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1.
ACS Omega ; 9(26): 28093-28104, 2024 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-38973876

RESUMO

One-sided surface charring of wood is a modification process used to lower moisture absorption and improve the resistance to biological degradation for durable surface exterior claddings. Cupressus lusitanica, Gmelina arborea, and Tectona grandis wood samples from fast-growth plantation were charred with a hot plate using three temperatures (300, 350, and 400 °C ± 3 °C) for 10 min. Wood density, surface quality (color and presence of splits), and sorption characteristics (wetting rate and water uptake) were evaluated. Results show that samples charred at 300 °C presented a lower loss of density and thickness than samples charred at 400 °C. Changes in the chemical structure of the wood as a result of the high temperatures caused a decrease of all color parameters (L*, a*, and b*). These values decreased in the samples charred at 400 °C for the three species. Also, the presence of cracks and splits on the surface, or in some cases the presence of detachments from the charring surface, was mostly observed in the samples charred at 350 and 400 °C. One-sided surface charring reduced the liquid water sorption of wood samples in comparison with that of reference samples, especially for C. lusitanica and T. grandis. G. arborea, due to the composition of its anatomical structure and its initial density, chars faster than the other species, causing a greater loss of density, wetting rate values like those of the reference wood, and higher values of water uptake.

2.
Materials (Basel) ; 15(9)2022 May 09.
Artigo em Inglês | MEDLINE | ID: mdl-35591726

RESUMO

Magnetic wood is a composite material that achieves harmony between both woody and magnetic functions through the active addition of magnetic characteristics to the wood itself. In addition to showing magnetic characteristics, magnetic wood offers low specific gravity, humidity control and acoustic absorption ability. It has potential for broad applications in the fields of electromagnetic wave absorption, electromagnetic interference shielding, furniture, etc. This work reports on the synthesis of Fe3O4 nanoparticles (NPs) in wood from three tropical species (Pinus oocarpa, Vochysia ferruginea and Vochysia guatemalensis) using a solution of iron (III) hexahydrate and iron (II) chloride tetrahydrate with a molar ratio of 1.6:1 at a concentration of 1.2 mol/L ferric chlorate under 700 kPa pressure for 2 h. Afterward, the wood samples were impregnated with an ammonia solution with three different immersion times. The treated wood (wood composites) was evaluated for the weight gain percentage (WPG), density, ash content and Fe3O4 content by the Fourier transform infrared spectroscopy (FTIR) spectrum, X-ray diffraction (XRD) and vibrating sample magnetometry (VSM). The results show that the species P. oocarpa had the lowest values of WPG, and its density decreased in relation to the untreated wood, with lower ash and Fe3O4 NP content. The XRD and some FTIR signals associated with changes in the wood component showed small differences from the untreated wood. Fe3O4 NPs presented nanoparticles with the smallest diameter of (approx. 7.3 to 8.5 nm), and its saturation magnetization (Ms) parameters were the lowest. On the other hand, V. guatemalensis was the species with the best Ms values, but the wood composite had the lowest density. In relation to the different immersion times, the magnetic properties were not statistically affected. Finally, the magnetization values of the studied species were lower than those of the pure Fe3O4 nanoparticles, since the species only have a certain amount of these nanoparticles (NPs), and this was reflected proportionally in the magnetization of saturation.

3.
Waste Manag Res ; 38(8): 886-895, 2020 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-31868136

RESUMO

The construction sector in Costa Rica produces approximately 100 kg per square meter of residues, of which wood waste comprises 30%. Utilization of these wastes is still limited, but options are being sought and biomass is one of them. The aim of this work was to evaluate the characteristics of biomass produced from wood waste from construction, its energy potential, and its appropriateness for pellet manufacturing by determining its energy, physical, and mechanical characteristics. It was found that wood waste from construction is composed of different species with densities below 0.5 g/cm3, 26% moisture content, and 10% ash content; contamination with cement and nails can reach 6%. The process of pellet manufacturing can adapt adequately to using wood waste from construction, with an efficiency or yielding of 33%. Pellets presented a calorific value of 19573 kJ/kg, a bulk density of 1.25 g/cm3, an apparent density of 700 kg/m3, a failure force in compression of 467 N, and durability of 94.28%. According to different standards, the results obtained for biomass from wood waste are within the range established for pellet quality; therefore, wood waste from construction can be used to produce pellets, despite the disadvantage of it presenting high ash content.


