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Partially Saturated Vertical Constructed Wetlands (PSV-CWs) are novel wastewater treatment systems that work through aerobic and anaerobic conditions that favor the removal of pollutants found in high concentrations, such as rivers contaminated with domestic wastewater and landfill leachate. The objective of the study was to evaluate the efficiency of PSV-CWs using monocultures and polycultures of Typha latifolia and Heliconia psittacorum to treat river waters contaminated with leachates from open dumps and domestic wastewater. Six experimental units of PSV-CWs were used; two were planted with Typha latifolia monoculture, two with Heliconia psittacorum monoculture and two with polycultures of both plants. The results indicated better organic matter and nitrogen removal efficiencies (p < 0.05) in systems with polycultures (TSS:95%, BOD5:83%, COD:89%, TN:82% and NH4+:99%). In general, the whole system showed high average removal efficiencies (TSS:93%, BOD5:79%, COD:85%, TN:79%, NH4+:98% and TP:85%). Regarding vegetation, both species developed better in units with monocultures, being Typha latifolia the one that reached a more remarkable development. However, both species showed high resistance to the contaminated environment. These results showed higher removals than those reported in the literature with conventional Free Flow Vertical Constructed Wetlands (FFV-CWs), so PSV-CWs could be a suitable option to treat this type of effluent.

The research addresses the contamination of water resources in developing countries by landfill leachate and domestic wastewater discharges. It proposes treatment through Partially Saturated Vertical Constructed Wetlands (PSV-CWs), which, despite the limited information available, have been shown to be effective in removing pollutants in effluents with high concentrations. In addition to evaluating PSV-CWs, the study examines the impact of different types of vegetation on pollutant removal efficiency, concluding that PSV-CWs are a promising and viable option for the treatment of these effluents.

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Landfills often become a source of environmental impact due to the percolation of the leachate (liquid resulting from the decomposition of buried waste), which can eventually disperse and contaminate the soil and water bodies. This study aimed to evaluate quantitatively and spatially the leachate plume from the former Belo Horizonte landfill in the Coqueiros and Taiobas watersheds by using tritium (3H) concentration in nineteen (19) sampling points: 14 groundwater, 4 surface water and 1 leachate. Among the methodologies applied to determine the 3H content in the leachate, pre-filtration proved to be the most effective due to the ease treating of the sample, as well as the identical results obtained compared to the traditional method. The 3H contents resulted in concentrations up to thirty times higher in the leachate (=96,19 to 111,87 TU) and ten times in groundwater (PM23/3 = 45,06 TU), compared to the calculated threshold (TS) of rainfall tritium (TS_3Hrain = 3,41 TU). Temporal series results indicate no trend and no influence of seasonality regarding the entry of pluvial tritium, leachate liquid level and wells water level. The 3H contour maps shows a transport of the mixture (water and leachate) towards the Coqueiros stream, with a higher concentration of leachate in wells closer to the landfill slope (PM13, PM14, PM15, and PM23) and in the southwest margin of the Coqueiros stream (PM17). In the furthest portion of the landfill, 3H levels are higher than the base threshold only at the deepest level of PM20 (=3,90 TU), possibly due to factors such as: i) denser character of the leachate compared to groundwater; ii) greater influence of recharge for regions further away from the landfill slope; and iii) the presence of the rock about 50 m from the surface. Based on the hydrogeological conceptual model, the transport of the leachate water mixture in the groundwater water compartment of the Coqueiros watershed basin seems to follow a piston or dispersion flow, with a small Peclet number (Pd = 0,05, as an example), as indicated by the high correlation coefficient values (R2 ≈ 0,85 to 0,99) from graphic interpolation. The mixture of water and leachate results in a transient time (tt) ≈ 30 years and linear velocity (Vl) ≈ 3-14 m/year in the interpolated sections. These indicate a coherent correlation with the mean hydraulic conductivity (K ≈ 29,34 m/year), as they result in effective porosity values between (Ne) ≈ 0.16 to 0.36, which corresponds to Ne range for unconsolidated sediments, similar to the wells lithotype profiles. Time series evaluation combined with lumped parameter approach suggest to be an interesting way to better understanding the HCM, and, therefore, to determine hydrodynamic parameters using tritium as a tracer.

