RESUMO
Landfill leachate consists mostly of a high content of refractory organic matter, ammonia and toxic compounds. All these compounds, regardless of their nature, have a potential pollution effect on local ground and surface waters. In this context, the purpose of the present study was to evaluate a treatment process (coagulation-flocculation with lime coupled with nanofiltration) applied to landfill leachate from Seropédica, Rio de Janeiro (Brazil). Jar tests were conducted to determine the optimum dosage of lime (ranged from 0 to 10 g L-1) and, at optimum lime dose, ammonia nitrogen was removed during coagulation-flocculation process due to high pH. The process was settled for 6 h with slow stirring (50 rpm) to promote air entrainment and NH3-N stripping before using the final treatment step of nanofiltration at 8 bar. After ammonia stripping, NH3-N was reduced from 1,236 mg L-1 to 353 mg L-1 (71% removal efficiency). At the end of the combined treatment, TOC (total organic carbon), HS (humic substances) and COD (chemical oxygen demand) removals were 89%, 80% and 94%, respectively. The results showed that the combined process was effective in the removal of recalcitrant compounds and NH3-N.
Assuntos
Compostos de Cálcio/química , Filtração , Floculação , Óxidos/química , Poluentes Químicos da Água/análise , Purificação da Água/métodos , Amônia/análise , Análise da Demanda Biológica de Oxigênio , Brasil , Substâncias Húmicas/análise , Modelos TeóricosRESUMO
Anaerobic biodegradability of oil shale wastewater was investigated after the following pretreatment sequence: ammonia stripping and activated carbon adsorption. Anaerobic biological treatment of oil shale wastewater is technically feasible after stripping at pH 11 for reducing the N-NH3 concentration, adsorption with 5â g/L of activated carbon in order to reduce recalcitrance and pH adjustment with CO2 so that the sulphate concentration in the medium remains low. After this pretreatment sequence, it was possible to submit the wastewater without dilution to an anaerobic treatment with 62.7% soluble chemical oxygen demand removal and specific methane production of 233.2â mL CH4STP/g CODremoved.