Assuntos
Madeira , Biomassa , Costa Rica
4.
Waste Manag Res ; 32(2): 106-14, 2014 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-24519224

RESUMO

Lignocellulosic wastes resulting from agricultural activities as well as Tetra Pak residues from urban centres can cause significant levels of pollution. A possible action to minimize this problem is to use them in the production of particleboards. The purpose of this study was to evaluate the physical, mechanical, and hydration properties of particleboards manufactured with the mixture of woody biomass (Cupressus lusitanica, Gmelina arborea, and Tectona grandis) and either agricultural wastes [pineapple leaves (Ananas comosus) and palm residues (Elaeis guineensis)] or Tetra Pak residues (TP). The results show that the particleboards prepared with TP and woody biomass can reduce the swelling and water absorption in up to 40% and 50% compared with particleboards without TP. Also, these particleboards had increased flexure resistance and shear stress (up to 100%) compared with those without TP. On the contrary, particleboards prepared with pineapple leaves in combination with woody biomass showed the lowest mechanical properties, particularly for tensile strength, hardness, glue-line shear, and nail and screw evaluation.


Assuntos
Materiais de Construção , Reciclagem/métodos , Madeira/química , Agricultura , Biomassa , Cinética , Maleabilidade , Resistência ao Cisalhamento , Água/química
5.
Rev Biol Trop ; 61(3): 1133-56, 2013 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-24027913

RESUMO

A total of 45 native Costa Rican tree species are threatened or in danger of extinction, but the Convention on International Trade Endangered Species (CITES) includes only eight of these in its Appendices. However, the identification of other species based on their wood anatomy is limited. The present study objective was to describe and to compare wood anatomy and fluorescence activity in some endangered or threatened species of Costa Rica. A total of 45 (22 endangered and 23 threatened with extinction) wood samples of these species, from the xylaria of the Instituto Tecnológico de Costa Rica and the Forest Products Laboratory in Madison, Wisconsin, were examined. Surface fluorescence was positive in eight species, water extract fluorescence was positive in six species and ethanol extract fluorescence was positive in 24 species. Almost all species were diffuse porous except for occasional (Cedrela odorata, C. fissilis, Cordia gerascanthus) or regular (C. salvadorensis and C. tonduzii) semi-ring porosity. A dendritic vessel arrangement was found in Sideroxylon capari, and pores were solitary in Guaiacum sanctum and Vantanea barbourii. Vessel element length was shortest in Guaiacum sanctum and longest in Humiriastrum guianensis, Minquartia guianensis and Vantanea barbourii. Finally, anatomical information and fluorescence activity were utilized to construct an identification key of species, in which fluorescence is a feature used in identification.


Assuntos
Espécies em Perigo de Extinção , Árvores/classificação , Madeira/anatomia & histologia , Costa Rica , Fluorescência , Árvores/anatomia & histologia
6.
Rev. biol. trop ; Rev. biol. trop;61(3): 1113-1156, sep. 2013. ilus, tab
Artigo em Inglês | LILACS | ID: lil-688465

