RESUMO

Incidents of mining dam failure have compromised the water quality, threatening the water supply. Different strategies are sought to restore the impacted area and to guarantee the water supply. One example is water treatment plants that treat high-polluted waters within the required limits for their multiple usages. The current study assesses the integration of reverse osmosis (RO) to a river water treatment plant (RWTP) installed in Brumadinho (Minas Gerais, Brazil) to treat the water from the Ferro-Carvão stream impacted by the B1 dam rupture in 2019. The RWTP started eleven months after the mining dam rupture and is equipped with eight coagulation-flocculation tanks followed by eight pressurised filters. A pilot RO plant was installed to polish the water treated by the RWTP. Water samples were collected at different points of the water treatment plant and were characterised by their physical, chemical, and biological parameters (160 in total). The results were compared with the historical data (1997-2022) to reveal the alterations in the water quality after the rupture event. The compliance with both parameters was only achieved after the RO treatment, which acted as an additional barrier to 30 contaminants. The water quality indexes (WQI) suggested that the raw surface water, even eleven months after the incident, was unfit for consumption (WQI: 133.9) whereas the reverse osmosis permeate was ranked as excellent in the rating grid (WQI: 23.7).

RESUMO

The present study provides an environmental risk assessment of the pharmaceutical mixtures detected in Brazilian surface waters, based on Toxic Units and Risk Quotients. Furthermore, the applicability of a previously proposed prioritization methodology was evaluated. The pharmaceuticals were classified according to their properties (occurrence, persistence, bioaccumulation, and toxicity) and the contribution of the prioritized compounds to the mixture risk was determined. The mixture risk quotients, based on acute and chronic toxicity data, often exceed 1, demonstrating a potential risk for the environment. While algae were most affected by acute effects, fish were the most sensitive organism to sublethal effects. The lipid regulator atorvastatin was the main driver for the mixture risk. Despite their lower occurrence, the antibiotics norfloxacin and enrofloxacin were critical compounds for the algae group. The prioritized pharmaceuticals contributed to more than 75% of the mixture risk in most of cases, indicating the applicability of prioritization approaches for risk management.

Assuntos

Preparações Farmacêuticas , Poluentes Químicos da Água , Animais , Bioacumulação , Monitoramento Ambiental , Medição de Risco , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/toxicidade

RESUMO

This study provided a monitoring of phenolic compounds occurrence in a river and in its treated water by a conventional water treatment plant (WTP) throughout a year-period, in Minas Gerais - Brazil. Furthermore, the environmental risk (hazard quotient - HQ), the human health risk (margin of exposure - MOE), and the cancer risk were calculated for the compounds. The results indicated that sixteen out of the seventeen investigated phenolic compounds were detected at some point during the sampling campaign. The most frequent compounds in the raw surface water were 2,3,4-trichlorophenol (234TCP), 2,4-dimethylphenol (24DMP), and 4-nitrophenol (4NP), whereas in treated water were 4NP and bisphenol A (BPA). In addition, the highest total concentration values were corelated to the months in which there was less precipitation, demonstrating that the presence of this micropollutants may be subject to seasonality. From the treated water results, it was not possible to state the efficiency of the conventional WTP in eliminating the phenols, since in some samples the phenolic compounds were totally removed and in others their increase or formation occurred. Regarding to the risk assessments, most of the evaluated compounds were considered highly toxic to some trophic level and posed a significant human health risk. Additionally, the risk reduction of phenolics using conventional WTP was low. The sixteen phenols contamination in surface and drinking waters appears to be subject to seasonality. Besides that, an alarming risk for environment and human health was identified.

Assuntos

Poluentes Químicos da Água , Compostos Benzidrílicos/análise , Brasil , Monitoramento Ambiental , Humanos , Fenóis/análise , Medição de Risco , Rios , Estações do Ano , Poluentes Químicos da Água/análise

RESUMO

The presence of pharmaceuticals in aquatic environments has become a major issue of concern for scientific community, since there is a lack of information about risks and impacts to the environment and public health. In the context of Brazil, many cities do not have Wastewater Treatment Plants (WWTPs) and domestic sewage is dumped directly into the water bodies, aggravating the problem. Thus, the present study aimed to evaluate the presence of 28 prescribed pharmaceuticals from different therapeutic classes in six full-scale Drinking Water Treatment Plants (DWTPs) in Minas Gerais state. Samples were collected in twelve field campaigns from August 2016 to August 2017 and water quality were monitored. Analytical methodology was based on solid phase extraction (C18 cartridge) followed by High Performance Liquid Chromatography (Prominence DGU/20A3 - Shimadzu) coupled to Mass Spectrometry (micrOTOF-QII - Bruker). Considering the 28 pharmaceuticals analyzed, 18 were detected in the surface water source at concentrations ranging from Method Quantification Limit (MQL) to 11,960 ng/L. In drinking water, the concentration of the 11 pharmaceuticals detected ranged from

Assuntos

Monitoramento Ambiental/métodos , Preparações Farmacêuticas/análise , Poluentes Químicos da Água/análise , Purificação da Água/métodos , Brasil , Cidades , Água Potável/química , Estações do Ano , Esgotos/química , Águas Residuárias/química , Abastecimento de Água