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During the operation of the landfills, leachate should be managed with caution to avoid possible negative environmental impacts. Considering this, the present study aims to evaluate the relationship between different variables in the leachate composition and elucidate the transformation processes through which this effluent passes during the landfill's period of operation. The study was conducted with eight sanitary landfills from the state of Minas Gerais, in southeastern Brazil, and used descriptive statistical analysis, principal component analysis (PCA), correlation analysis, and calculation of the leachate pollution index (LPI). The biochemical oxygen demand (BOD5)/chemical oxygen demand (COD) ratio was between 0.20 and 0.60. We also observed a significant correlation of 0.45 between Cl- and N-NH4+, which reflects the biological degradation processes that contribute to the presence of both variables. The PCA showed that inorganic variables and organic matter dominated the first component, with coefficients above 0.65, indicating the importance of those variables in determining the general data variability. The LPI values were between 15.26 and 25.97, with BOD5, COD, and N-NH4+ having sub-indexes above 35, being the main variables that increase the pollution potential of the leachate. On the other hand, trace metals present sub-indexes below 7 due to precipitation caused by increased pH and the characteristics of the waste discarded in landfills. The study provides essential information regarding the landfill leachate characteristics and its variation over time, which can contribute to the definition of treatment technologies for this affluent in different scenarios.

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Membrane filtration processes have been used to treat landfill leachate. On the other hand, closing the leachate treatment loop and finding a final destination for landfill leachate membrane concentrate (LLMC) - residual stream of membrane systems - is challenging for landfill operators. The re-introduction of LLMC into the landfill is typical; however, this approach is critical as concentrate pollutants may accumulate in the leachate treatment facility. From that, leachate concentrate management based on resource recovery rather than conventional treatment and disposal is recommended. This work comprehensively reviews the state-of-the-art of current research on LLMC management from leachate treatment plants towards a resource recovery approach. A general recovery train based on the main LLMC characteristics for implementing the best recovery scheme is presented in this context. LLMCs could be handled by producing clean water and add-value materials. This paper offers critical insights into LLMC management and highlights future research trends.

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Expanded vermiculite was used as an adsorbent to remove ammonia nitrogen from landfill leachate. Bench and pilot-scale adsorption experiments were performed with leachate collected from a closed sanitary landfill located in Curitiba, southern Brazil. At the bench-scale, two different heights of vermiculite and three different flow rates were tested using a fixed-bed column. These tests produced an average uptake capacity of 33.4 mg g-1 for the ammonia nitrogen concentration of 2,560 mg L-1. The Yan model was used to determine the breakthrough and the exhaustion times due to the best fit of the data to this model. At the pilot-scale, the flow rate was determined from the shortest length of the mass transfer zone obtained from bench-scale experiments. Tests were performed using one stainless-steel column filled with 26.2 kg of expanded vermiculite, which resulted in a bed height of 1.6 m. A leachate flow rate of approximately 350 L d-1 was applied to achieve the required contact time of 8.3 h. At this scale, an average uptake capacity of 18.1 mg g-1 was obtained for the ammonia nitrogen concentration of 1,193 mg L-1. It is worth mentioning that the flow rate and the concentration of the adsorbate in the feeding solution are fundamental to improve the operational time of the fixed-bed column. The main goal of this research was the determination of operating conditions to scale-up the adsorption process of ammonia nitrogen onto expanded vermiculite. The contact time was a key parameter to reach this goal.

