RESUMO
Hydrological data and total phosphorus (TP) concentration at reservoirs' outlet were combined in a transient complete-mix model to obtain mean input loads and inlet concentration-flow relationships. This approach was designed to investigate the issue of phosphorus pollution in semiarid regions with intermittent rivers. The methodology was applied for twenty reservoirs in the State of Ceará, Brazilian semiarid. The modeled TP loads correlated well (R2 = 0.74) with reference loads estimated from environmental inventories, with only 10% of underestimated results. The average input loads per unit area of the catchments ranged from about 4 to 40 kg km-2 yr-1, which were considerably lower than the national average of about 500 kg km-2 yr-1. This was attributed to lower precipitation indexes, intermittent river regime and a high-density reservoir network, peculiar of the Brazilian semiarid. Meanwhile, the input load per unit area of a small and highly populated urban catchment, with higher precipitation indexes and deficient sanitation was substantially higher (2626 kg km-2 yr-1). Moreover, the fitted TP concentration-flow relationships directly reflected different TP input sources: strong u-shaped behavior marked the curves of highly non-point source dominated catchments, whereas a dilution pattern prevailed in those with significant point source inputs. The model validation with measured riverine TP concentration reached a NSE of 0.63. However, peak values in TP concentration during low flow rates sensitively affected the fitting of the models. In spite of non-point source dominance in the catchments, some relationships presented a slight signal of this use type. The variation range of the fitting parameters in comparison with other studies, as well the expected behavior of the curves in light of land use characteristics, strongly support the methodology applied in this study. The proposed approach will potentially help address the TP issue in tropical semiarid regions. Furthermore, the paper presents a simple way to deal with the challenging lack of monitored data in such environments.
Assuntos
Fósforo , Poluentes Químicos da Água , Brasil , China , Monitoramento Ambiental , Nitrogênio/análise , Fósforo/análise , Rios , Poluentes Químicos da Água/análiseRESUMO
RESUMO O artigo teve como objetivo apresentar uma metodologia para caracterização da qualidade de água na Bacia Hidrográfica do Açude Acarape do Meio, no semiárido brasileiro. O mapeamento do uso do solo e o monitoramento de parâmetros de qualidade de água possibilitaram a identificação de fontes poluidoras e a construção do diagnóstico da bacia. A partir da modelagem da qualidade de água, 37 km do Rio Pacoti foram classificados como classe 4, exceto sua nascente, que ficou na classe 2. As principais fontes poluidoras para a degradação dos corpos hídricos foram as deficitárias Estações de Tratamento de Esgoto (ETEs), a falta de saneamento básico na zona rural, a pecuária e a atividade agrícola. O modelo QUAL-UFMG estimou a carga de entrada de fósforo no açude em 13,7 ton.ano-1 para uma concentração de 0,56 mg.L-1 e vazão média em 1,48 m³.s-1. Os coeficientes calibrados K1, Ks, Kd, Kb, Kspo, Koi e K2 foram iguais a 0,45 d-1, 0,29 d-1, 0,68 d-1, 0,65 d-1, 0,1 d-1, 0,01 d-1 e 5,4 d-1, respectivamente. Avaliaram-se as intervenções políticas e infraestruturais na bacia em dois cenários: melhoria na eficiência de operação das ETEs e efetivação de políticas públicas, que reduziram consideravelmente a carga de fósforo.
ABSTRACT This paper aimed at presenting a methodology for evaluating the water quality at the Acarape do Meio catchment, in the Brazilian semiarid. The land use mapping and monitoring of water quality parameters enabled the identification of main polluting sources and the construction of a catchment diagnosis. According to the water quality modelling, a stretch of 37 km along the Pacoti River was classified as class 4, except for those ones located at the catchment headwater, which was classified as class 2. The main polluting sources contributing to the water degradation were the inefficient Sewage Treatment Plants, the lack of basic sanitation in rural areas, livestock and agriculture activities. The QUAL-UFMG model estimated an affluent phosphorous load at the reservoir entrance of 13.7 ton.year-1 for the concentration of 0.56 mg.L-1 and mean water discharge of 1.48 m³.s-1. The K1, Ks, Kd, Kb, Kspo, Koi and K2 coefficients were 0.45, 0.29, 0.68, 0.65, 0.1, 0.01 and 5.4 d-1, respectively. The impacts of political and infrastructural measures over the catchment were evaluated taking into account two scenarios: improvement of efficiency at Sewage Treatment Plants and implementation of effective public policies, which reduced significantly the affluent phosphorous load into the reservoir.