RESUMO

A total of 45 native Costa Rican tree species are threatened or in danger of extinction, but the Convention on International Trade Endangered Species (CITES) includes only eight of these in its Appendices. However, the identification of other species based on their wood anatomy is limited. The present study objective was to describe and to compare wood anatomy and fluorescence activity in some endangered or threatened species of Costa Rica. A total of 45 (22 endangered and 23 threatened with extinction) wood samples of these species, from the xylaria of the Instituto Tecnológico de Costa Rica and the Forest Products Laboratory in Madison, Wisconsin, were examined. Surface fluorescence was positive in eight species, water extract fluorescence was positive in six species and ethanol extract fluorescence was positive in 24 species. Almost all species were diffuse porous except for occasional (Cedrela odorata, C. fissilis, Cordia gerascanthus) or regular (C. salvadorensis and C. tonduzii) semi-ring porosity. A dendritic vessel arrangement was found in Sideroxylon capari, and pores were solitary in Guaiacum sanctum and Vantanea barbourii. Vessel element length was shortest in Guaiacum sanctum and longest in Humiriastrum guianensis, Minquartia guianensis and Vantanea barbourii. Finally, anatomical information and fluorescence activity were utilized to construct an identification key of species, in which fluorescence is a feature used in identification.


Un total de 45 especies de árboles de Costa Rica se catalogaron como amenazadas o en peligro de extinción, de las cuales, CITES (Convention on International Trade Endangered Species) incluye solamente ocho en sus Apéndices. Sin embargo, la identificación de las especies basadas en su anatomía es muy limitada. El presente estudio tiene el objetivo describir y comparar la anatomía y la fluorescencia de las especies amenazadas o en peligro de extinción de Costa Rica. Muestras de madera de las especies en peligro de extinción o amenazadas de la xiloteca del Instituto Tecnológico de Costa Rica y del Laboratorio de Productos Forestales de los Estados Unidos en Wisconsin se examinaron, se describió su anatomía, se evaluó su actividad fluorescente y se midió su densidad. La superficie de la madera fue fluorescente en ocho especies, el extracto en agua fue fluorescente en seis especies y el extracto en etanol fue positivo en 24 especies. Muchas de las especies presentaban porosidad difusa, excepto algunas Cedrela odorata, C. fissilis, Cordia gerascanthus C. salvadorensis y C. tonduzii que presentaban porosidad semi-anular. Vasos con distribución déndrica se encontró en Sideroxylon capari y poros solitarios en Guaiacum sanctum y Vantanea barbourii. Los vasos más cortos se encontraron en Guaiacum sanctum y los vasos más largos en Humiriastrum guianensis, Minquartia guianensis y Vantanea barbourii. Finalmente, la información de la anatomía y de su fluorescencia se utilizó para construir una clave de identificación, donde la actividad de fluorescencia juega un papel importante en la identificación.


Assuntos
Espécies em Perigo de Extinção , Árvores/classificação , Madeira/anatomia & histologia , Costa Rica , Fluorescência , Árvores/anatomia & histologia
7.
Molecules ; 17(4): 3639-52, 2012 Mar 26.
Artigo em Inglês | MEDLINE | ID: mdl-22450677

RESUMO

The heterogeneity of color distribution between sapwood and heartwood limits the market for wood from fast-growth plantations of tropical species. Wood color is associated with wood extractives contents. This study presents the relationship between wood color parameters measured by the CIELab color system and total amount of extractives and phenolic-type extractives in ethanol-toluene and hot water extracts of wood from two fast-growth plantation species. The results demonstrated that the difference in sapwood and hardwood color in Vochysia guatemalensis and Acacia mangium is caused by lower concentrations of extractives in sapwood of both species. Additionally, variations in total extractive and phenolic content have different effects on the color parameters (L*, a* and b*) of both species studied. In Vochysia guatemalensis wood, parameter L* decreases as total extractive and phenolic content increases; however, parameter a* increases as the content of extractives and phenols increases. In Acacia mangium, the amount of phenols showed no relationship with the color parameters. The ethanol-toluene total extractive content, however, shows a relationship with several color parameters. An increase in the content of total extractives in water and ethanol-toluene increases parameter a*, but decreases parameter L*.


