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The Matusagaratí wetland in the Panamanian Darien is one of the largest wetlands in Central America. These types of riverine wetlands, associated with large drainage basins, are complex hydrological environments where variations in water flows and exchanges condition the existence of different wetland habitats. The work aimed to establish the hydrological functioning of the Matusagaratí wetland in different sectors of the Balsas River, emphasizing the exchanges of surface and groundwater flows and the hydrological connectivity that exists between the different laterally linked wetland environments. For this purpose, a monitoring network for surface water and groundwater was established along transects intersecting various wetland environments in the middle and lower basin of the Balsas River. This network is complemented by measurement points for surface water located in streams and in the upper basin of the river. Data collected in sensors installed in boreholes were compared to river level and precipitation data. Continuous water level recording sensors were installed at the monitoring points, and samples were collected for the determination of major ions and stable isotopes. The results indicate that in the mangroves of the lower basin and in the cativo forests of the middle basin levee there is a strong exchange of water between the river and the shallow groundwater. This water exchange is strongly influenced by the tide which spreads from the estuary to the continent through the river. Meanwhile, in the middle basin, mixed forests and orey forests developed on the alluvial plain exhibit a hydrological functioning that depends primarily on precipitation inputs. This study provides data that could serve as a basis for the management of this large tropical wetland that, despite having protection initiatives, could be hydrologically impacted by unsustainable socio-economic practices.

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The hydrobiological diversity in the basin depends on biotic and abiotic factors. A predictive model of hydrobiological diversity for periphyton and macrobenthos was developed through multiple linear regression analysis (MLRA) based on the physicochemical parameters of water (PPW) and metal content in sediments (MCS) from eight monitoring stations in the Asana-Tumilaca Basin during the dry and wet seasons. The electrical conductivity presented values between 47.9 and 3617 µS/cm, showing the highest value in the Capillune River due to the influence of geothermal waters. According to Piper's diagram, the water in the basin had a composition of calcium sulfate and calcium bicarbonate-sulfate. According to the Wilcox diagram, the water was found to be between good and very good quality, except for in the Capillune River. The Shannon-Wiener diversity indices (H') were 2.62 and 2.88 for periphyton, and 2.10 and 2.44 for macrobenthos, indicating moderate diversity; for the Pielou's evenness index (J'), they were 0.68 and 0.70 for periphyton, and 0.68 and 0.59 for macrobenthos, indicating similar equity, in the dry and wet seasons, respectively, for both indices. In the model there were three cases, where the first two cases only worked with PPW or MCS, and case 3 worked with PPW and MCS. For case 3, the predicted values for H' and J' of periphyton and macrobenthos concerning those observed presented correlation coefficients of 0.7437 and 0.6523 for periphyton and 0.9321 and 0.8570 for macrobenthos, respectively, which were better than those of cases 1 and 2. In addition, principal component analysis revealed that the As, Pb, and Zn contents in the sediments negatively influenced the diversity, uniformity, and richness of the macrobenthos. In contrast, Cu and Cr had positive impacts because of the adaptation processes.

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Due to an increasing reduction of hydrological resources across Mexico and their growing contamination from global warming and anthropogenic activities, this study evaluated water from the perennial Lake Coatetelco (Ca-Mg-HCO3) in tropical central-southern Mexico and groundwater (Ca-Mg-HCO3 and Na-HCO3-Cl) from the surrounding wells for drinking as well as irrigation qualities. Comparison with the WHO guidelines and the estimated water quality indices (DWQI and IWQI) grouped almost all the samples collected after the warm season rainfall in excellent and good categories (DWQI < 100) for drinking, even though fluoride remained > 1.5 mg/L in 50% samples. Except for one groundwater sample, all showed > 25% permeability (classes I and II) in Donnen classification indicating their suitability for irrigation. USSL and Wilcox classifications, however, catalogued some in the high-salinity hazard group and some as doubtful for irrigating regular plants. Samples from about 53% wells were also in high and severe restriction categories of IWQI for the irrigation. Total Hazard Quotient Index (THQI) for estimating the non-carcinogenic risk (HQfluoride > 1) showed that at least one lake water sample and 53% of groundwater might expose the adult and child population to dental and skeletal fluorosis. This water quality assessment data posterior to the rainfall season could be useful as a baseline for both the short- and long-term monitoring in attention to the United Nation's Sustainable Development Goal 6.

