RESUMO
The recovery of gold from wastewater is necessary from both environmental and economic standpoints. Metal-organic frameworks (MOFs) can serve as high-capacity and selective adsorbents, as shown in a recent work by Zhao and co-workers. Their novel three-dimension cationic framework goes further than selectively adsorbing AuCl4 - . It also serves as a stable platform to transform adsorbed gold into an efficient catalyst for the electrochemical reduction of CO2 . This work highlights the versatility of MOFs, which can serve as selective adsorbents and as a support for nanoparticle catalysts.
RESUMO
Metal-organic Frameworks (MOFs) have emerged as promising materials for different electrochemical applications. Their low conductivity, however, is a major challenge to overcome. Therefore, a deeper understanding on the charge transfer mechanism is needed to improve the conductivity of MOF-based electrodes. For this contribution, we focused on metalated MOF-525 and found that the nature of the metal center is one of the many factors contributing to the charge transfer kinetics, which is attributed to differences in redox behaviour, affecting the hopping distance and the electron transfer rate. These results highlight the importance of the nature of the redox active site to optimize charge transfer in MOF-based electrodes.