RESUMO

Y-TZP/MWCNT-SiO2 nanocomposite was synthesized by co-precipitation and hydrothermal treatment methods. After the characterization of the MWCNT-SiO2 powder, specimens were obtained from the synthesized material Y-TZP/MWCNT-SiO2 by uniaxial pressing for a second characterization and later comparison of its optical and mechanical properties with the conventional Y-TZP. The MWCNT-SiO2 was presented in bundles of carbon nanotubes coated by silica (mean length: 5.10 ± 1.34 µm /D90: 6.9 µm). The composite manufactured was opaque (contrast ratio: 0.9929 ± 0.0012) and had a white color with a slightly difference from the conventional Y-TZP (ΔE00: 4.4 ± 2.2) color. The mechanical properties of Y-TZP/MWCNT-SiO2: vickers hardness (10.14 ± 1.27 GPa; p = 0.25) and fracture toughness (4.98 ± 0.30 MPa m1/2; p = 0.39), showed no significant difference from the conventional Y-TZP (hardness: 8.87 ± 0.89; fracture toughness: 4.98 ± 0.30 MPa m1/2). However, for flexural strength (p = 0.003), a lower value was obtained for Y-TZP/MWCNT-SiO2 (299.4 ± 30.5 MPa) when compared to the control Y-TZP (623.7 ± 108.8 MPa). The manufactured Y-TZP/MWCNT-SiO2 composite presented satisfactory optical properties, however the co-precipitation and hydrothermal treatment methods need to be optimized to avoid the formation of porosities and strong agglomerates, both from Y-TZP particles and MWCNT-SiO2 bundles, which lead to a significant decrease in the material flexural strength.

Assuntos

RESUMO

OBJECTIVES: This study evaluated the effect of addition of alumina particles (polycrystalline or monocrystalline), with or without silica coating, on the optical and mechanical properties of a porcelain. METHODS: Groups tested were: control (C), polycrystalline alumina (PA), polycrystalline alumina-silica (PAS), monocrystalline alumina (MA), monocrystalline alumina-silica (MAS). Polycrystalline alumina powder was synthesized using a polymeric precursor method; a commercially available monocrystalline alumina powder (sapphire) was acquired. Silica coating was obtained by immersing alumina powders in a tetraethylorthosilicate solution, followed by heat-treatment. Electrostatic stable suspension method was used to ensure homogenous dispersion of the alumina particles within the porcelain powder. The ceramic specimens were obtained by heat-pressing. Microstructure, translucency parameter, contrast ratio, opalescence index, porosity, biaxial flexural strength, roughness, and elastic constants were characterized. RESULTS: A better interaction between glass matrix and silica coated crystalline particles is suggested in some analyses, yet further investigation is needed to confirm it. The materials did not present significant differences in biaxial flexural strength, due to the presence of higher porosity in the groups with alumina addition. Elastic modulus was higher for MA and MAS groups. Also, these were the groups with optical qualities and roughness closer to control. The PA and PAS groups were considerably more opaque as well as rougher. SIGNIFICANCE: Porcelains with addition of monocrystalline particles presented superior esthetic qualities compared to those with polycrystalline particles. In order to eliminate the porosity in the ceramic materials investigated herein, processing parameters need to be optimized as well as different glass frites should be tested.

Assuntos

RESUMO

A description of methods and computer programs for the prediction of "coupling properties" in axially-textured polycrystals is presented. Starting data are the single-crystal properties, texture and stereography. The validity and proper protocols for applying the Voigt, Reuss and Hill approximations to estimate coupling properties effective values is analyzed. Working algorithms for predicting mentioned averages are given. Bunge's symmetrized spherical harmonics expansion of orientation distribution functions, inverse pole figures and (single and polycrystals) physical properties is applied in all stages of the proposed methodology. The established mathematical route has been systematized in a working computer program. The discussion of piezoelectricity in a representative textured ferro-piezoelectric ceramic illustrates the application of the proposed methodology. Polycrystal coupling properties, predicted by the suggested route, are fairly close to experimentally measured ones.

RESUMO

O polimorfismo pode ocasionar desvios de qualidade durante o processo produtivo e influenciar o desempenho dos medicamentos. Por isso, o entendimento do fenômeno e suas implicações abre um campo amplo de possibilidades a serem exploradas na área farmacêutica, incluindo o surgimento de novos paradigmas e ferramentas na garantia da qualidade de medicamentos. Este trabalho apresenta uma introdução aos aspectos básicos do fenômeno do polimorfismo e suas implicações na produção e controle de medicamentos, com ênfase no polimorfismo dos fármacos.

Polymorphism can cause quality deviations during the production of medicines and can influence their effectiveness. Therefore, an understanding of this phenomenon and its implications opens a wide of possibilities to be explored in the pharmaceutical , including the emergence of new paradigms and tools for the quality assurance of medicines. This paper presents an introduction to basic aspects of the polymorphism phenomenon and its implications for the production and control of medicines, with emphasis on drug polymorphs.