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An increase in the frequency of severe hydrological events has highlighted the importance of sustainable water management in intensive agricultural regions. In a warming climate, improved understanding and stewardship of water resources are needed to guarantee water supply, ensure food security, and build resilience against extreme events. In this study, we evaluate a framework that combines spectral analysis and geochemical tracers as a potential tool for (1) gaining valuable insights into surface water (SW)-groundwater (GW) interactions, and (2) providing guidance for improved water management in an intensive agricultural basin in southern Guatemala. The framework proves to be useful in revealing important water dynamics, exposing key feedback mechanisms for water availability and quality. With the use of power density functions and hydrochemistry (T, pH, EC, and major ions), two specific interaction regimes (influent and effluent) were identified and delimited for the main watercourse. These segments are estimated to interact at high rates with the shallow aquifer in the river channel proximities and would lose influence towards the basin flanks. Furthermore, the δ2H and δ18O values indicate that regional groundwater flow systems play an essential role in the basin groundwater recharge. Lastly, we established three influence zones that depict the spatial extent of the SW-GW interactions within the basin. With these zones, we provide recommendations that will allow for further investigation and application into better water management strategies regulating groundwater development and land use activities within the agricultural context of the area.

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This work was conducted at the Pardo River hydrographic basin, which is a federal watershed belonging to the Paranapanema River hydrographic basin (PRHB) in Brazil (São Paulo State and Paraná State). The aim was to realize an integrated hydrochemical and radiometric (U-isotopes and 210Po) approach, highlighting the water/soil-rock and surface water/groundwater interactions, with implications to the weathering processes occurring there. The study area has been often considered one of the best preserved/unpolluted river in São Paulo State, contributing to the water supply of several cities distributed along its banks. However, the results reported here suggest possible lead diffuse pollution caused by the use of phosphate fertilizers in agricultural activities taking place in the basin. The analyzed groundwaters and surface waters tend to be neutral to slightly alkaline (pH of 6.8-7.7), possessing low mineral concentration (total dissolved solids up to 500 mg/L). SiO2 is the major dissolved constituent in the waters, while bicarbonate is the dominant anion, and calcium is the preponderant cation. The effects of the weathering of silicates to control the dissolution of constituents in the liquid phase have been identified from some diagrams often utilized in hydrogeochemical studies. Chemical weathering rates have been estimated from hydrochemical data associated to analytical results of the natural uranium isotopes 238U and 234U concerning to samples of rainwater and Pardo River waters. The fluxes in this watershed are permitted to obtain the following rates: 11.43 t/km2 year (sodium), 2.76 t/km2 year (calcium), 3.17 t/km2 year (magnesium), 0.77 t/km2 year (iron), and 8.64 t/km2 year (uranium). This new dataset constitutes valuable information for people engaged on the management of the Pardo River watershed, as well as to researchers interested on comparative studies considering the available data from other basins worldwide.

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A hydro-geochemical characterization was conducted in the northern part of the Sonora River basin, covering an area of 9400 km2. Equipotential lines indicated that groundwater circulation coincided with the surface water flow direction. Based on the groundwater temperature measured (on average ∼21 °C), only one spring exhibited thermalism (51 °C). Electrical conductivity (160-1750 µS/cm), chloride and nitrate concentrations (>10 and >45 mg/L) imply highly ionized water and anthropogenic pollution. In the river network, δ18O values revealed a clear modern meteoric origin. Focused recharge occurred mainly from the riverbeds during the rainy season. During the dry season, diffuse recharge was characterized by complex return flows from irrigation, urban, agricultural, mining, and livestock. Drilled wells (>50 m) exhibited a strong meteoric origin from higher elevations during the rainy season with minimal hydrochemical anomalies. Our results contribute to the knowledge of mountain-front and mountain-block recharge processes in a semi-arid and human-altered landscape in northern Mexico, historically characterized by limited hydrogeological data.