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The final disposal of municipal solid waste (MSW) in dumpsites is still a reality worldwide, especially in low- and middle-income countries, leading to leachate-contaminated zones. Therefore, the aim of this study was to carry out soil and leachate physicochemical, microbiological, and toxicological characterizations from a non-operational dumpsite. The L-01 pond samples presented the highest physicochemical parameters, especially chloride (Cl; 4101 ± 44.8 mg L-1), electrical conductivity (EC; 10,452 ± 0.1 mS cm-1), and chemical oxygen demand (COD; 760 ± 6.6 mg L-1) indicating the presence of leachate, explained by its close proximity to the landfill cell. Pond L-03 presented higher parameters compared to pond L-02, except for N-ammoniacal and phosphorus levels, explained by the local geological configuration, configured as a slope from the landfill cell towards L-03. Seven filamentous and/or yeast fungi genera were identified, including the opportunistic pathogenic fungi Candida krusei (4 CFU) in an outcrop sample. Regarding soil samples, Br, Se, and I were present at high concentrations leading to high soil contamination (CF ≤ 6). Pond L-02 presented the highest CF for Br (18.14 ± 18.41 mg kg-1) and I (10.63 ± 3.66 mg kg-1), while pond L-03 presented the highest CF for Se (7.60 ± 1.33 mg kg-1). The most severe lethal effect for Artemia salina was observed for L-03 samples (LC50: 79.91%), while only samples from L-01 were toxic to Danio rerio (LC50: 32.99%). The highest lethality for Eisenia andrei was observed for L-02 samples (LC50: 50.30%). The applied risk characterization indicates high risk of all proposed scenarios for both aquatic (RQ 375-909) and terrestrial environments (RQ > 1.4 × 105). These findings indicate that the investigated dumpsite is contaminated by both leachate and metals, high risks to living organisms and adjacent water resources, also potentially affecting human health.

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This work explores the techno-economic aspects of landfill leachate treatment by an integrated scheme composed of microfiltration (MF), nanofiltration (NF), and zeolite application for carbon and nitrogen removal. In bench-scale experiments, MF and NF were investigated, and zeolite batch tests were carried out to determine optimum conditions. A preliminary economic analysis is presented for a 200 m3 d-1 full-scale treatment facility based on the data obtained from experimental tests and literature surveys. The maximum removals of 92%, 94%, and 79% for chemical oxygen demand (COD), absorbance at 254 nm, and ammonium nitrogen (NH4+-N) were achieved in bench experiments, respectively. It was possible to reach the local discharge standard for COD (200 mg L-1), but it was not possible to reach the Brazilian disposal requirement for NH4+-N (20 mg L-1). The total cost of the integrated MF + NF + zeolite system was estimated at 19.89 US$m-3. In this study, the costs of the zeolite application account for around 70% of the total costs of the integrated scheme. Membrane process integration was an adequate strategy for removing organic compounds at low operating costs; However, further NH4+-N depuration is needed to meet discharge requirements.

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Worldwide, most solid waste ends its life in landfill sites, which have a significant environmental impact in several respects. In particular, rainfall over landfill sites results in the production of an aqueous leachate containing compounds having low biodegradability, high toxicity, and a high organic load. For this reason, this study aims to investigate the applicability of electro-Fenton (EF) and photoelectro-Fenton (PEF) processes as alternative for treating a local landfill effluent with high organic content (chemical oxygen demand (COD) = 2684.7 mg-O2 L -1) in a continuous-flow reactor (using, for first time, this kind of system with higher electrodes area of 35 cm2) using boron-doped diamond anode (Nb/BDD) and a carbon felt cathode (FC) electrodes. The effects of current density j (30, 60 and 90 mA cm-2) and UV radiation wavelength (UVA and UVC) were studied to evaluate the treatment efficiency as well as the energy consumption. Results clearly showed that, the best efficiencies removing organic matter, in terms of COD, were about 66%, 68% and 89% with an energy consumption of only 19.41, 17.61 and 17.59 kWh kg COD-1 for EF, PEF-UVA and PEF-UVC respectively, at 90 mA cm-2 after 4 h of operation. The treatment of this kind of effluent produced organic and inorganic by-products, the acetic and formic acids as well as NO2-, NO3-, and NH4+, being assessed their concentrations.

