce suffering, not just for humans and dogs separately, but also for the bonds they forge together. Building peace through health care demands repairing the ways in which armed violence has rendered the bonds between humans and nonhumans pathological.

Assuntos

RESUMO

SUMMARY: As it is currently played, volleyball is a game in which success depends in large measure on the athleticism of the participants. The aim of this research was to point out the importance of the cycle of stretching and shortening in different jumps for elite volleyball players. Thus, it is common for volleyball athletes to place considerable emphasis on jump training. Not surprisingly, overload injuries of the knee and ankle joints, both acute and chronic, occur frequently among volleyball players and are related to the volume of jump training and skill repetition. Understanding the biomechanics of jumping is therefore a prerequisite for designing effective training programs which minimize the risk of overuse injuries that may result from excessive jumping, and the repetitive mechanical loading of muscles and joints that are involved in jump training Muscles acting about a joint function naturally through a combination of eccentric (lengthening) and concentric (shortening) activations. In the lower limb, the stretch-shortening cycle is a reflex arc in which the tendomuscular system acting about the knee or ankle is eccentrically preloaded (stretched) in the loading or impact phase of the jump before concentrically shortening in the push-off or take-off phase.

RESUMEN: Actualmente, el voleibol es un juego en el que el éxito depende en gran medida del atletismo de los participantes. El objetivo de esta investigación fue señalar la importancia del ciclo de estiramiento y acortamiento en diferentes saltos para jugadores de voleibol de élite. Es común que los atletas de voleibol pongan un énfasis considerable en el entrenamiento de salto. No es sorprendente que las lesiones por sobrecarga de las articulaciones de la rodilla y el tobillo, tanto agudas como crónicas, ocurran con frecuencia entre los jugadores de voleibol y estén relacionadas con el volumen de entrenamiento de saltos y la repetición de destrezas. Comprender la biomecánica del salto es, por lo tanto, un requisito previo para diseñar programas de entrenamiento efectivos que minimicen el riesgo de lesiones por uso excesivo que pueden resultar de un salto excesivo y la carga mecánica repetitiva de los músculos y las articulaciones que están involucrados en el entrenamiento del salto. Los músculos que actúan sobre una articulación funcionan de forma natural a través de una combinación de activaciones excéntricas (alargamiento) y concéntricas (acortamiento). En el miembro inferior, el ciclo de estiramiento-acortamiento es un arco reflejo en el que el sistema tendomuscular que actúa sobre la rodilla o el tobillo se precarga (estira) excéntricamente en la fase de carga o impacto del salto antes de acortarse concéntricamente en el despegue o toma. -fase de apagado.

Assuntos

RESUMO

This study investigated the effect of 4 weeks of high-intensity interval training (HIIT) with specific techniques (TS-G) vs. repeated sprints (RS-G) and analyzed the inter-individual variability [classified into responders (Rs) and non-responders (NRs)] on sport-related fitness in taekwondo (TKD) athletes. Athletes of both genders (n = 12) were randomly assigned into TS-G and RS-G groups. Both groups trained 3 days/week for 4 weeks [two blocks of three rounds of 2 min of activity (4-s of all-out efforts with 28-s dynamical pauses) with 1 min of recovery in between and 5 min between blocks] during their regular training. The related sport fitness assessments included squat jump (SJ), countermovement jump (CMJ), multiple frequency speed of kick test (FSKTMULT), specifically total kicks and Kick Decrement Index (KDI), and 20-m shuttle run (20MSR). Relevant results indicate a significant effect of the time factor in both groups for SJ performance and a significant decrease for KDI in RS-G. In addition, an improvement in performance according to the effect size analysis in the TS-G in total kicks, KDI, and 20MSR. Complementarily, a higher proportion of athlete Rs was reported in TS-G vs. RS-G for SJ (50% vs. 30.3%, respectively), CMJ, and total kicks (16.6% vs. 0%). In conclusion, the addition to the regular training of a HIIT with specific-techniques and repeated-sprints associated with intervals and similar structure of the combat during 4 weeks of training can improve the concentric characteristics of lower limb performance, although they were not the sufficient stimuli in the other components of TKD-related fitness.