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Arsenic enrichment in groundwater resources in deltas and floodplains of large sediment-rich rivers is a worldwide natural hazard to human health. High spatial variability of arsenic concentrations in affected river basins limits cost-effective mitigation strategies. Linking the chemical composition of groundwater with the topography and fluvial geomorphology is a promising approach for predicting arsenic pollution on a regional scale. Here we correlate the distribution of arsenic contaminated wells with the fluvial dynamics in the Amazon basin. Groundwater was sampled from tube wells along the Amazon River and its main tributaries in three distinct regions in Peru and Brazil. For each sample, the major and trace element concentrations were analyzed, and the position of the well within the sedimentary structure was determined. The results show that aquifers in poorly weathered sediments deposited by sediment-rich rivers are prone to mobilization and accumulation of aqueous arsenic and manganese, both in sub-Andean foreland basins, and in floodplains downstream. Two zones at risk are distinguished: aquifers in the channel-dominated part of the floodplain (CDF) and aquifers in the overbank deposits on the less-dynamic part of the floodplain (LDF). Some 70 % of the wells located on the CDF and 20 % on the LDF tap groundwater at concentrations exceeding the WHO guideline of 10 µg/L arsenic (max. 430 µg/L), and 70 % (CDF) and 50 % (LDF) exceeded 0.4 mg/L manganese (max. 6.6 mg/L). None of the water samples located outside the actual floodplain of sediment-rich rivers, or on riverbanks of sediment-poor rivers exceed 5 µg/L As, and only 4 % exceeded 0.4 mg/L Mn. The areas of highest risk can be delineated using satellite imagery. We observe similar patterns as in affected river basins in South and Southeast Asia indicating a key role of sedimentation processes and fluvial geomorphology in priming arsenic and manganese contamination in aquifers.

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The physicochemistry and production rate of drinking water treatment residuals (DWTRs) depends on the raw water composition and the plant operational parameters. DWTRs usually contain Fe and/or Al oxyhydroxides, sand, clay, organic matter, and other compounds such as metal(oids), which are relevant in mining countries. This work proposes a simple approach to identify DWTRs reuse opportunities and threats, relevant for public policies in countries with diverse geochemical conditions. Raw water pollution indexes and compositions of DWTRs were estimated for Chile as a model case. About 23% of the raw drinking water sources had moderate or seriously contamination from high turbidity and metal(loid) pollution If the untapped reactivity of clean DWRTs was used to treat resources water in the same water company, the 73 and 64% of these companies would be able to treat water sources with As and Cu above the drinking water regulations, respectively. Integrating plant operational data and the hydrochemical characteristics of raw waters allows the prediction of DWTRs production, chemical composition, and reactivity, which is necessary to identify challenges and opportunities for DWTRs management.

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This work was conducted at Araxá city, Minas Gerais State, Brazil. The aim was to characterize by different approaches weathering rates at six watersheds occurring there. The study area is well-known in the country due to economic and touristic reasons. Beginning in the 1960's and 1970's, nowadays huge mining activities for niobium and phosphate fertilizer exploitation by different companies are taking place there along with the use of natural mineral waters for health treatment, following a tradition that started in the 19th century for tuberculosis treatment. The dataset utilized in this investigation comprised results obtained in the analysis of distinct geochemical compartments, i.e. rocks, soils, bottom sediments, rainwater and surface waters from small hydrographic basins. The waters of three catchments are extensively used by water-supply systems of Araxá city in order to meet the demand of this resource as a possible supply of drinking water for the local community. Hydrochemical (major and trace constituents) and radionuclides (238U, 234U, and 210Po) analyses of rainwater and water bodies samples allowed estimates of the fluxes in each drainage. These fluxes were subtracted from rainfall deposition, yielding positive net values only for bicarbonate and U-isotopes as natural tracers in all watersheds, which allowed to calculate chemical weathering rates of 2.6-38.9 ton/km2yr (bicarbonate) and 0.09-19.8 ton/km2yr (U-isotopes). Physical weathering rates were obtained from 210Pb data in bottom sediments and exceeded 200 to 1.3 × 105 times the chemical weathering rates evaluated by the U-isotopes approach, a finding compatible with others reported in literature but adopting a diverse conceptual framework. Thus, the development of all analytical protocols along this investigation permitted an integrated appraisal of distinct approaches applied to the same selected site, as well as a comparison of weathering rates with other values reported in the literature, improving the knowledge about this subject in Araxá city watersheds. The novel dataset reported in this paper constitutes an aid to the already existing number of weathering rates elsewhere, helping modellers engaged on predicting future landscape changes.

