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1.
J Environ Manage ; 261: 110218, 2020 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-32148288

RESUMO

Diverse fields of modern environmental technology are nowadays focused on the discovery and development of new sources for oil spill removal. An especially interesting type of sorbents is those of natural origin-biosorbents-as ready-to-use constructs with biodegradable, nontoxic, renewable and cost-efficient properties. Moreover, the growing problem of microplastic-related contamination in the oceans further encourages the use of biosorbents. Here, for the first time, naturally pre-designed molting cuticles of the Theraphosidae spider Avicularia sp. "Peru purple", as part of constituting a large-scale spider origin waste material, were used for efficient sorption of crude oil. Compared with currently used materials, the proposed biosorbent of spider cuticular origin demonstrates excellent ability to remain on the water surface for a long time. In this study the morphology and hydrophobic features of Theraphosidae cuticle are investigated for the first time. The unique surface morphology and very low surface free energy (4.47 ± 0.08 mN/m) give the cuticle-based, tube-like, porous biosorbent excellent oleophilic-hydrophobic properties. The crude oil sorption capacities of A. sp. "Peru purple" molt structures in sea water, distilled water and fresh water were measured at 12.6 g/g, 15.8 g/g and 16.6 g/g respectively. These results indicate that this biomaterial is more efficient than such currently used fibrous sorbents as human hairs or chicken feathers. Four cycles of desorption were performed and confirmed the reusability of the proposed biosorbent. We suggest that the oil adsorption mechanism is related to the brush-like and microporous structure of the tubular spider molting cuticles and may also involve interaction between the cuticular wax layers and crude oil.


Assuntos
Poluição por Petróleo , Petróleo , Aranhas , Poluentes Químicos da Água , Adsorção , Animais , Muda , Peru , Plásticos
2.
J Econ Entomol ; 96(3): 850-5, 2003 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-12852626

RESUMO

In the laboratory, Argentine ant, Linepithema humile (Mayr), mortality was positively correlated to the length of an aromatic cedar mulch section that had to be crossed before food could be reached. When ants could access food without crossing the mulch, mortality was not correlated to mulch section length. In the field, Argentine ants showed a tendency to avoid aromatic cedar mulch as a nesting substrate. In plant beds alongside buildings the number of ant nests (pockets containing brood) found was not significantly different between aromatic cedar and cypress mulch. However, when pine straw mulch around oak trees was replaced with aromatic cedar or cypress mulch, a similar number of ant nests was found in the cypress mulch as in the original pine straw, whereas numbers in aromatic cedar mulch were significantly lower. Also, fewer ants were trailing on the trees surrounded by aromatic cedar mulch compared with cypress mulch or the original pine straw. The number of ants attracted to apple jelly baits placed alongside the buildings did not differ between mulch types; neither did the number of ant trails crossing the mulch beds around the buildings. We suggest that aromatic cedar mulch may help control Argentine ants and reduce insecticide input when applied in combination with conventional control methods.


Assuntos
Formigas/efeitos dos fármacos , Formigas/fisiologia , Cedrus/química , Comportamento Alimentar/efeitos dos fármacos , Repelentes de Insetos/farmacologia , Comportamento de Nidação/efeitos dos fármacos , Animais , Argentina , Controle de Insetos , Atividade Motora , Controle Biológico de Vetores
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