RESUMO
The clinoptilolite natural zeolites (NZs) posses low herbicide adsorption capacity demanding acid-, alkali-, or salt chemical modifications that enhance its adsorption. However, this may affect the material structure and charge distribution. Alternatively, zeolites may be synthesized at a high cost and time-consuming process. Consequently, new methods, such as the hydrothermal method, for NZ modification needs to be studied. In this sense, a novel surface-modified zeolite (SMZ), using hexadecyltrimethylammonium bromide (CTAB), in acid media was produced by the hydrothermal method and applied for the adsorption of Atrazine (ATZ), Diuron (DIU) and 2,4-D. Commercial NZ and SMZ were characterized by SEM, XRD, TGA, FT-IR, AA spectroscopy, pHPZC, Zeta potential and N2-physisorption. The SMZ chosen for the adsorption experiments was the one with the highest modification yield and adsorption capacity obtained from a complete design of experiments (CTAB=0.74 ; D=12 Mesh; HCl=0.1 M; t=6 h and T=205 ºC). The adsorption experiments revealed that the SMZ adsorption capacity for the herbicide 2,4-D (qmax=9.02 mg/g) was greater than that obtained for ATZ (qmax=2.11 mg/g) and DIU (qmax=1.85 mg/g), which was explained by the presence of the hydroxyl group and by geometric characteristics of the 2,4-D. Adsorption models' fitting showed that the adsorption of 2,4-D onto SMZ were best described by pseudo-second order kinetic (k2=0.005-0.006 g/mg.min; qe,exp=7.122-8.614 mg/g) and Langmuir isothermal model (KL=0.283-0.499 L/mg; qm=7.167-7.995 mg/g). These results indicate that the hydrothermal method is a viable alternative to enable the use of NZs for the adsorption of emerging contaminants from wastewater.
Assuntos
Herbicidas , Zeolitas , Zeolitas/química , Adsorção , Espectroscopia de Infravermelho com Transformada de Fourier , Cetrimônio , Tensoativos/química , Diurona , Cinética , Ácido 2,4-DiclorofenoxiacéticoRESUMO
Diazepam has been detected in water sources around the world affecting the quality of drinking water. Even in small quantities, recent studies have proven the negative effects of the drug on human body. Since traditional water and sewage treatment do not remove this type of contaminant, it became interesting to evaluate forms to remove them from water sources. A cheap and eco-friendly alternative to remove this drug from the water is through adsorption using the natural clinoptilolite zeolite as an adsorbent. This work goal was to study the characterizations of clinoptilolite, such as scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffractometer (XRD), and Fourier transform infrared spectroscopy (FTIR) and analyze the potential of this material as an adsorbent. Kinetic studies and isotherm analysis were performed in batch. The results showed the potential of the natural zeolite to remove the pollutant in an aqueous medium reaching a maximum adsorption capacity of 8.25 mg g-1. The adsorption process followed a pseudo-second-order kinetics indicating that the adsorption was based on a chemisorption process. The isotherms curves shown favorable adsorption and the Langmuir isotherm model fit the experimental data better.
Assuntos
Água Potável , Poluentes Químicos da Água , Zeolitas , Humanos , Zeolitas/química , Adsorção , Cinética , Diazepam , Esgotos , Poluentes Químicos da Água/análise , Termodinâmica , Espectroscopia de Infravermelho com Transformada de Fourier , Concentração de Íons de HidrogênioRESUMO
The objective of this work was to evaluate the photocatalytic activity of zinc oxide catalysts supported on natural zeolite clinoptilolite for photocatalytic degradation of the drug hydroxychloroquine, used in the treatment of malaria and which has been tested in the treatment of COVID-19. To synthesize 10%ZnOCP and 15%ZnOCP catalysts, the wet impregnation methodology was used. The raw and synthesized catalysts were characterized by XRD, SEM, XRF, BET, DRS, PCZ, FT-IR and PL. The degradation of hydroxychloroquine was calculated using UV-vis absorption from the samples before and after the photocatalytic process. The maximum percentage of degradation (96%) was obtained with the operational parameters of C0 = 10 mg L-1; Ccat = 2 g L-1 of 15%ZnOCP; pH = 7.5; UV-A radiation. Ecotoxicological tests against the bioindicators Lactuca sativa and Artemia salina confirmed the reduction of effluent toxicity after treatment.
Assuntos
Tratamento Farmacológico da COVID-19 , Zeolitas , Óxido de Zinco , Catálise , Humanos , Hidroxicloroquina , SARS-CoV-2 , Espectroscopia de Infravermelho com Transformada de FourierRESUMO
The persistence of many micropollutants in water and wastewater is of great concern to the contemporary scientific community. Several types of advanced techniques such as heterogeneous photocatalysis are being used for the degradation of micropollutants in waters from domestic, industrial, and agricultural activities. Thus, structured photocatalytic systems are a great alternative in the development of photocatalytic reactors and continuous water treatment systems, as they present good autonomy during the treatment process. Many aspects such as type and geometry of the catalytic structure to be developed must be carefully chosen for the proper functioning of the system, as well as the best routes by which the photocatalysts will be immobilized. In this sense, this work brings the main photocatalytic coating techniques in low-cost structures for the treatment of water and wastewater contaminated with micropollutants. The methodologies and synthesis parameters that can influence the final result of the coating were highlighted, as well as the ability to reuse photocatalysts and methods for pretreating the structural surface. The dip-coating technique was the most reported among the current works due to its simplicity and, predominantly, the pretreatment techniques of the structure are still cleaning the surface with water, soap, and also some alcohols.