RESUMO

RESUMEN Se realizó un estudio observacional de corte transversal con enfoque descriptivo con el objetivo de determinar el riesgo por exposición a agentes químicos, atmósferas peligrosas y definir recomendaciones para mejorar las condiciones de trabajo en las minas de carbón de Tópaga (Boyacá). Para recopilar la información se utilizó el cuestionario para la identificación y prevención del riesgo en espacios confinados, del Instituto Nacional de Seguridad e Higiene en el Trabajo, y se realizaron mediciones de gases en las minas. Los resultados muestran que el 25% de las minas tienen niveles de oxígeno inferiores a 19,5% y ninguna supera el límite de explosividad. El 15% supera el Valor Límite Permisible (VLP) de monóxido de carbono y el 20% supera el VLP de sulfuro de hidrógeno y dióxido de azufre. Entre las recomendaciones propuestas se encuentra favorecer la ventilación natural, aplicar ventilación forzada cuando la natural resulte insuficiente y el empleo de calzado y herramientas antichispa. Se concluye que, en general, las condiciones de trabajo en las minas son inadecuadas para la seguridad y salud de los mineros.

ABSTRACT An observational cross-sectional study with a descriptive approach was carried out with the objective of determining the risk due to exposure to chemical agents, dangerous atmospheres and defining recommendations to improve working conditions in the coal mines of Tópaga (Boyacá). During the data collection process was used the questionnaire for the identification and prevention of risk in confined spaces, of the National Institute of Safety and Hygiene at Work. Moreover gas measurements were made in the mines. The results show that 25% of the mines have oxygen levels below 19.5% and none exceed the explosive limit. 15% exceed the Permissible Limit Value (VLP) for carbon monoxide and 20% exceed the VLP for hydrogen sulfide and sulfur dioxide. The proposed recommendations include favoring natural ventilation, applying forced ventilation when the natural one is insufficient and the use of non-sparking shoes and tools. It is concluded that, in general, the working conditions in the mines are inadequate for the safety and health of the miners.

RESUMO Foi realizado um estudo observacional transversal com abordagem descritiva com o objetivo de determinar o risco devido à exposição a agentes químicos, atmosferas perigosas e definir recomendações para melhorar as condições de trabalho nas minas de carvão de Tópaga em Boyacá. Para colher as informações, foi utilizado o questionário de identificação e prevenção de riscos em espaços confinados, do Instituto Nacional de Segurança e Higiene no Trabalho, e realizaram medidas do nível dos gases nas minas visitadas. Os resultados mostram que 25% das minas apresentam níveis de oxigênio abaixo de 19,5% e nenhuma excede o limite explosivo. 15% excedem o valor limite permitido (VLP) para o monóxido de carbono e 20% excedem o VLP para o sulfeto de hidrogênio e dióxido de enxofre. Entre as recomendações propostas estão favorecer a ventilação natural, aplicar ventilação forçada quando a ventilação natural for insuficiente e o uso de calçados e ferramentas anti-faísca. Conclui-se que, em geral, as condições de trabalho nas minas são inadequadas para a segurança e a saúde dos mineiros.

