RESUMO

The development of techniques to improve the welding of super duplex steels is necessary in order to ensure that the phase balance and properties of the material are not affected during this process. Hybrid arc-laser welding is a perfect combination of the advantages of both processes, producing deeper weld beads with more balanced phases than the pulsed laser process. Here, the objective was to improve the corrosion resistance of UNS S32750 weld beads by increasing the volumetric austenite percentage in the fusion zone (FZ) with a hybrid process of GTAW (gas tungsten arc welding) and pulsed laser Nd-YAG (neodymium-doped yttrium aluminum garnet). Welds were performed in bead on plate conditions with fixed laser parameters and a varying heat input introduced through the GTAW process. Additionally, welds within a nitrogen atmosphere were performed. After base metal characterization, an analysis of the FZ and heat affected zone were performed with optical microscopy, scanning electron microscopy and critical pitting tests (CPT). The synergy between the thermal input provided by the hybrid process and austenite-promoting characteristic of nitrogen led to a balanced volumetric austenite/ferrite fraction. Consequently, the results obtained in CPT tests were better than conventional welding processes, such as laser or GTAW solely.

RESUMO

A non-isothermal transformation model was proposed to determine the austenite formation kinetics in a steel alloyed with 2.6% wt. Si by dilatometric analysis, considering that the nucleation mechanism does not change with the heating rate. From the dilatometric analysis, it was observed that the austenite formation occurs in two stages; critical temperatures, degree and austenite formation rate were determined. The activation energies associated with each of the stages were obtained employing the Kissinger method (226.67 and 198.37 kJ·mol-1 for the first and second stage) which was used in concert with the austenite formation rate in the non-isothermal model as a first approximation, with acceptable results in the second stage, but not in the first due to the activation energies magnitude. Then, the activation energies were adjusted by minimizing the minimal squares error between estimated and experimental austenite formation degree, obtaining values of 158.50 kJ·mol-1 for the first and 165.50 kJ·mol-1 for the second stage. These values are consistent with those reported for the diffusion of carbon in austenite-FCC in silicon steels. With these activation energies it was possible to predict the austenite formation degree with a better level of convergence when implementing the non-isothermal model.

RESUMO

OBJECTIVES: This study aims to evaluate the effects of cyclic loading on the bending moments and the developed stress state of austenitic and R-phase endodontic files through finite element analysis. MATERIALS AND METHODS: The mechanical properties of two groups of NiTi wires, austenite and R-phase, were measured in samples at two different conditions: uncycled and cycled. The cycled condition was achieved by subjecting samples of the two groups to 80% of the corresponding fatigue life under rotating bending efforts. The measured mechanical properties were then used in the finite element analysis, where the boundary and loading conditions were set to replicate a standard bending test. RESULTS: The results showed that mechanical cycling leads to decreasing stress levels and bending moments in the simulated files, especially in the austenitic ones. In comparison with austenite, R-phase presented a more stable mechanical behavior during cycling. CONCLUSIONS: The results show that the moment and stress calculated for an instrument under bending can be considerably decreased after some cyclic work. CLINICAL RELEVANCE: The fatigue related to the clinical use of an endodontic file decreases the moment (as well as the forces) imposed by the instrument during the shaping of a curved root canal. This decrease is directly related to the type of atomic array present in the alloy.

Assuntos

Ligas Dentárias , Titânio , Desenho de Equipamento , Fadiga , Análise de Elementos Finitos , Humanos , Teste de Materiais , Preparo de Canal Radicular , Estresse Mecânico

RESUMO

Following the first and second generations, the challenge in obtaining a better balance between strength and elongation is still the main characteristic of the third generation of advanced high-strength steels (AHSS). With this, the use of multiphase microstructures has increased over the last few years. It can be difficult to characterize all the phases with only optical microscopy (OM), so the use of scanning electron microscopy (SEM) is essential for accuracy in cases where researchers lack experience. To expand the possibilities, this research proposed a new approach that would allow experienced researchers to characterize multiphase steels using only OM. A high silicon steel was austempered slightly below martensite start (Ms) temperature for three different time periods in order to obtain different quantities of martensite, bainite and retained austenite. X-ray diffraction was carried out in order to confirm and obtain retained austenite volume fractions, and the results indicated that shorter holding times were not enough to enrich and stabilize retained austenite. Then, each samples was etched with four different etchants. Results showed that the new multiple etchings methodology (MEM) allowed a better visualization of all the phases when viewed together. Beraha martensitc revealed nontempered martensitic microstructures. Sodium metabisulfite revealed retained austenite. LePera and Nital were the best at revealing the evolution of the microstructure over time, even with the changes which occurred due to martensite tempering. SEM images confirmed the results obtained via MEM. LAY DESCRIPTION: For improving safety, environmental protection, mechanical resistance and others issues, many different steel grades have been studied. These grades were named depending on their mechanical properties. The current generation is the third, which is still searching for one of the main antagonists in material science: the best balance between mechanical resistance (how strong it is) and elongation (how long it can be stretched to). In order to achieve this goal, many researchers are studying variations in the production processes. During production, the materials are able to internally change their basic microstructure, named phases. In the past, steels were usually produced to have only a few phases. Today's advanced high strength steels (AHSS) can have many. Each of these phases has its own characteristics. The main focus of this research was to give a new way of identify these phases using an optical microscope. For revealing these phases, etchants are normally used. The etchants used in this research are capable of tinting each of these phases with a different colour or tone. So the purpose of this work was to suggest a new approach in order to allow for more precise identification of the phases in the steel. The results were positive, showing that looking at the samples as a whole is better than the traditional methods. Also, different etchants' characteristics were observed during the changes obtained by this work's chosen processes.