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Landfill leachates are high-strength complex mixtures containing dissolved organic matter, ammonia, heavy metals, and sulfur species, among others. The problem of leachate treatment has subsisted for some time, but an efficient and cost-effective universal solution capable of ensuring environmental resources protection has not been found. Aerobic granular sludge (AGS) has been considered a promising technology for biological wastewater treatment in recent years. Granules' layered structure, with an aerobic outer layer and an anaerobic/anoxic core, enables the presence of diverse microbial populations without the need for support media, allowing simultaneous removal of different pollutants in a single unit. Besides, its strong and compact arrangement provides higher tolerance to toxic pollutants and the ability to withstand large load fluctuations. Furthermore, its good that settling properties allow high biomass retention and better sludge separation. Nevertheless, AGS-related research has focused on carbon-nitrogen-phosphorus removal, mainly from sanitary sewage. This review aims to summarize and analyze the main findings and problems reported in the literature regarding AGS application to landfill leachate treatment and identify the knowledge gaps for future applications.

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Ecotoxicological assessment of landfill leachate has become a priority to determine its impacts on the ecosystem. Toxicity assays with microorganisms stand out due to their quick response, low cost and ease of testing. In this context, the present study evaluated the acute toxic effects of leachates from two landfills of different ages and modes of operation to bacterium Aliivibrio fischeri and activated sludge microorganisms and the ammonia nitrogen and humic substances (HS) sensitivity to these organisms. Reductions greater than 30% in leachate toxicity were observed after ammonia removal for A. fischeri and activated sludge microorganisms. After 97% removal of HS, the greater reductions in toxicity (44.28 to 79.82%) were verified for microbial species studied, indicating that the organic compounds (measured as chemical oxygen demand, total organic carbon and humic substances) were the primary pollutants responsible for the toxicity of the leachates. Concerning the organisms studied, A. fischeri showed greater sensitivity to the leachates' pollutants compared to the activated sludge microorganisms. Nevertheless, a strong correlation was observed between A. fischeri and activated sludge microorganisms' toxicity responses, suggesting that respirometry assay can be used to determine leachate toxicity.

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Ozonation process was used for leachate treatment from a landfill located in Rio de Janeiro, Brazil. The influence of pH and ozone concentration on COD (Chemical Oxygen Demand), TOC (Total Organic Carbon), Absorbance at 254 nm (ABS254nm), and True color was evaluated through RCCD (Rotatable Central Composite Design) experimental design, resulting in mathematical models that were statistically analyzed in Statistica and Design Expert software. The removals obtained was up to 26.1%, 29.9%, 56.9%, and 97.9% for COD ([COD]0=3,323 mg/L), TOC ([TOC]0=1,275 mg/L), ABS254nm (ABS0=32.2), and True color ([True color]0=3,467 mgPt-Co/L), respectively. Statistical and variance analysis of the experimental data revealed that one quadratic model obtained in Statistica was valid, ABS254nm reduction. However, by applying the Design Expert software, modified models were generated to predict the behavior of all dependent variables. Thus, the optimum point for the best response after ozonation of the landfill leachate was at the highest pH and the lowest ozone dose (9 and 2.2 mgO3/m3, respectively). Toxicity toward Allivibrio fischeri bacteria was abated at the same time that it decreased the impact of the effluent to Danio rerio fish (from 125 UT to 62 UT) on the treated leachate.

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Several environmental problems in Brazil are caused by the accelerated urban and industrial growth and by the multiplicity of urban waste generated. Waste disposal in landfills is still common practice in Brazil. This work was conducted in sand filters and activated carbon column, proposing an alternative for the physical-chemical treatment of leachate as a pre-treatment to preserve the biological process. The results showed reductions of up to 74% for COD, 47% for BOD5, 93% for color, 90% for ammonia and an increase from 0.3 to 0.9 in the BOD5/COD ratio. Although the results obtained do not fall within the limits of the legislation, the results for ammonia concentration was reduced by 33.25% and 85.37% after filtration and activated carbon column treatment respectively. The use of activated carbon columns resulted in an excellent performance in the reduction of heavy metals in the leachate. The performance demonstrated a removal of 60-96%. Limitations were found in the length of the filtration races, as a limiting factor in the process. The results show the potential of using direct upward filtration with sand and activated carbon filters for the treatment of landfill leachate.