RESUMO

As military applications of the insensitive munitions compounds (IMCs) 2,4-dinitroanisole (DNAN) and 3-nitro-1,2,4-triazol-5-one (NTO) increase, there is a growing need to understand their environmental fate and to develop remediation strategies to mitigate their impacts. Iron (II) monosulfide (FeS) minerals are abundant in freshwater and marine sediments, marshes, and hydrothermal environments. This study shows that FeS solids can reduce DNAN and NTO to their corresponding amines under anoxic ambient conditions. The reactions between IMCs and the FeS minerals were surface-mediated since they did not occur when only dissolved Fe2+(aq) and S2-(aq) were present. Mackinawite, a tetragonal FeS with a layered structure, reduced DNAN mainly to 2-methoxy-5-nitroaniline (MENA), which in turn was partially reduced to 2-4-diaminoanisole (DAAN). The layered structure of mackinawite provided intercalation sites likely responsible for partial adsorption of MENA and DAAN. Mackinawite entirely reduced NTO to 3-amino-1,2,4-triazol-5-one (ATO). The reduction of IMCs showed concurrent oxidation of mackinawite to goethite and elemental sulfur. A commercial FeS product, composed mainly of pyrrhotite and troilite, reduced DNAN to DAAN and NTO to ATO. At pH 6.5, DNAN and NTO transformation rates were 667 and 912 µmol h-1 m-2, respectively, on the mackinawite surface and 417 and 1344 µmol h-1 m-2, respectively, on the commercial FeS surface. This is the first report of the reduction of a nitro-heterocyclic compound (NTO) by FeS minerals. The evidence indicates that DNAN and NTO can be rapidly transformed to their succeeding amines in anoxic subsurface environments and aquatic sediments rich in FeS minerals.

Assuntos

RESUMO

2,4-Dinitroanisole (DNAN) is an insensitive munitions compound expected to replace 2,4,6-trinitrotoluene (TNT). The product of DNAN's reduction in the environment is 2,4-diaminoanisole (DAAN), a toxic and carcinogenic aromatic amine. DAAN is known to become irreversibly incorporated into soil natural organic matter (NOM) after DNAN's reduction. Herein, we investigate the reactions between DAAN and NOM under anoxic conditions, using 1,4-benzoquinone (BQ) and methoxybenzoquinone (MBQ) as model humic moieties of NOM. A new method stopped the fast reactions between DAAN and quinones, capturing the fleeting intermediates. We observed that DAAN incorporation into NOM (represented by BQ and MBQ models) is quinone-dependent and occurs via Michael addition, imine (Schiff-base) formation, and azo bond formation. After dimers are formed, incorporation reactions continue, resulting in trimers and tetramers. After 20 days, 56.4% of dissolved organic carbon from a mixture of DAAN (1 mM) and MBQ (3 mM) had precipitated, indicating an extensive polymerization, with DAAN becoming incorporated into high-molecular-weight humic-like compounds. The present work suggests a new approach for DNAN environmental remediation, in which DNAN anaerobic transformation can be coupled to the formation of non-extractable bound DAAN residues in soil organic matter. This process does not require aerobic conditions nor a specific catalyst.

RESUMO

RESUMEN La pliometría es un método de entrenamiento diseñado para reproducir movimientos rápidos, explosivos y potentes; mejora la fuerza y la rapidez en distintos planos musculares, por lo cual suele ser muy útil para mejorar ciertas habilidades físicas en deportes como el fútbol. El objetivo de esta investigación es validar teóricamente, mediante consulta por especialistas, un grupo de ejercicios pliométricos de fuerza-reactiva para futbolistas categoría sub-14. Esta investigación es de tipo descriptiva-explicativa, de orden cualitativa y correlacional. Se encuestan a 21 especialistas de fútbol, clasificados en dos grupos independientes, se validan teóricamente alcances y limitaciones de una propuesta de ejercicios pliométricos para miembros inferiores, adaptados a futbolistas sub-14. Los promedios que describen los puntajes alcanzados fueron mayores en el postest, existen diferencias significativas al evaluar indistintamente cada grupo estudiado (Grupo 1: "I" r=0.004, "A" r=0.005, "P" r=0.003, "V" r=0.003 y "EP" r=0.003; Grupo 2: "I" r=0.002, "A" r=0.003, "P" r=0.001, "V" r=0.003 y "EP" r=0.002), no existen diferencias significativas al comparar los resultados entre cada grupo independiente como parte del pretest "I" (p=0.973), "A" (p=0.756), "P" (p=0.426), "V" (p=1.000) y "EP" (p=0.468) y como parte del postest "I" (p=0.223), "A" (p=0.973), "P" (p=0.173), "V" (p=0.918) y "EP" (p=0.918). Con este trabajo, se mejora teóricamente la propuesta de intervención, concerniente en 25 ejercicios de pliometría aplicada a miembros inferiores de futbolistas sub-14, además, se tienen presente cinco indicadores de análisis. Se recomienda realizar una validación práctica que enfoque la investigación a futuro, con un tipo de investigación experimental o cuasi-experimental.