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Mountains arid environments are vulnerable under climate change scenarios. Variations in the recharge sources and the rising temperature can affect the water availability, threaten the socio-productive systems on local and regional scales. In this sense, two hydrological systems were studied in the Andes Range, Argentina, by hydrochemical and isotope techniques, with the purpose to understand the origin of water, the groundwater recharge, and to conceptualize the groundwater flow system. In the two sampling periods (winter and summer seasons) most of the waters were characterized by low mineralization and a HCO3-Ca type. The isotopic composition showed wide ranges of variation consistent with the altitudinal differences existing in the study systems. However, no significant isotope changes were observed between the samples collected in winter and summer periods. Therefore, little influence of liquid precipitation is inferred in the recharge source of both hydrological systems. This means that the western sector of the valley, where the ice bodies and permafrost are located, is the main recharge area for groundwater of both basins. This confirms the former hypothesis used for the hydrogeochemical conceptual model proposed, and highlights the importance of protecting these environments to ensure the provision of water in arid lands.

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The Argentine Atlantic coast constitutes an extensive area where numerous wetlands develop under humid, semi-arid and arid conditions, in which there are also variations in relation to tidal influence with estuarine, mixing and marine areas. The aim of this work is to conduct a comparative study on the processes controlling the groundwater salinity in medium to high latitudinal coastal wetlands of four natural reserves with contrasting hydrological and climatic conditions. In each study area a monitoring network was established where the content of CO32-, HCO3-, Cl-, SO42-, Ca2+, Mg2+, Na+, K+, δ2H and δ18O of the water were determined. The results show a saline groundwater increase along a latitudinal gradient with electrical conductivities varying from 0.3 mS/cm at 34°47' S to 154 mS/cm at 42° 25' S. The results obtained show that the ionic contents in groundwater are partially controlled by the salinity of the tidal flood water whose electrical conductivity varies from 0.3 mS/cm in the Río de la Plata estuary to 52 mS/cm in the sea water of the southern study area. In the southern wetlands, where an increase of aridity is also registered, there is a clear increase in groundwater ionic concentrations, which occurs without isotopic enrichment indicating processes of salts dissolution of the sediments. The evaporites precipitation occurs due to the total evaporation of the tidal water that floods the wetlands in spring high tides. The salinization of groundwater responds to natural processes inherent to the hydrological, climatic and lithological characteristics of each wetland. Given that the areas studied correspond to natural reserves, the results generate databases that will allow the identification of future changes in salinity associated with anthropic influences or changes in hydrological and/or climatic conditions as a result of climate change.

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The implications of land use change in small watersheds through the conversion of forests to agropastoral areas have altered the natural nutrient cycle, intensifying exports under freshwater ecosystems. This study aimed to investigate the land use effects on nutrient and sediment exports in two small watersheds in northeastern Brazil to understand if anthropogenic disturbance alters the structure end functioning of these systems. Thus, land use mapping and hydrological treatment of a digital elevation model were made to characterize the basins. Water samples were collected monthly from Aug. 2016 to Jan. 2017 to evaluate suspended sediments and dissolved nutrient fluxes ([Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], and dissolved organic nitrogen and phosphorus). The results indicated that land use change had a greater influence on exports from the most disturbed basin, where the nutrient and sediment increments were respectively an average 6.61 and 5.81 times higher than the most preserved basin. Thus, the conservation status of the forest cover has influenced the assimilation capacity of diffuse loads, highlighting the differences between the microbasins of this study.

