RESUMO

The influence of process conditions (rotary speed/temperature) on the performance of a rotary kiln reactor for non-catalytic pyrolysis of a perennial grass (elephant grass) was investigated. The product yields, the production of non-condensable gases as well as the biochar properties were evaluated. The maximum H2 yield was close to that observed for catalytic pyrolysis processes, while the bio-oil yield was higher than reported for pyrolysis of other biomass in rotary kiln reactors. A H2/CO ratio suitable for Fischer-Tropsch synthesis (FTS) was obtained. The biochars presented an alkaline pH (above 10) and interesting contents of nutrients, as well as low electrical conductivity, indicating a high potential as soil amendment.

Assuntos

Biomassa , Carvão Vegetal , Pennisetum , Solo/química , Catálise , Cátions , Cromatografia Gasosa , Condutividade Elétrica , Gases , Temperatura Alta , Hidrogênio/química , Concentração de Íons de Hidrogênio , Lignina/química , Temperatura , Termogravimetria