RESUMO A Pliometria é um método de treino concebido para reproduzir movimentos rápidos, explosivos e poderosos; melhora a força e a rapidez em diferentes planos musculares, pelo que é normalmente muito útil para melhorar certas capacidades físicas em desportos como o futebol. O objetivo desta investigação é validar teoricamente, através da consulta por especialistas, um grupo de exercícios pliométricos de força reativa para jogadores de futebol sub-14. Esta investigação é descritiva-explicativa, qualitativa e correlacional. Vinte e um especialistas em futebol, classificados em dois grupos independentes, foram inquiridos. O âmbito e as limitações de uma proposta de exercícios pliométricos para membros inferiores, adaptados aos jogadores de futebol sub-14, foram teoricamente validados. As médias que descrevem as pontuações obtidas foram mais elevadas no pós-teste, existem diferenças significativas ao avaliar indistintamente cada grupo estudado (Grupo 1: "I" r=0. 004, "A" r=0,005, "P" r=0,003, "V" r=0,003 e "EP" r=0,003; Grupo 2: "I" r=0,002, "A" r=0,003, "P" r=0,001, "V" r=0,003 e "EP" r=0. 002), não há diferenças significativas ao comparar os resultados entre cada grupo independente como parte do "I" (p=0,973), "A" (p=0). 756), "P" (p=0,426), "V" (p=1.000) e "EP" (p=0,468) e como parte do pós-teste "I" (p=0,223), "A" (p=0,973), "P" (p=0,173), "V" (p=0,918) e "EP" (p=0,918). Com este trabalho, a proposta de intervenção é teoricamente melhorada, relativamente a 25 exercícios pliométricos aplicados aos membros inferiores dos jogadores de futebol sub-14, além disso, são tidos em conta cinco indicadores de análise. Recomenda-se a realização de uma validação prática que focalize a investigação futura, com um tipo de investigação experimental ou quase-experimental.

ABSTRACT Plyometry is a training method designed to reproduce fast explosive and powerful movements, it improves strength and speed in different muscle planes, which is why it is usually very useful to improve certain physical skills in sports such as soccer. The objective of this research is to theoretically validate, through consultation with specialists, a group of plyometric strength-reactive exercises for U-14 soccer players. This is a qualitative and correlational descriptive-explanatory research. Twenty-one soccer specialists classified into two independent groups were surveyed, theoretically validating the scope and limitations of a plyometric exercises proposal for lower limbs adapted to U-14 soccer players. The averages that describe the scores achieved were higher in the post-test, with significant differences when evaluating each group studied (Group 1: "I" r=0.004, "A" r=0.005, "P" r=0.003, " V "r=0.003 and" EP "r=0.003; Group 2:" I "r=0.002," A"r=0.003," P "r=0.001," V "r=0.003 and" EP "r=0.002), there is not significant differences when comparing the results between each independent group as part of the pretest "I" (p = 0.973), "A" (p = 0.756), "P" (p = 0.426), "V" (p = 1.000) and "EP" (p = 0.468), and as part of the post-test "I" (p = 0.223), "A" (p = 0.973), "P" (p = 0.173), "V" (p = 0.918) and "EP" (p = 0.918). With this work, the intervention proposal is theoretically improved, concerning 25 plyometric exercises applied to lower limbs of U-14 soccer players, in addition, five analysis indicators are taken into account. It is recommended to carry out a practical validation that focuses future research, with a type of experimental or quasi-experimental research.