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In the eastern region of central Costa Rica, land use in the sub-basins of the Maravilla-Chiz and Quebrada Honda rivers (47 km2) is dominated by agricultural and livestock production, while groundwater resources constitute the main drinking water supply. This study aimed to (a) evaluate the location of groundwater recharge areas and groundwater flow paths, and (b) provide a characterization of the hydrochemistry and possible anthropic impacts. Groundwater was collected from 20 sites during the dry and rainy seasons and analysed for major ions, water stable isotopes and 222Rn. Approximated recharge areas were estimated through a local altitudinal line based on isotopic compositions in springs. The hydrochemical and isotopic characterization of groundwater showed that the main recharge areas occur in the upper part of the basin, except for springs in the middle part of the basin probably due to a certain hydraulic disconnection from the upper part that facilitates local recharge processes. In the lower basin, groundwater exhibited greater transit times and longer flow paths. Low nitrate, chloride and sulphate concentrations found in groundwater indicate low leaching of fertilizers or urban wastewaters. Our results are focused to improve water resources and agricultural management plans in a dynamic tropical landscape.

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Groundwater represents almost half of the drinking water worldwide and more than one third of water used for irrigation. Agro-industrial activities affect water resources in several manners; one of the most important is leaching of agrochemical residues. This research identifies the major contributors of changes in groundwater quality comparing two contrasting land uses in a karstic area of the Yucatan peninsula as case study. Using a multiple approach, we assess the impact of land use with physicochemical data, multivariate analyses, hydrogeochemistry and nitrate isotopic composition. We confirmed that agricultural land use has a greater impact on groundwater quality, observed in higher concentration of nitrates, ammonium, potassium and electrical conductivity. Seasonality has an influence on phosphates and the chemical composition of the groundwater, increasing the concentration of dissolved substances in the rainy season. There was a clear effect of manure application in the agricultural zone and the nitrate isotopic composition of groundwater points toward recharge in certain areas. We consider that seasonality and land use effects are intertwined and sometimes difficult to separate, likely because of land use intensity and hydrogeochemical process at a local scale. Finally, we observed poor groundwater quality in the agricultural area during the wet season; thus, it is desirable to maintain non-agricultural areas that provide groundwater of appropriate quality.

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Arsenic (As) is an important component in thermal springs, which can reach water sources constituting an important hazard for both the environment and people. For this reason, the aim of this paper is to analyze the geologic and geochemical processes that determine the presence and concentration of As in wet-meadows associated to a geothermal field in Patagonia (Argentina) which is used as water supply. To achieve this, during field surveys temperature, pH and electrical conductivity were measured and water and rock samples were taken. Major ions and stable isotopes were determined in water samples while As content was analyzed in both water and rock samples. Due to geological control and chemical analyses, three areas were recognized with respect to major streams in the geothermal field: wet-meadows at headwaters, thermal springs at mid basin and wet-meadows at down basin. Even though, water in wet-meadows have the same origin the obtained results evidence how thermal springs at mid-basin influence the chemistry of these wetlands, particularly those at down basin. In the latter, As raises over two orders of magnitude than the ones at headwaters which surpasses the reference limit, proving that thermal springs are also responsible for the increase of the As content in water changing its quality as a source of potable water. The concentration of this metalloid could be higher but it is retained in travertine and sinter deposits formed near the geothermal discharge area. Understanding processes controlling water quality and the chemistry of As in this type of wetlands is of vital importance, mainly in an arid region where water supply sources are scarce.

