RESUMO
Considering that functional magnetite (Fe3O4) nanoparticles with exceptional physicochemical properties can be highly applicable in different fields, scaling-up strategies are becoming important for their large-scale production. This study reports simulations of scaled-up production of citric acid-coated magnetite nanoparticles (Fe3O4-cit), aiming to evaluate the potential environmental impacts (PEIs) and the exergetic efficiency. The simulations were performed using the waste reduction algorithm and the Aspen Plus software. PEI and energy/exergy performance are calculated and quantified. The inlet and outlet streams are estimated by expanding the mass and energy flow, setting operating parameters of processing units, and defining a thermodynamic model for properties estimation. The high environmental performance of the production process is attributed to the low outlet rate of PEI compared to the inlet rate. The product streams generate low PEI contribution (-3.2 × 103 PEI/y) because of the generation of environmentally friendlier substances. The highest results in human toxicity potential (3.2 × 103 PEI/y), terrestrial toxicity potential (3.2 × 103 PEI/y), and photochemical oxidation potential (2.6 × 104 PEI/y) are attributed to the ethanol within the waste streams. The energy source contribution is considerably low with 27 PEI/y in the acidification potential ascribed to the elevated levels of hydrogen ions into the atmosphere. The global exergy of 1.38% is attributed to the high irreversibilities (1.7 × 105 MJ/h) in the separation stage, especially, to the centrifuge CF-2 (5.07%). The sensitivity analysis establishes that the global exergy efficiency increases when the performance of the centrifuge CF-2 is improved, suggesting to address enhancements toward low disposal of ethanol in the wastewater.
RESUMO
The incorporation of sustainability aspects into the design of chemical processes has been increasing since the last century. Hence, there are several proposed methodologies and indicators to assess chemical facilities through process analysis techniques. A comprehensive assessment involving economic, environmental, safety, and exergy parameters of two alternatives for butanol production from Manihot esculenta Crantz (cassava waste) is presented in this study. The modeling of process topologies involved using Aspen Plus software. Topology 1 generated a product flow rate of 316,477 t/y of butanol, while this value was 367,037 t/y for topology 2. Both processes used a feed flow of 3,131,439 t/y of biomass. This study used seven technical indicators to evaluate both alternatives, which include the return of investment, discounted payback period, global warming potential, renewability material index, inherent safety index, exergy efficiency, and exergy of waste ratio. Otherwise, this study implemented an aggregate index to assess overall sustainability performance. The results revealed that topology 2 presented higher economic normalized scores for evaluated indicators, but the most crucial difference between these designs came from the safety and exergetic indexes. Topology 1 and topology 2 obtained weighted scores equaling to 0.48 and 0.53; therefore, this study found that the second alternative gives a more sustainable design for butanol production under evaluated conditions.