RESUMO

: Este estudo investigou o impacto de 5 semanas de treinamento pliométrico em membros superiores e inferiores sobre o desempenho físico em estudantes de Educação Física. Foram recrutados 16 estudantes do sexo masculino de 18 a 23 anos divididos em 2 grupos (Controle e Treino). O grupo Treino foi submetido ao treinamento pliométrico de membros superiores e inferiores por 5 semanas com 3 sessões/semana de 30-40 minutos/sessão, composta de 10 exercícios de braço e perna (10-20 repetições/exercício). Antes e imediatamente após o programa de treinamento pliométrico, os indivíduos foram avaliados por parâmetros antropométricos (peso, estatura, índice de massa corporal e percentual de gordura), nível de flexibilidade e desempenho físico (forças de toque e de ataque, salto vertical, sprint de 20 m e agilidade). Dados de flexibilidade e desempenho físico foram avaliados por análise de covariância (ANCOVA), além da correlação de Pearson entre as variáveis de desempenho físico após 5 semanas de treinamento. O grupo Treino exibiu maior ganho de desempenho no salto vertical quando comparado ao grupo Controle (p< 0,05). Todavia, não foi observada diferença significativa entre os grupos Treino e Controle nos ganhos de força de toque e de ataque, no desempenho do teste de sprint de 20 m, no teste de agilidade e de flexibilidade (p> 0,05). Houve correlação positiva entre os testes de forças de toque e de ataque com o salto vertical (p< 0,001, r= 0,633; e p< 0,001, r= 0,639; respectivamente), como também correlação dos testes salto vertical com os testes de velocidade (p< 0,001, r= -0,768) e agilidade (p< 0,002, r= -0,537) após o treinamento. Conclui-se que 5 semanas de treinamento pliométrico de membros superiores e inferiores exibiram melhora no desempenho do salto vertical de estudantes de Educação Física, bem como observou-se correlação entre os parâmetros neuromusculares anaeróbicos de membros inferiores e superiores após o período de treinamento.(AU)

This study investigated the impact of 5 weeks of plyometric training on upper and lower limbs on physical performance parameters in Physical Education students. Sixteen male college students aged 18 to 23 years were divided into 2 groups (Control and Training). The Training group was submitted to 5 weeks of plyometric training for upper and lower limbs, with 3 sessions per week for 30-40 minutes per session. Training sessions consisted of 10 arm and leg exercises (10-20 repetitions per exercise). Anthropometric parameters (weight, height, body mass index and body fat percentage), level of flexibility and physical performance (touch and attack strength, vertical jump, 20m sprint, agility) were assessed before and immediately after the plyometric training program. Flexibility and physical performance data were assessed by covariance analysis (ANCOVA), in addition to Pearson's correlation among physical performance parameters after 5 weeks of training. The Training group showed a greater gain in the vertical jump performance when compared to the Control group. However, no significant difference was observed between the Training and Control groups for touch and attack strength gains, for 20 m sprint performance gains, and for agility and flexibility test gains. There was a positive correlation between the tests of touch and attack strengths with vertical jump performance. There was also positive correlation between touch and attack strength with vertical jump (p< 0.001, r= 0.633; e p< 0,001, r= 0.639; respectively), and between vertical jump performance and 20m sprint performance (p< 0.001, r= -0,768) and agility test after training (p< 0.002, r= -0,537). It is concluded that 5 weeks of plyometric training for upper and lower limbs showed improvement in the vertical jump performance in Physical Education students. There was also a correlation between the anaerobic neuromuscular parameters of lower and upper limbs after the training period.(AU)

Assuntos

RESUMO

The study of historic volcanic eruptions is often complicated by the lack of recorded primary data and observations of such events. In the case of large-magnitude historic eruptions, these types of data are important to better understand not only the physical nature of these rare events but also the volcanic and social impacts that follow. In this paper, we compile contemporary data on the Santa María Plinian eruption of 1902, in Guatemala. The data supplement those presented in the original research article [1] but individually provide an interesting and useful compilation of eyewitness testimonies, scientific studies and newspaper reports. We identify key contemporary sources containing quantitative data as well as various qualitative reports that we convert to quantitative measurements through a simple classification scheme. We also compile wind reanalysis data from the time of the eruption to display wind direction and speed with height. Both the data and the description of the methods of data analysis can aid future studies of qualitative (historic, eyewitness) to quantitative data conversion, as well as studies investigating this important eruption.