Assuntos

RESUMO

Purpose: To analyze the stress distribution on a cantilever-fixed partial denture after simulation of maximum mastication loads in order to optimize its design. Methods: A cantilever-fixed partial denture framework was designed in the CAD-CAM system Everest®Kavo v2.0 using two materials, titanium and zirconium, with connectors of 5.28 mm² and 9.05 mm², respectively. A finite element model was built for stress analysis using simulations of mastication load. Results: For zirconia, only the molar cantilever with the smaller connector area and a 0.5-mm fillet exceeded the considered threshold resistance value of 575 MPa. All the other designs yielded resistances below this value. For titanium, only cantilevers with 9.05 mm² connector area and fillets of 1 or 1.4 mm presented stress values inferior to titanium yield strengh. Conclusion: Within the limitations of this study, it can be concluded that titanium cantilever-fixed partial denture frameworks with a 5.28 mm² connector area cannot support maximum mastication loads; frameworks of this material require larger connectors with fillets introduced in the gingival embrasure. Zirconia, however, supports maximum bite forces in most situations with both molar and premolar design cantilevers. Precaution should be taken when dealing with smaller connectors of 5.28 mm².

Objetivo: Analisar a distribuição de tensões em próteses parciais fixas em cantilever após aplicação de cargas simuladoras da mastigação, de forma a otimizar o seu desenho. Metodologia: Obteve-se a infra-estrutura de uma prótese parcial fixa em cantilever no sistema CAD-CAM Everest®Kavo v2.0, considerando dois materiais: titânio e zircônia, com conectores de 5,28 mm² e 9,05 mm², respectivamente. Gerou-se um modelo de elementos finitos, onde foram efetuadas análises de tensões com cargas simuladoras da mastigação. Resultados: Para zircônia, apenas o cantilever molar com área de conector mais reduzida, e concordância de 0,5 mm, excedeu o valor de resistência 575 MPa. Para o titânio, apenas o cantilever de 9,05 mm², com concordâncias de 1 e 1,4 mm, apresentou valores inferiores à tensão do titânio. Conclusão: Dentro das limitações deste estudo pode-se concluir que as infra-estruturas de titânio em cantilever não suportam cargas mastigatórias máximas com uma área de conector de 5,28 mm² e requerem conectores de áreas superiores, com concordâncias introduzidas na embrasura gengival. A zircônia geralmente suporta forças mastigatórias máximas com cantilever molar ou pré-molar. Deve-se ter precaução quando a área dos conectores é reduzida para 5,28 mm².

Assuntos

RESUMO

Purpose: To present a case report of a patient with amelogenesis imperfecta rehabilitated with 26 CAD-CAM all-ceramic fully sintered zirconia crowns.Case description: A male subject, 28 year-old, sought dental treatment presenting a clinical condition compatible with amelogenesis imperfecta. All teeth had yellow, brown, and white areas of weak enamel. Composite restorations were present on teeth 14, 16, 24, 25, 26, 27, and 46; dental caries were shown on teeth 36, 37, and 47. Hipersensitivity was reported. The treatment included fully sintered zirconia crowns for all teeth, using a CAD-CAM system. No problems of marginal adaptation of the crowns were detected, and the final results were satisfactory for both the patient and the clinician. Conclusion: The clinical rehabilitation of an amelogenesis imperfecta case is a challenge, and a multidisciplinary approach is required. Zirconia all-ceramics crowns are an excellent option to restore dental aesthetics as the opaque zirconia coping can mask dischromic abutments, and the crowns have biocompatibility and improved physical properties.

Objetivo: Apresentar o caso clínico de um paciente com amelogenesis imperfecta, que foi reabilitado com 26 coroas CAD-CAM de zircônia totalmente sinterizada. Descrição do caso: Um sujeito do sexo masculino, 28 anos, procurou tratamento odontológico apresentando uma condição clínica compatível com amelogenesis imperfecta. Todos os dentes tinham áreas amarelas, marrons e brancas de esmalte enfraquecido. Havia restaurações de resina composta nos dentes 14, 16, 24, 25, 26, 27 e 46; cárie dentária estava presente nos dentes 36, 37 e 47. Relatou-se hipersensibilidade dentária. O tratamento incluiu coroas de zircônia totalmente sinterizada para todos os dentes, usando um sistema CAD-CAM. Nenhum problema de adaptação marginal das coroas foi detectado e os resultados finais foram satisfatórios para ambos o paciente e o clínico. Conclusão: A reabilitação clínica de amelogenesis imperfecta é um desafio e a abordagem multidisciplinar deve ser mandatória. As coroas de zircônia são uma excelente opção para a reabilitação de pacientes com esta anomalia, pois o opaco dos copings de zircônia pode mascarar as diferentes cores dos pilares e o resultado final é esteticamente aceitável, com biocompatibilidade e propriedades físicas superiores.

Assuntos