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Spatial patterns, cluster or dispersion trends are statistically different from random patterns of trace elements (TEs), which are essential to recognize, e.g., how they are distributed and change their behavior in different environmental processes and/or in the polluted/contaminated areas caused by urban and industrial pollutant located in upstream basins and/or by different natural geological conditions. The present study focused on a statistical approach to obtain the spatial variability of TEs (As, B and Sb) in shallow groundwater (GW) in a high-altitude arid region (Lower Katari Basin, Bolivian Altiplano), using multivariate analysis (PCA and HCA), geochemical modeling (PHREEQC, MINTEQ) and spatial analyses (Moran's I and LISA), considering the community supply wells. The results indicate that despite of the outliers there is a good autocorrelation in all cases, since Moran's I values are positive. The global spatial dependence analysis indicated a positive and statistically significant spatial autocorrelation (SA) for all cases and TEs are not randomly distributed at 99% confidence level. The results of hydrochemical modeling suggested the precipitation and stability of Fe (III) phases such as goethite. The re-adsorption of As and Sb on the mineral surface in the aquifer could be limiting the concentrations of both metalloids in southern regions. Spatial autocorrelation was positive (High-High) in northwestern (arsenic), southeastern (boron) and northeastern (antimony) region. The results reflected that the As and Sb are the main pollutants linked to the natural geological conditions, but B is a main pollutant due to the anthropogenic activities. Furthermore, >50% shallow groundwater exceeded the WHO limit and NB-512 guideline values for Sb (87%), B (56%) and As (50%); therefore the spatial distribution and concentrations of these TEs in GW raise a significant concern about drinking water quality in the study area.

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Occurrences of high arsenic (As) in sediments and groundwaters were investigated in the Claromecó fluvial basin, southern Pampean plain, Argentina. This investigation includes sedimentology, mineralogy, and hydrogeochemistry of the Neogene and Quaternary aquifers to determine possible sources and transport mechanisms for As in the Claromecó basin. Characterization of the sediments revealed homogeneous mineralogy in both Neogene highlands and Quaternary floodplains with abundant plagioclase, volcanic glass shards (VGS), K-feldspar, quartz, clay minerals and minor concentrations of clinopyroxenes, orthopyroxenes, hornblende, epidote, Fe-(oxy)hydroxides and fluorapatite. The sedimentary As concentrations ranged between 2.8 and 31 mg kg-1 in both aquifers. The average total dissolved As (dissolved AsT) concentrations was 47.2 ±â€¯30.8 µg L-1 (15.3-110 µg L-1) in groundwater in Neogene aquifer (GW1), while it was 97.1 ±â€¯30.6 µg L-1 (45-144 µg L-1) in Quaternary floodplain aquifer (GW2), with all samples exceeding WHO's guideline for dissolved AsT in safe drinking water of 10 µg L-1. Some GW1 (33%) and all GW2 samples contained high levels of fluoride (F-) ranging from 0.6 to 2.6 mg L-1 (1.37 ±â€¯0.59 mg L-1) in GW1 and 2 to 5 mg L-1 (3.2 ±â€¯0.9 mg L-1) in GW2 which also exceeded WHO's guideline for F- in safe drinking water of 1.5 mg L-1. Elevated concentrations of Na+, Cl- and SO42- in the Quaternary flood plain groundwater (GW2) could indicated some degree of sea water mixing as well as some contribution from inland processes (e.g. high evapotranspiration rates, long residence time and soil-water interactions). Dissolution of As bearing VGS or Fe-(oxy)hydroxides, alkaline desorption or competitive desorption with HCO3- from Fe-(oxy)hydroxides appear to be dominating processes of As mobilization, while desorption from fluorapatite elevate dissolved F- levels. This study provides valuable insights on As mobilization processes in Neogene and near coast Quaternary floodplain aquifer.

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Despite the growing progress in the construction of underground dams, there are few studies to evaluate and monitor these reservoirs after their construction. Thus, a research study was carried out to evaluate the water table level in alluvial aquifers and water salinity in four underground dams selected in the Cobras river basin, Parelhas municipality, Rio Grande do Norte. Water level variation was monitored using the traditional method and the Ground Penetrating Radar with generation of 3D virtual models. Water samples were collected between the months of December 2010 and December 2011 for electrical conductivity analysis. The results indicate that the accumulation of groundwater and salinity (expressed by electrical conductivity) in the reservoirs were affected by the spatial position within the hydrographic basin (limited occurrence of alluvial aquifer recharge area in headwater sectors) and the presence of surface reservoirs (upstream dams), which promote a more continuous recharge, greater renovation, and reduction of the salinity of the waters of the alluvial aquifer downstream.