RESUMO

ABSTRACT We aimed to assess upper and lower limbs explosive strength, and its correlation with biceps brachii (BB) and vastus lateralis (VL) architecture. Absolute and maximum torque normalized rate of torque development (RTD) were measured from isometric elbow flexion (EF) and knee extension (KE). BB and VL architectures were assessed by ultrasound. Absolute RTD of KE was higher (129-272%), although normalized RTD was higher in EF (80-21%). The absolute RTD was correlated to muscle thickness only in the BB (r=.39-46). No relationship was found between muscle architecture and normalized RTD. In conclusion, the higher RTD from KE seems to be due to their greater strength. Only the muscle architecture could not explain the differences found in the RTD.

RESUMO Nosso objetivo foi avaliar a força explosiva de membros superiores e inferiores e a sua correlação com a arquitetura do bíceps braquial (BB) e vasto lateral (VL). A taxa de desenvolvimento de torque (TDT) absoluta e normalizada pela força máxima foi medida na flexão de cotovelo (FC) e extensão de joelho (EJ). A arquitetura do BB e do VL foi avaliada por ultrassonografia. A TDT absoluta de EJ foi maior (129-272%), mas a TDT normalizada foi maior na FC (80-21%). A TDT absoluta foi correlacionada com a espessura do BB (r=.39-46). A TDT normalizada não foi correlacionada à arquitetura muscular. Concluindo, a TDT superior da EJ parece causada pela maior força máxima. Apenas a arquitetura muscular não parece explicar a diferença na TDT.

RESUMEN Nuestro objetivo era evaluar la fuerza explosiva de los miembros superiores y inferiores y su correlación con la arquitectura del bíceps braquial (BB) y vasto lateral (VL). Se medio la tasa de desarrollo de torque (TDT) absoluta y normalizada por la fuerza máxima in la flexión de codo (FC) e extensión de rodilla (ER). La arquitectura del BB y VL fue evaluada por ultrasonido. La TDT absoluta de ER fue mayor (129-272%), pero la TDT normalizada fue mayor en la FC (80-21%). La TDT absoluta se correlacionó con el grosor del BB (r=.39-46). La TDT normalizada no se correlacionó con la arquitectura. En conclusión, la TDT superior del ER parece estar causado por la mayor fuerza máxima. La arquitectura muscular sola no parece explicar la diferencia en la TDT.

RESUMO

Intermittent Explosive Disorder (IED) is a psychiatric disorder characterized by recurrent outbursts of aggressive behaviour. Deep brain stimulation (DBS) in the posteromedial nucleus of the hypothalamus (pHyp) is an alternative therapy for extreme cases and shows promising results. Intraoperative microdialysis can help elucidate the neurobiological mechanism of pHyp-DBS. Objective To evaluate efficacy and safety of pHyp-DBS using eight-contact directional leads in patients with refractory IED (rIED) and the accompanying changes in neurotransmitters. Methods A prospective study in which patients with a diagnosis of rIED were treated with pHyp-DBS for symptom alleviation. Bilateral pHyp-DBS was performed with eight-contact directional electrodes. Follow-up was performed at 3, 6 and 12 months after surgery. Results Four patients (3 men, mean age 27 ± 2.8 yr) were included. All patients were diagnosed with rIED and severe intellectual disability. Two patients had congenital rubella, one has co-diagnosis of infantile autism and the fourth presents with drug-resistant epilepsy. There was a marked increase in the levels of GABA and glycine during intraoperative stimulation. The average improvement in aggressive behaviour in the last follow-up was 6 points (Δ: 50%, p= 0.003) while also documenting an important improvement of the SF-36 in all domains except bodily pain. No adverse events associated with pHyp-DBS were observed. Conclusions This is the first study to show the safety and beneficial effect of directional lead pHyp-DBS in patients with refractory Intermittent Explosive Disorder and to demonstrate the corresponding mechanism of action through increases in GABA and glycine concentration in the pHyp.