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It is estimated that approximately 0.4% of the total leachate produced in a landfill is destined for treatment plants, while the rest can reach the soil and groundwater. In this context, this study aimed to perform leachate toxicity evaluations through immune system cytotoxic assessments, genotoxic (comet assay) appraisals and antioxidant system (superoxide dismutase - SOD; catalase - CAT, glutathione-S-transferase - GST; reduced glutathione - GSH and metallothionein - MT) evaluations in Eisenia andrei earthworms exposed to a Brazilian leachate for 77 days. The leachate sample contained high organic matter (COD - 10,630 mg L-1) and ammoniacal nitrogen (2398 mg L-1), as well as several metals, including Ca, Cr, Fe, Mg, Ni and Zn. Leachate exposure resulted in SOD activity alterations and increased CAT activity and MT levels. Decreased GST activity and GSH levels were also observed. Antioxidant system alterations due to leachate exposure led to increased malondialdehyde levels as a result of lipid peroxidation after the 77 day-exposure. An inflammatory process was also observed in exposed earthworms, evidenced by increased amoebocyte density, and DNA damage was also noted. This study demonstrates for the first time that sublethal effect assessments in leachate-exposed earthworms comprise an important tool for solid waste management.

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The necessity for landfill leachate treatment is a requisite to reduce the environmental impact related to municipal solid waste landfills and different aspects must be considered while deciding for an appropriate treatment process. For example, it was demonstrated that the landfill leachate stabilization in tropical regions is achieved right after its first year of operation, requiring technologies capable of treating leachates of a higher recalcitrant character if compared to those leachates from temperate regions and same landfill age. In view of its complexity and variability, stand-alone processes (either biological or physicochemical) are often ineffective in attaining the threshold values for its discharge in receiving bodies. Due to that fact, full-scale facilities have adopted integrated routes, harvesting the benefits of both biological and physicochemical processes. The implementation of membrane bioreactors followed by polishing membrane separation process (nanofiltration and reverse osmosis) seems to be a trend in leachate treatment by full-scale treatment plants. This technology is widely employed in China, European countries, and tropical countries as Brazil, generally with a treatment cost lower than the costs related to its disposal in domestic effluent collection systems. From the technologies already employed by full-scale facilities, four integrated routes were proposed for a sensitive analysis considering the treatment of a landfill leachate of different physicochemical characteristics. From all routes, those employing the membrane separation process as a polishing step had a better efficacy in attaining the threshold values for leachate disposal, being that an interesting alternative for leachate polishing by full-scale facilities.

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The sludges derived from the leachate treatment (LS) represent an important environmental and operational problem in the landfill management. On the other hand, they can be utilized as an alternative source of nutrients and organic matter. The main objective of this work was to evaluate the reuse of the LS of a sanitary landfill in Santa Fe city - Argentina, as an organic amendment for the development of Nicotiana alata L. plants. Different doses of LS were applied to a soil mixture for potted seedling growth. The response surface methodology was applied, using a one-factor design. Once the phenological stage of flowering began, the plants were harvested. Physiological and biochemical determinations were made in order to evaluate the effects of the different amendments. Application of LS notably improved growth parameters such as stem height, leaf area and dry matter. Additionally, the content of proteins and photosynthetic pigments was enhanced. Through the multiple regression statistical analyses, the relationship between the response variables and the sludge content was established. The multivariate optimization analysis yielded 53% as the optimal sludge content. Our results indicate that this sludge, in appropriate doses, can be used as an organic amendment for the revegetation of sanitary landfills.

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The leachate is a type of effluent from landfills containing high concentrations of ammonia, even after normal treatment procedures are applied. Due to its characteristic, the leachate can adversely impact the environment and public health. Leachate treatment seeks to remove a series of compounds with adverse characteristics present in this type of effluent. Ammonia nitrogen is the main problem, easily observed in concentrations near 2000 mg/L. The effluents with high concentrations of ammonia nitrogen can stimulate the growth of algae, reduce the dissolved oxygen in rivers, and cause toxicity on the aquatic biota, even in low concentrations. Many research for treatment methods aiming to remove this compound, specifically, have been increasingly deeper, mainly by physical-chemical processes. This study aimed to test the process of air stripping in a closed system and pilot scale, applied on leachate treatment of landfills, to remove the high concentrations of ammonia nitrogen and its recovery by the chemical absorption of ammonia on phosphoric acid, resulting in a product with potential application as agricultural fertilizer, the ammonia phosphate. The leachate flows used were 9, 18, 20, and 40 L/h, and the air flows were 1800 and 3600 L/h. Calcium carbonate (standard grade), commercial hydrated lime (CHL), and sodium hydroxide (standard grade) were used for pH adjustments. To the ammonia recovery, three flasks were used with 2.5 L of a phosphoric acid solution of 0.12 and 0.24 mol/L. The air stripping tower removed an average of 98% of ammoniacal nitrogen, with an operating time of 4 to 9 days. The volume of air consumed to remove 1 g of ammoniacal nitrogen varied from 9, 91, and 21.6 m3. The ammonia recovery was about 92% using a phosphoric acid solution, producing the ammonia phosphate.