Assuntos
Extratos Vegetais/química , Madeira/química , Acacia/química , Cor , Fenol/análise
8.
Rev. biol. trop ; Rev. biol. trop;56(2): 689-704, jun. 2008. ilus, graf, mapas, tab
Artigo em Inglês | LILACS | ID: lil-637669

RESUMO

The tree Gmelina arborea has been widely introduced in Costa Rica for commercial purposes. This new conditions for melina cause variations on anatomy in secondary xylem of the trees growing in plantations. The objective of the present research was to determine the variation in the anatomy of xylem caused by the ecological conduction variation. Dimensions of fiber, axial parenchyma percentage of cross sections, parameters of vessels and the ray were measured. The results showed that some anatomical characteristics remained stable despite variations of ecological conditions, especially radial parenchyma and anatomical features which were less affected by the altitude. On the other hand, the vessels, axial parenchyma and fiber were less stable because they were affected significantly by the longitude, latitude, altitude and precipitation. Latitude significantly affected vessel percentage, length and diameter of the fiber and lumen. Longitude affected vessel percentage and fiber diameter. Altitude had a significant correlation with the amount of cells at ray height. Annual average precipitation affected vessel percentage and diameter, not only of the fiber, but also of the lumen. These results suggest that the new growth conditions of G. arborea trees in Costa Rica have produced an anatomic adaptation. Rev. Biol. Trop. 56 (2): 689-704. Epub 2008 June 30.


Gmelina arborea ha sido introducida y ampliamente sembrada en Costa Rica en plantaciones de rápido crecimiento. Estas nuevas condiciones ecológicas provocan variación en la anatomía del xilema de estos árboles. El presente trabajo tuvo como objetivo determinar la variación en la anatomía del xilema debido a la variación de la latitud, longitud, altitud y precipitación. Se evaluaron las dimensiones de las fibras, el porcentaje de área ocupada por el parénquima y los parámetros de los vasos y los radios. Algunas características anatómicas se mantuvieron estables con las variaciones de las condiciones ecológicas evaluadas, especialmente el parénquima radial. La altitud es la condición ecológica con menor afecto en la anatomía de la madera. Los vasos, el parénquima axial y las fibras fueron menos estables debido a que fueron afectados significativamente por la longitud, latitud, altitud y precipitación. La latitud afectó significativamente el porcentaje de vasos, porcentaje de radios, largo y diámetro de la fibra y diámetro del lumen; la longitud afectó el porcentaje de vasos y el diámetro de la fibra; la altitud únicamente mostró relación significativa con la cantidad de células en la altura de los radios. La precipitación media anual mostró efectos sobre el porcentaje de poros y el diámetro de la fibra y el lumen. Dichos resultados sugieren que las condiciones de crecimiento en Costa Rica para G. arborea son indicadores de un posible genotipo del árbol.


Assuntos
Ecossistema , Geografia , Chuva , Verbenaceae/anatomia & histologia , Madeira/anatomia & histologia , Costa Rica
9.
Rev Biol Trop ; 56(2): 689-704, 2008 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-19256437

RESUMO

The tree Gmelina arborea has been widely introduced in Costa Rica for commercial purposes. This new conditions for melina cause variations on anatomy in secondary xylem of the trees growing in plantations. The objective of the present research was to determine the variation in the anatomy of xylem caused by the ecological conduction variation. Dimensions of fiber, axial parenchyma percentage of cross sections, parameters of vessels and the ray were measured. The results showed that some anatomical characteristics remained stable despite variations of ecological conditions, especially radial parenchyma and anatomical features which were less affected by the altitude. On the other hand, the vessels, axial parenchyma and fiber were less stable because they were affected significantly by the longitude, latitude, altitude and precipitation. Latitude significantly affected vessel percentage, length and diameter of the fiber and lumen. Longitude affected vessel percentage and fiber diameter. Altitude had a significant correlation with the amount of cells at ray height. Annual average precipitation affected vessel percentage and diameter, not only of the fiber, but also of the lumen. These results suggest that the new growth conditions of G. arborea trees in Costa Rica have produced an anatomic adaptation.


Assuntos
Ecossistema , Geografia , Chuva , Verbenaceae/anatomia & histologia , Madeira/anatomia & histologia , Costa Rica
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