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This work was conducted at the Pardo River hydrographic basin, which is a federal watershed belonging to the Paranapanema River hydrographic basin (PRHB) in Brazil (São Paulo State and Paraná State). The aim was to realize an integrated hydrochemical and radiometric (U-isotopes and 210Po) approach, highlighting the water/soil-rock and surface water/groundwater interactions, with implications to the weathering processes occurring there. The study area has been often considered one of the best preserved/unpolluted river in São Paulo State, contributing to the water supply of several cities distributed along its banks. However, the results reported here suggest possible lead diffuse pollution caused by the use of phosphate fertilizers in agricultural activities taking place in the basin. The analyzed groundwaters and surface waters tend to be neutral to slightly alkaline (pH of 6.8-7.7), possessing low mineral concentration (total dissolved solids up to 500 mg/L). SiO2 is the major dissolved constituent in the waters, while bicarbonate is the dominant anion, and calcium is the preponderant cation. The effects of the weathering of silicates to control the dissolution of constituents in the liquid phase have been identified from some diagrams often utilized in hydrogeochemical studies. Chemical weathering rates have been estimated from hydrochemical data associated to analytical results of the natural uranium isotopes 238U and 234U concerning to samples of rainwater and Pardo River waters. The fluxes in this watershed are permitted to obtain the following rates: 11.43 t/km2 year (sodium), 2.76 t/km2 year (calcium), 3.17 t/km2 year (magnesium), 0.77 t/km2 year (iron), and 8.64 t/km2 year (uranium). This new dataset constitutes valuable information for people engaged on the management of the Pardo River watershed, as well as to researchers interested on comparative studies considering the available data from other basins worldwide.

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210Po and 210Pb activity concentrations in spas groundwaters occurring at São Paulo (SP) and Minas Gerais (MG) states, Brazil, have been reported in this paper with a dual purpose: to compare different indices for evaluating the radionuclides mobility into waters and to evaluate the drinking water quality from dose calculations. The waters (75 sampling points) are extensively used for drinking in public places, bottling and bathing purposes, among other. The samples were taken from springs and wells drilled at different aquifer systems inserted in Paraná and Southeastern Shield hydrogeological provinces. The WHO guideline reference value for 210Pb and 210Po of 0.1 Bq/L in drinking water was not reached for 210Pb but the 210Po levels were equal or above it in four spas groundwaters from MG State. The maximum WHO guidance dose level of 0.1 mSv/yr was also reached or surpassed in them. The 210Pb "mobility index" taking into account the ratio of the weight of the dissolved 210Pb per unit volume of solution to its weight per unit weight of the rock matrix yielded values in the range of 0.01-5.2 kg/m3. Another "mobility index" (Preference Ratio) expressing the ratio of 210Pb and 238U in the waters divided by the ratio of 210Pb and 238U in the rock matrices provided values between 0.004 and 7994. The 210Pb/238U activity ratios of some spas groundwaters suggested preferential 238U transport relative to 210Pb into the liquid phase, whereas the ratio of the 210Pb to 238U mobility indices indicated the opposite. Such finding showed a better usefulness of the mobility indices for evaluating processes affecting the radionuclides release into the liquid phase during the water/rock interactions.

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This paper describes the natural radioactivity due to 238U and 234U in 75 water sources from spas located in 14 municipalities in São Paulo and Minas Gerais states, Brazil. These waters are extensively utilized for drinking in public places, bottling and bathing purposes, among other uses. The water samples were taken from springs and pumped tubular wells drilled into different aquifer systems in the Paraná and Southeastern Shield hydrogeological provinces. The measurements of alpha-emitting radionuclides were also accompanied by the monitoring of temperature, pH, Eh, electrical conductivity, dissolved gases (O2, CO2, H2S, radon, thoron) and major constituents. The dissolved U concentration data were lognormally distributed. The median and mean values corresponded to 0.02 and 0.09 µg/L, respectively. Significant relationships were found among the 234U/238U activity ratio (AR) of dissolved uranium, the total dissolved solids (TDS) and dissolved bicarbonate contents, and also between the AR and dissolution rate in the monitored sites. The logU versus AR diagram used for the hydrogeochemical prospecting of concealed U deposits indicated that the water sources were mainly from reduced environments. The possibility of using the reciprocal of the dissolved U concentration and AR data to determine mixing volumes of different groundwater masses was demonstrated. The highest dissolved U concentration (4.82 µg/L) was well below the maximum allowed by WHO.

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No Brasil, a maior parte das fontes de água apresenta baixa concentração de flúor; entretanto, foram identificadas localidades onde estes valores estavam acima do recomendado como ideal para o consumo humano, ocasionando o surgimento do primeiro sinal clínico da intoxicação crônica por este elemento, a Fluorose dentária. O objetivo deste estudo foi conhecer o teor de flúor presente na água de 175 poços superficiais que abastecem as residências dos moradores da zona rural do município de Gabriel Monteiro/SP, em 2004. De posse de um mapa do município, foram localizadas e visitadas todas as residências nas quais uma amostra da água utilizada foi coletada em frasco de polietileno, posteriormente encaminhados para o laboratório do Núcleo de Pesquisa em Saúde Coletiva (NEPESCO) do Programa de Pós-graduação em Odontologia Preventiva e Social da Faculdade de Odontologia de Araçatuba ­ Universidade Estadual Paulista (FOA - UNESP) para análise do teor de flúor. O método utilizado foi o eletrodo específico para íon flúor (Orion 9609 BN) acoplado a um analisador de íons (Orion 710 A). Os resultados evidenciaram que em 71,36% das amostras a concentração de flúor é considerada desprezível (< 0,10 ppm F- ). A concentração de flúor presente nas fontes de água não ultrapassam os valores recomendados pela legislação brasileira, no entanto, considerando-se as baixas concentrações de flúor encontradas nas fontes analisadas, é importante que seja recomendado o emprego de produtos Fluoretados, desde que utilizados com os devidos cuidados, visando a promoção de saúde bucal desta população.

Most of the water supplies in Brasil have a low Fluoride concentration, however there are some places where these concentrations are above the recommended as suitable for human consumption, causing chronicle intoxication, more specifically, dental Fluorosis. This study aimed to know the Fluoride content naturally present in water from 175 shallow wells located in the rural zone of Gabriel Monteiro city, in São Paulo state, in 2004, and to verify if these contents could prevent dental decay. Armed with a map of the city were located and visited all households in which a sample of water used was collected in a polyethylene bottle, then sent to NEPESCO (Collective Health Research Nucleus) laboratory of the Post-Graduation Program of Preventive and Social Dentistry of the Araçatuba Dental School-UNESP, The method used was the Fluoride ion-specific electrode (Orion 9609 BN), coupled to an ion-analyzer (Orion 710 A). The results showed that in 73.36% of the samples in the Fluoride concentrations was considered despicable (< 0.10 ppm F). The Fluoride concentration in water sources do not exceed the values recommended by Brazilian legislation, however, considering the low concentrations of Fluoride found in the sources analyzed, it is important to recommend the use of Fluoride products, if used with proper care, aiming to promote oral health in this population.

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