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The reverse osmosis (RO) process has been increasingly applied to landfill leachate treatment. The published literature reports several studies that investigated the technical feasibility of RO. However, information about process costs is scarce. Also, companies that run leachate treatment plants do not provide actual costs. To fill this gap, this study aimed to evaluate the treatment costs of a full-scale RO for the treatment of landfill leachate located in Rio de Janeiro State, Brazil. A procedure was proposed to estimate the capital expenses (CAPEX), operational expenses (OPEX), and specific total treatment cost, the total cost per m3 of treated leachate, of the leachate treatment by membrane process, and the results obtained are discussed. The CAPEX for this full-scale RO was estimated at MUS$ 1.413, and OPEX ranged from US$ 0.132 to US$ 0.265 m-3 per year. The cost of leachate treatment has been estimated at US$ 8.58 m-3 considering the operation of the RO-unit for 20 years after landfill closure.

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The objective of this study was to evaluate the performance of the anaerobic co-digestion of different concentrations of industrial landfill leachate associated with crude residual glycerin, in relation to the methanogenic potential, COD removal, accumulated methane production, the effects of the factors (food/microorganism ratio and percentage of glycerin added to the leachate) and their interactions on kinetic parameters of methane production (CH4) using the modified Gompertz model. Co-digestion tests were carried out in bench scale (400 mL of useful volume) under batch mode at 30 ± 1°C during 30-day incubation of anaerobic sewage sludge as inoculum. The parameters glycerin addition to the leachate (v/v) (0%, 1.5%, 5%, 8.5% and 10%) and F/M ratio (0.3, 0.5, 1, 1.5 and 1.7) were investigated using Central Composite Rotational Design method (CCRD). The results indicated significant effect to the response variables: methanogenic potential, COD removal, accumulated production of CH4 and maximum estimated production of CH4, considering a confidence interval of 95% (p < .05). The ideal mixture of 95.13% of leachate with 4.87% of raw glycerin was obtained by desirability test to F/M of 1.61 gCOD of substrate per gVSS (volatile suspended solids) of sludge. Methanogenic potential was 0.19 LNCH4 gTVSrem -1, and the average removal of COD was 92%, resulting in accumulated production and maximum estimated production of CH4 of 74 and 80 mL, respectively. It was noted that the process of co-digestion of the industrial landfill leachate with the crude residual glycerin is promising, due to is potential of complementing and balancing organic materials, nutrients and other components that influence the biological process. Abbreviations: AN: ammoniacal nitrogen; BMP: biochemical methane potential; CCRD: central composite rotational design; COD: chemical oxygen demand; F/M ratio: food/microorganism ratio; FSS: fixed suspended solids; NTP: normal temperature and pressure; TSS: total suspended solids; TA: total alkalinity; TFS: total fixed solids; TKN: total Kjeldahl nitrogen; TP: total phosphorus; TS: total solids; TVA: total volatile acids; TVS: total volatile solids; VSS: volatile suspended solids; WWTP: wastewater treatment plant.