Apesar do crescente avanço na construção de barragens subterrâneas, há poucos estudos de avaliação e monitoramento das barragens subterrâneas após a sua construção. Assim, foi realizada uma pesquisa com o objetivo de avaliar a salinidade da água e a variação do nível freático em aquífero aluvial em quatro barragens subterrâneas selecionadas na microbacia do rio das Cobras, município de Parelhas, RioGrande do Norte. As amostras de água foram coletadas entre os meses de dezembro de 2010 a dezembro de 2011 para análise da condutividade elétrica. A variação do nível da água foi monitorada utilizando método tradicional e o Ground Penetrating Radar com geração de modelos virtuais 3D. Os resultados indicam que a acumulação da água subterrânea e a sua salinidade (expressa pela condutividade elétrica) nos reservatórios foram afetadas pela posição espacial dentro da bacia hidrográfica (ocorrência limitada de área de recarga do aquífero aluvial em setores de cabeceiras do rio) e pela presença de reservatórios superficiais (açudes à montante), os quais promovem uma recarga mais contínua, maior renovação, e redução da salinidade das águas do aquífero aluvial à jusante.

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Environmental liabilities have become one of the most important problems of the last years, especially those of contaminated sites located in urban areas which have been abandoned by pollution intensive industries. Such sites may contain hazardous materials that pose risks to human health and the environment. Industrial waste from the ancient sulfuric acid industry is scattered in a local area at the petrochemical pole in a sector of the Río de la Plata coastal plain. The aim of this work is to define the geochemical processes that determine the alteration of waste in the old sulfuric acid industry (OSAI) area and to study the migration of soluble pollutants to groundwater. A survey of soil and waste deposit was carried out and samples were examined by X-ray diffraction, under a scanning electron microscope and a polarizing microscope. Surface water and groundwater samples, both to the unconfined and semi-confined aquifers, were collected to determine electrical conductivity, pH and major elements. The results show the presence of minerals composed of sulfur associated with jarosite and iron oxides on superficial sediments. The detailed study of soil sediments together with that of the water physicochemical characteristics make it possible to understand the geochemical processes developed in soil that cause the high concentrations of sulfates in groundwater. Furthermore, high SO4-2 concentration registered in the semi-confined aquifer due to its infiltration from the unconfined aquifer shows that the industrial pollution has an important impact at local level. These results may contribute to the understanding of chemical processes and pollutants distribution in highly industrialized coastal plain areas.

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This case study examines the geological imprint and land use practices on water quality in the arid Huasco Valley against the backdrop of ongoing water conflicts surrounding competing demands for agriculture and mining. The study is based on a detailed analysis of spatial and temporal variations of monthly surface and bi-monthly groundwater quality samples measured during the Chilean summer of 2015/16. Additional information on source regions and river-groundwater interactions were collected using stable water isotopes. Regarding the geological impact on water quality, high concentrations of Ca2+, SO42- and HCO3- indicate a strong influence of magmatic rocks, which constitute this high mountain basin, on the hydrochemistry. Piper and Gibbs-diagrams revealed that all samples show a homogenous distribution dominated by rock-water interactions. Measured NO3- concentrations in surface water are generally low. However, groundwater aquifers exhibit higher concentrations. Mn is the only heavy metal with elevated concentrations in surface water, which are possibly related to mining activities. The results illustrate that both surface and groundwater can be classified as suitable for irrigation. In addition, groundwater has been found to be suitable as drinking water. High similarities in isotopic signatures indicate a strong connection between surface and groundwater. Isotopic analyses suggest a strong influence of evaporation. This combined approach of hydrogeochemical and isotopic analysis proved to be a helpful tool in characterizing the catchment and can serve as a basis for future sustainable water management.

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