RESUMO
In recent years, there has been an increase in pesticide use to improve crop production due to the growth of agricultural activities. Consequently, various pesticides have been present in the environment for an extended period of time. This review presents a general description of recent advances in the development of methods for the quantification of pesticides used in agricultural activities. Current advances focus on improving sensitivity and selectivity through the use of nanomaterials in both sensor assemblies and new biosensors. In this study, we summarize the electrochemical, optical, nano-colorimetric, piezoelectric, chemo-luminescent and fluorescent techniques related to the determination of agricultural pesticides. A brief description of each method and its applications, detection limit, purpose-which is to efficiently determine pesticides-cost and precision are considered. The main crops that are assessed in this study are bananas, although other fruits and vegetables contaminated with pesticides are also mentioned. While many studies have assessed biosensors for the determination of pesticides, the research in this area needs to be expanded to allow for a balance between agricultural activities and environmental protection.
Assuntos
Técnicas Biossensoriais/métodos , Colorimetria/métodos , Técnicas Eletroquímicas/métodos , Medições Luminescentes/métodos , Praguicidas/isolamento & purificação , Espectrometria de Fluorescência/métodos , Agricultura , Técnicas Biossensoriais/economia , Técnicas Biossensoriais/instrumentação , Colorimetria/economia , Colorimetria/instrumentação , Conservação dos Recursos Naturais/métodos , Produtos Agrícolas/efeitos dos fármacos , Produtos Agrícolas/microbiologia , Produtos Agrícolas/parasitologia , Produtos Agrícolas/virologia , Técnicas Eletroquímicas/economia , Técnicas Eletroquímicas/instrumentação , Monitoramento Ambiental/instrumentação , Monitoramento Ambiental/métodos , Humanos , Limite de Detecção , Medições Luminescentes/economia , Medições Luminescentes/instrumentação , Musa/efeitos dos fármacos , Musa/microbiologia , Musa/parasitologia , Musa/virologia , Espectrometria de Fluorescência/economia , Espectrometria de Fluorescência/instrumentaçãoRESUMO
Smart electroactive biomaterials are sought to allow the direct delivery of electrical, electrochemical and electromechanical signals to biological tissues. Specifically, poly-(3,4-ethylenedioxythiophene) (PEDOT) is a polymer of special interest attending to its biocompatibility, tuneable electrical conductivity and processing versatility. In this work, nanostructured PEDOT was synthesized using starch/κ-carrageenan aerogels as templates. κ-carrageenan biopolymer acted as doping agent of the conductive polymer to enhance the biocompatibility and the electrical response. The physicochemical, morphological, mechanical and electrical properties of the nanostructured PEDOT and templates were characterized. The incorporation of κ-carrageenan to the nanostructured materials resulted in an increase in the compressive strength of ca. 40% and a decrease in the electrical impedance of one order-of-magnitude. The synergistic combination of the inherent electrical properties of the PEDOT, the advantageous features of κ-carrageenan as doping agent and the porous morphology of the aerogel template resulted in electroactive PEDOT nanostructures with relevant properties for biomedical applications.