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RESUMO Neste trabalho, são apresentados os resultados do desempenho de dois sistemas de tratamento combinado de lixiviado de aterros sanitários e lodos de fossas. Na escala de laboratório, empregou-se um geobag de pequenas dimensões e um filtro biológico de percolação a jusante dele. Na escala real, investigou-se o desempenho de uma unidade de tratamento constituída de geobag seguido de lagoas de estabilização e wetland. Em ambos os estudos, empregou-se relação volumétrica de 4:1 (lodo de fossa:lixiviado) e adicionou-se floculante à mistura antes de sua alimentação no geobag. As remoções obtidas na unidade de campo foram superiores às alcançadas em laboratório para os parâmetros carbono orgânico dissolvido (COD) e sólidos em suspensão totais, cujas remoções foram superiores a 50 e a 95%, respectivamente. A remoção de nitrogênio amoniacal, entretanto, foi maior na instalação de bancada (68%). O desempenho desses sistemas de tratamento com relação à toxicidade para os organismos-teste Aliivibriofischeri, Daphniasimillis e Daniorerio também foi investigado.

ABSTRACT This paper presents the performance results of two combined landfill leachate and sewage sludge treatment systems. In the laboratory scale, a small geobag was followed by a trickling filter. In the real scale, the performance of a geobag treatment unit followed by stabilization and wetland lagoons was investigated. In both studies, a 4:1 volumetric ratio (pit sludge: leachate) was employed and flocculant was added to the mixture prior to feeding in the geobag. The field unit removals were higher than those obtained in the laboratory for the following parameters: dissolved organic carbon and suspended solids, whose removals were greater than 50 and 95%, respectively. Ammonium nitrogen was removed at higher percentages in the lab-scale unit (68%). The performance of both treatment units regarding toxicity to Aliivibriofischeri, Daphnia simillis and Danio rerio organisms was also investigated.

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ABSTRACT A set of experiments were carried out in order to establish and evaluate the potential of activated carbon, produced from coffee waste in adsorption process, in the depuration of landfill leachate. Different reagents were studied in the activation of carbon: HCl, HCl + H2O2, H3PO4, H3PO4 + H2O2, all with an impregnation rate of 1:1. The activated carbon that showed the best global results was activated with H3PO4, obtaining a 51.0, 32.8, 66.0, 81.0 and 97.1% elimination of chemical oxygen demand, ammonia, total chlorine, bromine and copper, respectively. This activated carbon has a total pore area of 4.85 m2/g and a median pore diameter of 65.32 micrometers. When different loads of this carbon were placed in a stirrer system in contact with landfill leachate, with the aim of evaluating the effect of the adsorption load and contact time, the concentration of ammonia decreased from the beginning of the adsorption process to the end of it, and the removal of ammonia increased with the increase in the adsorbent load. However, the trend of the amount adsorbed per unit mass decreased with increased dosage. The model Freundlich equilibrium isotherm fits experimental data adequately, giving R2 values of 0.95, 1/n of 0.5183, and a K value of 7.08*10-5 L/g, being favourable for adsorption process.

RESUMO Foi realizada uma série de experimentos para estabelecer e avaliar o potencial de carvão ativado produzido de resíduos de café por meio de um processo de adsorção na depuração do lixiviado de aterro sanitário. Foram estudados diferentes reagentes para a ativação do carvão: HCl, HCl + H2O2, H3PO4, H3PO4 + H2O2, todos com taxa de impregnação de 1:1. O carvão que apresentou os melhores resultados foi ativado com H3PO4, obtendo uma eliminação de 51,0; 32,8; 66,0; 81,0; e 97,1% de demanda química de oxigênio e concentração de amônia, cloro total, bromo e cobre, respetivamente. O referido carvão ativado tem uma área total de poro de 4,85 m2/g e diâmetro médio de poro de 65,32 micrômetros. Com o objetivo de avaliar o efeito da carga de adsorção e do tempo de contato, foram colocadas diferentes cargas desse carvão em um sistema de agitação em contato com o lixiviado de aterro sanitário. Observou-se que a concentração de amônia diminuiu e que sua remoção foi maior à medida que a carga adsorvente aumentava. No entanto, a quantidade adsorvida por unidade de massa diminuiu com o aumento da dosagem. Os dados experimentais adequaram-se corretamente ao modelo de isoterma de Freundlich, obtendo-se valores de R2 de 0,95, 1/n de 0,5183, e um valor de K de 7,08*10-5 L/g, considerados favoráveis para o processo de adsorção.