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1.
Total Synthesis of Colombiasin A This work was financially supported by the National Institutes of Health (USA) and The Skaggs Institute for Chemical Biology, postdoctoral fellowships from Bayer AG (to R.K. and W.M.), and grants from Abbott, Amgen, ArrayBiopharma, Boehringer-Ingelheim, Glaxo, Hoffmann-La Roche, DuPont, Merck, Novartis, Pfizer, and Schering Plough.
Nicolaou, K. C.; Vassilikogiannakis, Georgios; Mägerlein, Wolfgang; Kranich, Remo.
Angew Chem Int Ed Engl ; 40(13): 2482-2486, 2001 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-11443672
2.
Total Synthesis of Colombiasin A.
Nicolaou, K C; Vassilikogiannakis, Georgios; Mägerlein, Wolfgang; Kranich, Remo.
Angew Chem Int Ed Engl ; 40(13): 2482-2486, 2001 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-29712275

RESUMO

Colombian corals of the species Pseudopterogorgia elisabethae produce the title compound, colombiasin A (1). This structurally novel, biologically active tetracyclic compound has now been synthesized for the first time in racemic form. Preliminary studies toward the asymmetric total synthesis of both enantiomers indicate that the determination of the absolute stereochemistry can be expected soon.

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